Soil Iodine Determination in Deccan Syneclise,India: Implications for Near Surface Geochemical Hydrocarbon Prospecting

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana–Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r ² < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.     

Elemental (C,N, H and P) and stable isotope (δ<Superscript>15</Superscript>N and δ<Superscript>13</Superscript>C) signatures in sediments from Zeekoevlei,South Africa: a record of human intervention in the lake

We used elemental carbon, nitrogen, phosphorus and hydrogen ratios (C/N, N/P and H/C) with total organic carbon (TOC) and total phosphorus (TP) as well as stable carbon and nitrogen isotopes (δ¹³C and δ¹⁵N) to investigate the source and depositional conditions of organic matter in sediments from Zeekoevlei, the largest freshwater lake in South Africa. Typical C/N (10–12), H/C ratios (≥1.7) and δ¹³C_organic values (−22 to −19‰) together with the increase in TOC concentration indicate elevated primary productivity in lower middle (18–22 cm) and top (0–8 cm) sections of the sediment cores. Seepage of nutrients from a nearby waste water treatment plant, rapid urbanization and heavily fertilized farming in the catchments are responsible for the increased productivity. Consistent with this, measured δ¹⁵N_organic values (∼11‰) indicate increased raw sewage input towards the top-section of the core. Although cyanobacterial blooms are evident from the low δ¹⁵N values (∼3‰) in mid-section of the core, they did not outnumber the phytoplankton population. Low N/P ratio (∼0) and high TP (100–2,200 mg l⁻¹) support cyanobacterial growth under N limited condition, and insignificant input of macrophytes towards the organic matter pool. Dredging in 1983, caused sub-aerial exposure of the suspended and surface sediments, and affected organic matter preservation in the upper mid-section (12–14 cm) of the core.     

Mudbank regime off the Kerala coast during monsoon and non-monsoon seasons

Field experiments conducted in the nearshore ocean to understand the dynamics of mudbank off Kerala, south-west coast of India, are highlighted. Real time monitoring of the nearshore ocean off Purakkad, Kerala was accomplished using pressure transducers for nearshore surface wave measurements, and current sensors for nearshore velocity measurements. Comprehensive information on the spatial structure of mudbank was obtained from aerial surveys. Extensive data collected on surface waves and currents in the nearshore ocean, indicate that the infra-gravity (IG) waves (leaky modes and trapped edge wave modes), and far infra-gravity (FIG) waves coupled with strong shoreline reflections and undertow play an important role in the dynamics associated with the mudbanks off Kerala during the monsoon season. During the non-monsoon season evidence for progressive edge waves in the infragravity frequency band, an energetic gravity wave band and a strong undertow with weak reflections was observed.     

Behaviour of radiogenic Pb in zircon during ultrahigh-temperature metamorphism: an ion imaging and ion tomography case study from the Kerala Khondalite Belt,southern India

Zircon crystals from a locally charnockitized Paleoproterozoic high-K metagranite from the Kerala Khondalite Belt (KKB) of southern India have been investigated by high-spatial resolution secondary ion mass spectrometry analysis of U–Th–Pb and rare earth elements (REE), together with scanning ion imaging and scanning ion tomography (depth-profiled ion imaging). The spot analyses constrain the magmatic crystallization age of the metagranite to ca. 1,850 Ma, with ultrahigh-temperature (UHT) metamorphism occurring at ca. 570 Ma and superimposed charnockite formation at ca. 520–510 Ma, while the ion imaging reveals a patchy distribution of radiogenic Pb throughout the zircon cores. Middle- to heavy-REE depletion in ca. 570 Ma zircon rims suggests that these grew in equilibrium with garnet and therefore date the UHT metamorphism in the KKB. The maximum apparent ²⁰⁷Pb/²⁰⁶Pb age obtained from the unsupported radiogenic Pb concentrations is also consistent with formation of the Pb patches during this event. The superimposed charnockitization event appears to have caused additional Pb-loss in the cores and recrystallization of the rims. The results of depth-profiling of the scanning ion tomography image stack show that the Pb-rich domains range in size from <5 nm to several 10 nm (diameter if assumed to be spherical). The occurrence of such patchy Pb has previously been documented only from UHT metamorphic zircon, where it likely results from annealing of radiation-damaged zircon. The formation of a discrete, heterogeneously distributed and subsequently immobile Pb phase effectively arrests the normal Pb-loss process seen at lower grades of metamorphism.     

Relative abundance of biotic communities of plankton and zoobenthos in three ox-bow lakes of Eastern India

We made comparative studies of three tropical ox-bow lakes in India with different trophic states. The species number of zooplanktons was negatively correlated with the degree of water eutrophication, and lakes of similar trophic status had higher similarity of species. The most significant differences of species composition were observed with rotifers and zoobenthos. The density and biomass of phytoplankton, rotifers, oligochaetes and chironomids tended to increase with increasing nutrients. We observed a significant difference of dominant species in different waters, especially the eutrophic lake, which was dominated by a few species of oligochaetes. The abundance of Tanypus bilobatus showed a highly significant correlation with the degree of eutrophication. Rotifers and zoobenthos showed considerably lower biodiversity in the eutrophic lake.     

Elevation,slope aspect and integrated nutrient management effects on crop productivity and soil quality in North-west Himalayas,India

On farm bio-resource recycling has been given greater emphasis with the introduction of conservation agriculture specifically withclimate change scenarios in the mid-hills of the north-west Himalaya region（NWHR）. Under this changing scenario, elevation, slope aspect and integrated nutrient management（INM） may affect significantly soil quality and crop productivity. A study was conducted during 2009-2010 to 2010-2011 at the Ashti watershed of NWHR in a rainfed condition to examine the influence of elevation, slope aspect and integrated nutrient management（INM） on soil resource and crop productivity. Two years of farm demonstration trials indicated that crop productivity and soil quality is significantly affected by elevation, slope aspect and INM. Results showed that wheat equivalent yield（WEY） of improved technology increased crop productivity by -20%-37% compared to the conventional system. Intercropping of maize with cowpea and soybean enhanced yield by another 8%-17%. North aspect and higher elevation increased crop productivity by 15%-25% compared to south aspect and low elevation（except paddy）. Intercropping of maize with cowpea and soybean enhanced yield by another 8%-15%. Irrespective of slope, elevation and cropping system, the WEY increased by -30% in this region due to INMtechnology. The influence of elevation, slope aspect and INM significantly affected soil resources（SQI） and soil carbon change（SCC）. SCC is significantly correlated with SQI for conventional（R2 = 0.65＊）, INM technology（R2 = 0.81＊） and for both technologies（R2 = 0.73＊）. It is recommended that at higher elevation.（except for paddy soils） with a north facing slope, INM is recommended for higher crop productivity; conservation of soil resources is recommended for the mid hills of NWHR; and single values of SCC are appropriate as a SQI for this region.     

Assessment of Thermal Maturity,Source Rock Potential and Paleodepositional Environment of the Paleogene Lignites in Barsingsar,Bikaner–Nagaur Basin,Western Rajasthan,India

Natural Resources Research - Investigations on the Paleogene lignites were carried out through geochemical, mineralogical and petrographic analyses to assess their paleodepositional environment,...     

Hidden mass in the solar neighborhood

It is suggested that the minimum mass of a star at the time of its formation is approximately 0.01M . Making use of this fact and the stellar mass functionF(M) M ^–, it is found that the hidden mass (or the missing mass) in the solar neighborhood may be explained by the presence of a large number of invisible stars of very low mass (0.01M M<0.07M ).     

Water Quality,Phytoplankton Diversity and Production in G. B. Pant Sagar at Rihand Dam,Pipri

The man made reservoir, G. B. Pant Sagar at the dam site (24° 15′ N Lat) in the South Mirzapur district of eastern U. P. was investigated in terms of water quality, phytoplankton diversity and production at monthly intervals between January 1987 and December 1987. The reservoir water showed low to moderate dissolved oxygen (4.3 … 7.5 mg/l) and quite low nutrient contents (0.01-0.2 mg l^?1). Phytoplankton diversity narrowly fluctuated (3.17-3.74) and mean annual production (149.7 g/m³ · aC) showed a meso- to eutrophic condition. A significant positive correlation was obtained between gross production and phytoplankton density (r = 0.79; P < 0.001) Multiple regression equation (GPP = 11.292 + 0.043 BAC + 0.075 CHL + 0.073 CYN) indicates that Chlorophyta contributed more to gross production due to the presence of a higher number of individuals.