An improved approach for assigning pumping rates to heterogeneous aquifer models

A common assumption of ground water models formulated using a block-centered finite-difference method is that a well is located at the center of a cell regardless of its actual location. Due to this assumption, errors are introduced in the spatial distribution of simulated heads. This paper presents an alternative approach for assigning the pumping rates of wells that are located off cell centers. This approach consists of assigning the pumping rate not only to the cell in which the well is located but also to adjacent cells, taking into account the length of the well screen, the hydraulic conductivity, and the distance from the well to the center of its cell. The advantage of this alternative approach over the conventional one is illustrated with a test problem of a synthetic aquifer. Statistical measures of error indicate a much better model fit when pumping rates of wells are distributed over several cells.     

The climatology of tornadoes and waterspouts in Italy

In this work 10 years of reports collected by weather amateurs are used to define a preliminary climatology of tornadoes and waterspouts in Italy. The results show behaviors different from those observed in other countries. Generally, tornadoes and waterspouts are more frequent in late summer and autumn than in the other seasons. The seasonality of tornadoes and waterspouts appears different for different Italian zones, in particular in the Po Valley and Friulian plain and coast (south to the Alps) tornadoes and waterspouts are more frequent in spring and early summer while in the Tirrenian and Ionian coasts (western and southern Italy), tornadoes and waterspouts are more frequent in late summer and autumn. As observed in other studies (Brooks, H., E. and Doswell, C. A. III, 2001. Some aspects of the international climatology of tornadoes by damage classification. Atmos. Res., 56, 191–201.) Italian tornadoes and waterspouts are statistically weaker than in other countries but this difference cannot be completely ascribed to the presence of waterspouts. The “CAPE Storm-Relative-Helicity diagrams” and “Shear Magnitude diagrams” obtained for Italian tornadoes and waterspouts show different characteristics than those obtained for US. The cause of these differences is still unknown, it can rely in the sample selection (problems with the concept of proximity sounding) or in a real climatic effect.     

Structure of the rift basins in the central Gulf of California: Kinematic implications for oblique rifting

We use structural and seismostratigraphic interpretation of multichannel seismic reflection data to understand the structure and kinematic history of the central Gulf of California. Our analysis reveals that oblique strain in the central Gulf formed two tectono–sedimentary domains during distinct deformation stages. The eastern domain, offshore Sonora, is bounded by the East and West Pedro Nolasco faults that may constitute the southernmost segments of the Tiburón Fault System. Within this domain, the dip-slip Yaqui Fault controlled deposition of 3.9 km of sediments in the half-graben Yaqui Basin. The western domain, offshore Baja California, is bounded by the Guaymas Transform Fault, which controlled the accumulation of 1.45 km of sediments within a half-graben that formed the early Guaymas Basin. The tectono–sedimentary activity offshore Sonoran likely ranges from Late Miocene–Pliocene to Late Pliocene time, while activity in the Guaymas Basin commenced in Late Pliocene time. Extinction of the main faults offshore Sonora was nearly coeval to the initiation of the Guaymas Transform Fault. Our results suggest that oblique strain has been accommodated by strain partition since the onset of rifting in the central Gulf. The Guaymas Basin is now a nascent spreading center, but prior to this, it evolved as a half-graben controlled by the Guaymas Transform Fault; such drastic transition is not constrained, but likely occurred during the Pleistocene time and must be localized < 30 km north of the axial troughs. The faults within the central Gulf transpose the Miocene N–S oriented grabens of Basin and Range style preserved onshore in the conjugate rifted margins.     

Changes in the Wetlands of Andalusia (Doñana Natural Park, SW Spain) at the End of the Little Ice Age

The Little Ice Age is a climatic period still insufficiently known. This ignorance is more marked in the case of Andalusia (southern Spain), where only recent works throw any light on the topic. Our studies, primarily from the perspective of botany and changes in the plant landscape, reveal the effects that this period had in these latitudes, and in particular on the Doñana Natural Park (SW Spain). This work shows an aridization in climatic conditions coinciding with the end of the Little Ice Age. The results corroborate the most recent theses on this period in Spain. Furthermore, the effects on the marsh areas studied lead us to conclude that the interpretation of the Little Ice Age in these southern latitudes should be different to that normally given for more northerly latitudes – much better known and more studied than the Mediterranean regions.     

Hydrolysis of neptunium(V) at variable temperatures (10-85°C)

Neptunium is one of the few radioactive elements that are of great concern in the disposal of nuclear wastes in the geological repository, due to its hazards and the long half-life of the isotope, ²³⁷Np (t_1/2 = 2.14 × 10⁶ years). To understand and predict the migration behavior of neptunium in the geological media, it is of importance to study its hydrolysis at elevated temperatures, because the temperature in the waste package and the vicinity of the repository could be high. Moreover, the chemical analogy between neptunium(V) and plutonium(V) adds even greater value to this investigation, because the latter could exist at tracer levels in neutral and slightly oxidizing waters but is difficult to study due to its rather labile redox behavior.In this work, the hydrolysis of neptunium(V) was studied at variable temperatures (10 to 85°C) in tetramethylammonium chloride (1.12 mol kg⁻¹). Two hydrolyzed species of neptunium(V), NpO₂OH(aq) and NpO₂(OH)₂⁻, were identified by potentiometry and Near-IR absorption spectroscopy. The hydrolysis constants (*β_n) and enthalpy of hydrolysis (ΔH_n) for the reaction NpO₂⁺ + nH₂O = NpO₂(OH)_n⁽¹⁻ⁿ⁾⁺ + nH⁺ (n = 1 and 2) were determined by titration potentiometry and microcalorimetry. The hydrolysis constants, *β₁ and *β₂, increased by 0.8 and 3.4 orders of magnitude, respectively, as the temperature was increased from 10 to 85°C. The enhancement of hydrolysis at elevated temperatures is mainly due to the significant increase of the degree of ionization of water as the temperature is increased. The hydrolysis reactions are endothermic but become less endothermic as the temperature is increased. The heat capacities of hydrolysis, ΔC_p1 and ΔC_p2, are calculated to be −(71 ± 17) J K⁻¹ mol⁻¹ and −(127 ± 17) J K⁻¹ mol⁻¹, respectively. Approximation approaches to predict the effect of temperature, including the constant enthalpy approach, the constant heat capacity approach and the DQUANT equation, have been tested with the data.     

Spectral Characteristics of the He <Emphasis Type="SmallCaps">i</Emphasis> D<Subscript>3</Subscript> Line in a Quiescent Prominence Observed by THEMIS

We analyze the observations of a quiescent prominence acquired by the Téléscope Heliographique pour l’Étude du Magnetisme et des Instabilités Solaires (THEMIS) in the He?i 5876 Å (He?i D₃) multiplet aiming to measure the spectral characteristics of the He?i D₃ profiles and to find for them an adequate fitting model. The component characteristics of the He?i D₃ Stokes I profiles are measured by the fitting system by approximating them with a double Gaussian. This model yields an He?i D₃ component peak intensity ratio of \(5.5\pm0.4\), which differs from the value of 8 expected in the optically thin limit. Most of the measured Doppler velocities lie in the interval ±?5 km?s^?1, with a standard deviation of ±?1.7 km?s^?1 around the peak value of 0.4 km?s^?1. The wide distribution of the full-width at half maximum has two maxima at 0.25 Å and 0.30 Å for the He?i D₃ blue component and two maxima at 0.22 Å and 0.31 Å for the red component. The width ratio of the components is \(1.04\pm0.18\). We show that the double-Gaussian model systematically underestimates the blue wing intensities. To solve this problem, we invoke a two-temperature multi-Gaussian model, consisting of two double-Gaussians, which provides a better representation of He?i D₃ that is free of the wing intensity deficit. This model suggests temperatures of 11.5 kK and 91 kK, respectively, for the cool and the hot component of the target prominence. The cool and hot components of a typical He?i D₃ profile have component peak intensity ratios of 6.6 and 8, implying a prominence geometrical width of 17 Mm and an optical thickness of 0.3 for the cool component, while the optical thickness of the hot component is negligible. These prominence parameters seem to be realistic, suggesting the physical adequacy of the multi-Gaussian model with important implications for interpreting He?i D₃ spectropolarimetry by current inversion codes.