Comparison of isotope pairing and N2:Ar methods for measuring sediment denitrification—Assumption, modifications, and implications

Denitrification has been measured during the last few years using two different methods in particular: isotope pairing measured on a triple-collector isotopic ratio mass spectrometer and N₂:Ar ratios measured on a membrane inlet mass spectrometer (MIMS). This study compares these two techniques in short-term batch experiments. Rates obtained using the original N₂∶Ar method were up to 3 to 4 times higher than rates obtained using the isotope pairing technique due to O₂ reacting with the N₂ during MIMS analysis. Oxygen combines with N₂ within the mass spectrometer ion source forming NO⁺ which reduces the N₂ concentration. The decrease in N₂ is least at lower O₂ concentrations and since oxygen is typically consumed during incubations of sediment cores, the result is often a pseudo-increase in N₂ concentration being interpreted as denitrification activity. The magnitude of this ocygen effect may be instrument specific. The reaction of O₂ with N₂ and the subsequent decrease in N₂ was only partly correctly using an O₂ correction curve for the relationship between N₂ and O₂ concentrations. The O₂ corrected N₂∶Ar denitrification rates were lower, but still did not match the isotope pairing rates and the variability between replicates was much higher. Using a copper reduction column heated to 600°C to remove all of the O₂ from the sample before MIMS analysis resulted in comparable rates (slightly lower), and comparable variability between replicates, to the isotope pairing technique. The N₂:Ar technique determines the net N₂ production as the difference between N₂ production by denitrification and N₂ consumption by N-fixation, while N-fixation has little effect on the isotope pairing technique which determines a rate very close to the gross N₂ production. When the two different techniques were applied on the same sediment, the small difference in rates obtained by the two methods seemed to reflect N-fixation as also supported from measurements of ethylene production in acetylene enriched sediment cores. The N₂:Ar and isotope pairing techniques may be combined to provide simultaneous measurements of denitrification and N-fixation. Both techniques have several assumptions that must be met to achieve accurate rates; a number of tests are outlined that can be applied to demonstrate that these assumptions are being meet.     

Tracer experiments with turbulently dispersed air ions

Unipolar air ions released into the wind constitute a tracer which can be measured with high resolution. An ion source produces a cloud with homogeneous charge density, insensitive to source strength, dependent on time since formation only. It is well suited for tracing concentration changes due to turbulence, less suited for cloud size tracing. A tight array of 8 sensors has been used to examine turbulently dispersed ions. High-resolution records are presented and discussed. The highest concentrations measured could be undiluted source material. The frequency distribution within a plume did not differ from that in a multitude of puffs. The distribution seems to be log-normal with a geometric standard deviation of about 2.45. The time resolution used corresponds to volume resolutions of 40, 225, and 650 cm³. Sample size had no apparent effect.     

Interpolating paleovegetation data with an artificial neural network approach

To drive an atmospheric general circulation model (AGCM), land surface boundary conditions like albedo and morphological roughness, which depend on the vegetation type present, have to be prescribed. For the late Quaternary there are some data available, but they are still sparse. Here an artificial neural network approach to assimilate these paleovegetation data is investigated. In contrast to a biome model the relation between climatological parameters and vegetation type is not based on biological knowledge but estimated from the available vegetation data and the AGCM climatology at the corresponding locations. For a test application, a data set for the modern vegetation reduced to the amount of data available for the Holocene climate optimum (about 6000 years B.P.) is used. From this, the neural network is able to reconstruct the complete global vegetation with a kappa value of 0.56. The most pronounced errors occur in Australia and South America in areas corresponding to large data gaps.     

Seasonal dynamics of elemental sulfur in two coastal sediments

A spectrophotometric method for elemental sulfur (S⁰) analysis without interference from other reduced sulfur compounds was adapted for the use in reducing sediments. The S⁰ distribution in two coastal sediments was studied regularly from summer to winter and compared to factors regulating the S⁰ accumulation, such as redox potentials, the rate of bacterial sulfide production and the general sulfur chemistry. Dense coatings of sulfur bacteria developed on the sediment surface of a sulfuretum which had an S⁰ concentration of up to 41 μmol S cm^?3. The 2·5-mm thick bacterial coating contained 40% of all S⁰ in the sediment. A more typical marine sediment with a few cm thick oxidized surface layer had an S⁰ maximum of 1–3 μmol S cm^?3 at 2–4 cm depth. The S⁰ maximum in both sediments increased from summer to winter as the sediments gradually became more oxidized. The deeper layers maintained a low S⁰ concentration. Most of the S⁰ in the upper few mm of a laboratory sulfuretum was present inside sulfur bacteria and actively migrated up and down with the bacteria depending upon the changing light and oxygen conditions.     

On the structural evolution of the Central Trough in the Norwegian and Danish sectors of the North Sea

The Central Trough of the North Sea is not a simple rift graben. It is an elongated area of regional subsidence which was initiated in mid Cretaceous times and continued to subside through to the late Tertiary. Its form is not representative of pre-mid Cretaceous tectonics.In Late Permian times the North Sea was divided into a northern and southern Zechstein basin by the E-W trending Mid North Sea-Ringkøbing-Fyn High. The latter was dissected by a narrow graben trending NNW through the Tail End Graben and the Søgne Basin. The Feda Graben was a minor basin on the northern flank of the Mid North Sea High at this time. This structural configuration persisted until end Middle Jurassic times when a new WNW trend separated the Tail End Graben from the Søgne Basin. Right lateral wrench movement on this new trend caused excessive subsudence in the Tail End and Feda Grabens while the Søgne Basin became inactive.Upper Jurassic subsidence trends continued during the Early Cretaceous causing the deposition of large thicknesses of sediments in local areas along the trend. From mid Cretaceous times the regional subsidence of the Central Trough was dominant but significant structural inversions occurred in those areas of maximum Early Cretaceous and Late Jurassic subsidence.     

Egg production of Calanus finmarchicus—A basin-scale study

Egg production of Calanus finmarchicus was studied during joint basin-scale surveys in April–June 2003 in the Norwegian Sea. Surveys covered the whole Norwegian Sea and were conducted from Norwegian, Icelandic and Faroese research vessels. Stations were classified as being in pre-bloom, bloom or post-bloom phase according to levels of chlorophyll a and nitrate. Individual egg production rates and population egg production rates were calculated and compared between areas. Both individual egg production rates (eggs female⁻¹ day⁻¹) and population egg production rates (eggs m⁻² day⁻¹) were significantly higher in bloom areas compared with pre-bloom and post-bloom areas. However, when integrated over an estimated duration of the three phases, the time-integrated egg production (eggs m⁻²) in most years was highest in the pre-bloom phase, and this was explained by the longer duration of this phase compared with the two other phases.     

X-ray,Hα, and radio observations of the two-ribbon flare of 16 May, 1981

The paper is a contribution to the study of two-ribbon flares. A variety of observational material, i.e. Hα pictures, radio spectrum in the frequency band of 150–1000 MHz, radio map at 6 cm, fluxes at other frequencies, magnetograms and X-ray flux in a broad energy interval, enabled us to study the development of the 16 May, 1981 flare. The onset of the flare could be described by the model of Van Tend and Kuperus. A diminishing of the magnetic shear during the activation of the filament was observed. From radio and X-ray data it was found that pulsed acceleration took place in the region under the rising filament, the electrons propagating in a limited region both upwards to greater heights and downwards into the footpoints. Internal oscillations of the filament were observed. A manifestation of the primary process of interplanetary shock-wave generation was found. The 6 cm radio sources could be localized in the footpoints of magnetic loops.     

Facies distribution and dissolution depths of surface sediment components from the Vema channel and the Rio Grande rise (southwest Atlantic Ocean)

Surface sediments from the Vema channel and from the Rio Grande rise (western extremity) contain less calcareous fossils with increasing water depth. The pteropodal (aragonite) lysocline corresponds to the 3200-m isobath. The pteropodal compensation depth is found above the lower boundary of the North Atlantic Deep Water: 3500 m. The planktonic foraminiferal lysocline (4050 m) seems to be very close to the abyssal thermocline and is therefore here the upper limit of the Antarctic Bottom Water. The foraminiferal and the coccolith compensation depths seem to coincide: 4500 m. Distribution and dissolution of calcareous sediment components are the same all around the western extremity of the Rio Grande rise (southern, western and northern flanks).     

The 1s 2s states of negative hydrogen

Term values for the 1s 2s states of H^– are calculated with the use of simple eigenfunction approximations constructed on the basis of available Hartree-type functions for the 1s ² and 2s ² states of the ion. The results seem to support a tentative identification of the interstellar diffuse absorption bands at 4890 and 6180 as due to negative hydrogen.