Neodymium diffusion in orthopyroxene: Experimental studies and applications to geological and planetary problems

We have determined the Nd³⁺ diffusion kinetics in natural enstatite crystals as a function of temperature, f(O₂) and crystallographic direction at 1 bar pressure and applied these data to several terrestrial and planetary problems. The diffusion is found to be anisotropic with the diffusion parallel to the c-axial direction being significantly greater than that parallel to a- and b-axis. Also, D(//a) is likely to be somewhat greater than D(//b). Diffusion experiments parallel to the b-axial direction as a function of f(O₂) do not show a significant dependence of D(Nd³⁺) on f(O₂) within the range defined by the IW buffer and 1.5 log unit above the WM buffer. The observed diffusion anisotropy and weak f(O₂) effect on D(Nd³⁺) may be understood by considering the crystal structure of enstatite and the likely diffusion pathways. Using the experimental data for D(Nd³⁺), we calculated the closure temperature of the Sm-Nd geochronological system in enstatite during cooling as a function of cooling rate, grain size and geometry, initial (peak) temperature and diffusion direction. We have also evaluated the approximate domain of validity of closure temperatures calculated on the basis of an infinite plane sheet model for finite plane sheets showing anisotropic diffusion. These results provide a quantitative framework for the interpretation of Sm-Nd mineral ages of orthopyroxene in planetary samples. We discuss the implications of our experimental data to the problems of melting and subsolidus cooling of mantle rocks, and the resetting of Sm-Nd mineral ages in mesosiderites. It is found that a cooling model proposed earlier [Ganguly J., Yang H., Ghose S., 1994. Thermal history of mesosiderites: Quantitative constraints from compositional zoning and Fe-Mg ordering in orthopyroxene. Geochim. Cosmochim. Acta 58, 2711-2723] could lead to the observed ∼90 Ma difference between the U-Pb age and Sm-Nd mineral age for mesosiderites, thus obviating the need for a model of resetting of the Sm-Nd mineral age by an “impulsive disturbance” [Prinzhoffer A, Papanastassiou D.A, Wasserburg G.J., 1992. Samarium-neodymium evolution of meteorites. Geochim. Cosmochim. Acta 56, 797-815].     

Helium-isotope systematics at Nevado del Ruiz volcano, Colombia: implications for the volcanic hydrothermal system

We have collected 14 water and gas samples from 9 thermal springs and gas vents near Nevado del Ruiz volcano, Colombia. The ³He/⁴He and ⁴He/²⁰Ne ratios vary significantly from 0.98 R_atm (where R_atm is the atmospheric ³He/⁴He ratio of 1.4 × 10⁻⁶) to 6.30 R_atm, and from 0.37 to 7.0, respectively. The ³He/⁴He ratio (corrected for air contamination) decreases with increasing distance from the central crater of the volcano to the sampling site. The trend is very similar to that observed at Ontake volcano, Japan. A hydrodynamic porous-media dispersion model can explain the ³He/⁴He trend. The temporal variations in the ³He/⁴He ratio at four sites provide useful information on the apparent velocity of the magmatic fluid flow brought on by a volcanic eruption. The estimated value of several tens m day⁻¹ agrees well with the inferred velocity of flow in Oshima volcano, Japan and is comparable to the largest rate of groundwater movement in a deep sedimentary basin.     

Short-term and intermediate-term geochemical precursors

Detection of precursory phenomena in observation data is essential to earthquake prediction studies. Continuous monitoring of radon concentration in groundwater in Japan in one case showed a short-term anomaly related to a nearby earthquake. With the exception of the 1978 Izu-Oshimakinkai earthquake (M7.0), however, no abnormal change has been noted. This may be due partially to difficulty in detecting insignificant precursory signals from observation data, which ordinarily contains a noise-induced fluctuations, and partially to lack of understanding of the mechanism controlling the appearance of precursory phenomena. In order to increase our knowledge of the variation pattern of precursory changes in radon concentration of groundwater, hydrologic precursors with significant features are examined in this paper. Complexity of appearance of precursory phenomena and problems in assignment of the specific earthquake are discussed.     

Volume transport in the Soya Strait during 2006–2008

Time-series data of the vertical structure of the Soya Warm Current (SWC) were obtained by a bottom-mounted acoustic Doppler current profiler (ADCP) in the middle of the Soya Strait from September 2006 to July 2008. The site of the ADCP measurement was within the coverage of the ocean-radar measurement around the strait. The volume transport of the SWC through the strait is estimated on the basis of both the vertical structure observed by the ADCP and the horizontal structure observed by the radars for the first time. The annual transport estimates are 0.62–0.67 Sv (1 Sv = 10⁶ m³s⁻¹). They are somewhat smaller than the difference between the previous estimates of the inflow and outflow through other straits in the Sea of Japan, and smaller than those obtained in the region downstream of the strait during 2004–05 (0.94–1.04 Sv). The difference in the two periods may be attributed to interannual variability of the SWC and/or the different measurement locations.     

Helium isotopes of seawater in the Japan Sea

We have collected fifty-five seawater samples at seven stations at various depths in the Yamato and Japan Basins of the Japan Sea and measured their helium isotopic ratios. The ³He/⁴He ratios vary from 0.997 R_atm to 1.085 R_atm where R_atm is the atmospheric ratio. The maximum ³He excesses about 8%, are observed at mid-depth (1000 m), and these values are significantly lower than those observed in deep Pacific waters. This implies that mantle-derived helium in deep Pacific water cannot enter the Japan Sea since it is an almost landlocked marginal sea. The observed 8% excess ³He may be attributable to the decay product of tritium. Slightly higher ³He/⁴He ratios in the Bottom Water were observed in the Yamato Basin than in the Japan Basin. The ventilation ages of seawater shallower than 1000 m are calculated as about 5 to 20 years, which is consistent with the CFC ages reported in the literature. There is a positive correlation between the apparent oxygen utilization and ³H-³He ages. The estimated oxygen utilization rate from the correlation in a layer between 500 m and 1000 m is about 3 μmol/kg/yr, which is similar to that in the eastern subtropical North Atlantic.     

Ion microprobe uranium‐thorium‐lead dating of Shergotty phosphates

Abstract— We report ion microprobe U‐Th‐Pb dating of Shergotty phosphates by means of the sensitive high‐resolution ion microprobe (SHRIMP) recently installed at Hiroshima University, Japan. ten analyses of whitlockite (merrillite) and three analyses of apatite indicate a ²³⁸u/²⁰⁶pb isochron age of 225 ± 200 ma and a tera‐wasserburg concordia‐constrained linear three‐dimensional isochron age of 217 ± 110 ma in the ²³⁸u/²⁰⁶pb‐²⁰⁷pb/²⁰⁶pb²⁰⁴pb/²⁰⁶pb diagram. These ages agree well with the 232Th‐208pb age of 189 ± 83 Ma, which suggests that primary crystallization or a shock metamorphic event defined the formation age of the phosphate minerals. The average of the later two ages, 204 ± 68 Ma, is consistent with the previously published Rb‐Sr age of 165 ± 11 Ma and U‐Th‐Pb age of ～200 Ma. These show marginal agreement with the ⁴⁰Ar‐³⁹Ar age of 254 ± 10 Ma but are significantly different from the Sm‐Nd age of 360 ± 16 Ma. Taking into account the closure temperature of the U‐Pb system in apatite, we suggest the time that Shergotty last experienced a temperature of ～900 °C was 204 ± 68 Ma.     

Geochemical contrast between the Sanbagawa psammitic schists (Oboke unit) and the Cretaceous Shimanto sandstones in Shikoku, Southwest Japan and its geologic significance

Abstract A systematic geochemical study of sandstones from the Cretaceous Shimanto Supergroup and psammitic schists from the Oboke unit in Shikoku has been carried out in order to clarify the depositional age of the protoliths of the Oboke psammitic schists. The geochemical data, together with chronological and geologic data, led to the following conclusions. (i) It is inferred that Oboke psammitic schists are metamorphically equivalent to sandstones in the Hiwasa Formation of the Shimanto accretionary complex, deposited in a trench area during the Campanian, in eastern Shikoku. (ii) The protolith attained to maximum metamorphic conditions within 20 million years after the deposition. (iii) The accumulation of a large amount of coarse-grained clastic sediments in the trench area induced offscraping and underplating of the sediments in the subduction zone, forming the Hiwasa Formation and Oboke unit, respectively.     

Improved Kakioka automatic standard magnetometer (KASMMER)

The KASMMER (Kakioka Automatic Standard Magnetometer) has been constructed in 1972 for the standard magnetic observation at Kakioka (Yanagiharaet al., 1973). Then KASMMER system has been improved successively for the high level standard magnetic observation. The purpose of the present paper is to introduce an outline of the improved KASMMER system.The KASMMER system consists of four parts which are four optical pumping magnetometers, a fluxgate magnetometer (Supporting system to the optical pumping magnetometers), a calibration system and a data acquisition system (computer system). The calibration system consists of a proton magnetometer and a magnetic theodolite (Di-72). Details for each part are described and the ability of the improved system is shown to be higher than that of classical magnetic observatory systems.     

Noble gas elemental and isotopic abundances in deep-sea trenches in the western Pacific

Noble gas elemental and isotopic abundances were measured in seven deep-sea water samples from five different sampling sites in the Nankai Trough, the Japan Trench and the Kuril Trench. The samples were obtained by the manned submersible “Nautile”. Most of the sampling sites are associated with clam colonies and/or fluid venting. Excesses both in³He/⁴He ratio and He concentration are observed in a seawater sample collected a few kilometers off the clam colonies which were found at a depth of 3830 m at the mouth of the Tenryu Canyon. Concentrations of noble gases (Ne, Ar, Kr and Xe) in this sample show progressive depletion from Ne to Xe relative to those in 1°C air-saturated seawater, which can be attributed to mixing of hot water ( 15°C) with cold ambient water ( 1°C). Isotopic compositions of Ne, Ar, Kr and Xe in this sample are atmospheric. These observations may reflect venting of hot pore water around the Tenryu Canyon. All the other samples show a significant excess in concentration of all noble gases relative to 1°C air-saturated seawater and the isotopic compositions are atmospheric. This excess of noble gas concentrations may appear to be air contamination in the samples. However, results of hydrocarbon analyses of the Kaiko samples imply that such large amount of air contamination is improbable. Decomposition of gas hydrate in deep-sea sediments is a more likely explanation for the observed excess of noble gas concentration.     

Helium Isotopes in Pacific Waters from Adjacent Region of Honshu, Japan

We have measured helium isotopic ratios of thirty-seven Pacific water samples from various depths collected in adjacent regions of Honshu, Japan. The ³He/⁴He ratios vary significantly from 0.989 R _atm to 1.208 R _atm where R _atm is the atmospheric ratio of 1.39 × 10⁻⁶. The mid-depth (750–1500 m) profile of ³He/⁴He ratios at ST-1 located Northwestern Pacific Ocean east of Japan (Off Joban; 37°00′ N, 142°40′ E) is significantly different from that at ST-2 of the Northern Philippine Sea south of Japan (Nankai Trough; 33°07′ N, 139°59′ E), suggesting that these waters were separated by a topographic barrier, the Izu-Ogasawara Ridge. Taking ³He/⁴He data of the Geosecs expeditions in the western North Pacific, an extensive plume of 15% excess ³He relative to the air may be traced at ST-1 over 12,000 kilometers to the northwest of the East Pacific Rise where the mantle helium may originate. The 20% excess found at ST-2 may be attributable to the additional source of the subduction-type mantle helium in the Okinawa Trough. A 15% excess of ³He has also been discovered at a depth of about 1000∼1500 m at ST-3 adjacent to Miyakejima Island (33°57′ N, 139°22′ E) and ST-4 of Sagami Bay (35°00′ N, 139°22′ E). It is confirmed that mid-depth all over the western North Pacific water is affected by the mantle helium with a high ³He/⁴He ratio. This revised version was published online in July 2006 with corrections to the Cover Date.