DNAPL Characterization Methods and Approaches, Part 1: Performance Comparisons

Contamination from the use of chlorinated solvents, often classified as dense nonaqueous phase liquids (DNAPLs) when in an undissolved state, represents an environmental challenge with global implications. Mass-transfer limitations due to rate-limited dissolution can lead to long-term aquifer persistence for even small volumetric fractions. The identification of DNAPL source zones located beneath the water table is critical to ultimately achieve site remediation and aquifer restoration. This paper provides a comparison of the advantages and disadvantages of many of the methods being used for detecting and delineating DNAPL contaminant source zones. The objective is to determine which options are best to pursue based on site characteristics, method performance, and method costs. DNAPL characterization methods are grouped into approaches, which include site preparation, characterization, and data-processing activities necessary to design an effective remediation system. We compare the different approaches based on the level of chemical and hydrogeologic resolution, and the need for additional data requirements. Our findings can be used to assist with selection of appropriate site remediation management options.     

Evolution of disturbed oak woodlands: the case of Mexico City's western forest reserve

Mexico City is the largest city in population and area in the world. In the last 30 years it has expanded its area westwards to include the mountains of the Sierra de las Cruces. These mountains contain the nearest forest reserve for the citizens of Mexico City. Deforestation and severe ecological degradation resulting from the destruction of the natural environment; air, water and soil pollution; and hydrological and geomorphological imbalances, limit the capacity of these areas to support forest regeneration. This study focuses on the geo-ecology of the climax oak woodlands found in the Sierra de las Cruces. Based on morpho-structural evidence, bioclimatic type, degree of human intervention and general geo-ecological considerations, three territorial systems have been differentiated in which the oak woodlands exist in different climax facies: a) oak woodlands developed in very humid and cool environments located on low mountain slopes; b) disturbed oak woodlands developed in humid and cool environments located on high piedmonts; and c) highly disturbed oak woodlands developed in subhumid and temperate environments, located on low piedmonts. A comparative study of the content, structure and functional relationships of the secondary facies associated with these climax communities, allowed conclusions to be drawn on the way oak woodlands respond to human intervention, and the risky situations to which these communities are subjected, particularly the most sensitive facies that deserve immediate protection.     

Vorläufige Mitteilung über einen Meteoritenregen an der Quillagua-Oase,Provinz Antofagasta,Chile

Zusammenfassung Im Rahmen einer weiträumigen geologischen Kartierung für das Instituto de Investigaciones Geológicas wurde 1956 direkt östlich der Oase Quillagua in Nordchile eine sehr auffallende Kratergruppe entdeckt und photogeologisch ausg     

Design and implementation of an image stabilization device at the THEMIS solar telescope

An image stabilizer has been inserted into the optical path of the THEMIS solar telescope. THEMIS is a Ritchey–Chretien reflector telescope using an altazimuthal mount and closely tied to its spectrograph. The optical and mechanical design, implementation and system tests are described, and emphasis is put on the complexity of situations that this stabilizer must accept, including the scanning of the solar surface while stabilizing. The current closed-loop crossover frequency of the device is 65 Hz at ??3 dB on all typical solar scenes.     

Force reduction factors for steel buildings with welded and post-tensioned connections

The seismic responses of steel buildings with perimeter moment resisting frames (MRF) with welded connections (WC) are estimated and compared to those of similar buildings with semi-rigid post-tensioned connections (PC). The responses are estimated in terms of ductility reduction factors (R _µ,), ductility demands (µ _G ) and force reduction factors (R). Two steel model buildings, which were modeled as complex-3D-MDOF systems, were used in the study. Results indicate that the reduction magnitude of global response parameters is larger than that of local response parameters, contradicting the same reduction implicitly assumed in the static equivalent lateral force procedure, implying that non-conservative design may result. The value of 8 for R, suggested in many codes for ductile steel MRF, and the value of 1 suggested in the well known Newmark and Hall procedure for the ratio of R to µ _G , cannot be justified. The reason for this is that SDOF systems were used to model actual structures, where higher mode effects, energy dissipation and structural overstrength weren’t explicitly considered. The codes should be more transparent regarding the magnitude and the components involved in the force reduction factors. The seismic performance of steel buildings with PC may be superior to that of the buildings with WC, since their force reduction factors are larger and their ductility demands smaller, implying that PC buildings could be designed for smaller lateral seismic forces. The conclusions of this paper are for the particular structural systems and models considered. Much more research is needed to reach more general conclusions.     

Magnetic properties and Archeointensity of Earth’s magnetic field recovered from El Opeño,earliest funeral architecture known in Western Mesoamerica

Despite of the impressive cultural heritage and abundant archaeological sites, absolute geomagnetic intensity data from Mesoamerica are still sparse. Archeointensity determinations using the Coe variant of the Thellier and Thellier method have been carried out on some selected pottery fragments from the El Opeño archeological site which has the earliest funeral architecture known in western Mesoamerica. The El Opeño chronology is supported by six C¹⁴ datings performed on carbon-bearing materials. Detailed rock magnetic experiments including susceptibility vs. temperature curves, hysteresis cycles and thermal demagnetization procedures were carried out in order to estimate the magnetic carriers and their stability. Cooling rate and anisotropy remanence corrected intensity values range from 25.0 ± 2.3 to 40.2 ± 3.0 μT and corresponding virtual axial dipole moments (VADM) range from 5.6 ± 0.5 to 8.9 ± 0.7 × 10²² Am². In addition, we present here a new compilation and analysis of existing absolute intensity data in order to try to estimate the variation of the Earth’s magnetic field over the past three millennia. The mean archeointensity obtained in the present study agrees reasonably well with the predicted absolute intensities retrieved from the CALS7K main field model. Other available Mesoamerican data, however, differ from this model. Most of available archeointensity data from Mesoamerica agree reasonably well with the ARCH3K main field model prediction. The broad peak defined at about 50 A.D. by our data is also predicted by the CALS3k.3 main field model but slightly displaced to the right while two smaller peaks are observed on the ARCH3K curve for the same time interval. The intensity value obtained at about 200 B.C. is a clear outlier and thus its geomagnetic significance should be confirmed by further investigations.     

Geochemistry of deep-sea sediments in two cores retrieved at the mouth of the Coatzacoalcos River delta,western Gulf of Mexico,Mexico

Coastal margins, especially the river-influenced coastal areas, are considered as active interfaces between the continental and oceanic environments, which have huge dispersal of detrital materials and heavy metal input. It is well determined that the fine-grained sediments are important reservoir for the accumulation of heavy metals. In this study, we analyzed the radiocarbon age, texture, organic matter, carbonate content, and geochemical compositions of two sediment cores (GM42 and GM44) retrieved in front of the Coatzacoalcos River mouth basin, southwestern Gulf of Mexico (～864 and 845 m water depth, respectively). Our objective was to infer the sedimentation rate, intensity of weathering, provenance, and influence of anthropogenic activities on heavy metal contamination in sediments. The radiocarbon-age measurements of mixed planktonic foraminifera for core GM44 reveals an age of 21,289 ± 136 cal. years B.P., which fall within the Late Glacial Maximum (LGM; 21000 ± 2000 years B.P). The calculated sedimentation rate for core GM42 (~0.013 cm/year) is lower than in core GM44 (0.022 cm/year), which is probably due to the variations in detrital sediment input and/or seafloor topography. The weathering indices such as chemical index of alteration (CIA), chemical index of weathering (CIW), and plagioclase index of alteration (PIA) suggested that the source area experienced low to moderate intensity of chemical weathering under warm to humid climatic conditions. The SiO₂/Al₂O₃, Al₂O₃/Na₂O, and K₂O/Al₂O₃ ratio values indicated moderate to high compositional maturity. The major and trace element concentrations suggested that the sediments were likely derived from intermediate source rocks. The heavy metal contents indicated that the sediments were not contaminated by the industrial waste disposals supplied by the Coatzacoalcos River. The redox proxy sensitive elements such as V, Cr, Cu, and Zn indicated an oxic depositional environment for the deep-sea sediment cores. The application of discrimination diagrams for the geochemistry data revealed a passive margin setting for the sediment cores. The compositional variations observed at the upper sections (<30 cm) between the two sediment cores revealed that the type of detrital sediments supplied by the Coatzacoalcos River to the deep sea area is not uniform, which is also revealed by the variation in sedimentation rate.     

Functional diversity of fish and invertebrates in coral and rocky reefs of the Eastern Tropical Pacific

To define the functional groups of fish and macroinvertebrates in the Eastern Tropical Pacific (ETP), visual censuses were performed in 18 areas of four biogeographic provinces: Cortés, Mexican, Panamic and Oceanic Islands. A total of 257 fish and macroinvertebrate species were recorded, and from them, 27 morpho‐functional groups (MFGs) were constructed on the basis of trophic level, maximum size, taxonomy and morphology. Biomass, richness, diversity and evenness of MFGs were calculated for each province and compared statistically; a regression analysis between taxonomic and functional diversity was conducted to observe the relationship between these two indicators. There were significant differences in all ecological indices (p < .002), highlighting the high biomass and richness of MFGs in the Cortés and Oceanic Islands provinces (>400 g/m²), associated with the influence of cold currents in the northernmost region and less fishing pressure in protected areas. A decreasing pattern of MFG richness towards the tropics was observed, which demonstrates that in the ETP, the relationship between habitat heterogeneity and species diversity has been translated into functional complexity. The Mexican province was the most functionally diverse (biomass well distributed in the MFG; H′ = 0.46 ± 0.009). Related to this, it is predicted that biomass is biased towards certain functional groups (i.e., large carnivores), which shows that the H′ index of the MFG is not a good indicator of the conservation status of ETP reefs. Finally, regression analysis suggests that functional diversity increases at low species diversity but eventually reaches an asymptote (almost all possible functions are represented).