Comparison of the quantitative determination of soil organic carbon in coastal wetlands containing reduced forms of Fe and S

The performance of the Walkley–Black wet oxidation chemical method for soil organic carbon (SOC) determination in coastal wetland soils (mangroves, coastal lagoons, and hypersaline tidal flats) was evaluated in the state of Ceará along the semiarid coast of Brazil, assessing pyrite oxidation and its effects on soil C stock (SCS) quantification. SOC determined by the chemical oxidation method (C_WB) was compared to that assessed by means of a standard elemental analyzer (C_EA) for surficial samples (<30 cm depth) from the three wetland settings. The pyrite fraction was quantified in various steps of the chemical oxidation method, evaluating the effects of pyrite oxidation. Regardless of the method used, and consistent with site-specific physicochemical conditions, higher pyrite and SOC contents were recorded in the mangroves, whereas lower values were found in the other settings. C_WB values were higher than C_EA values. Significant differences in SCS calculations based on C_WB and C_EA were recorded for the coastal lagoons and hypersaline tidal flats. Nevertheless, the C_WB and C_EA values were strongly correlated, indicating that the wet oxidation chemical method can be used in such settings. In contrast, the absence of correlation for the mangroves provides evidence of the inadequacy of this method for these soils. Air drying and oxidation decrease the pyrite content, with larger effects rooted in oxidation. Thus, the wet oxidation chemical method is not recommended for mangrove soils, but seems appropriate for SOC/SCS quantification in hypersaline tidal flat and coastal lagoon soils characterized by lower pyrite contents.     

Stable sulfur and oxygen isotope ratios of the Świętokrzyski National Park spring waters generated by natural and anthropogenic factors (south-central Poland)

This paper presents the results of an isotopic study of spring waters in ?wi?tokrzyski (Holy Cross Mountain) National Park (?NP), south-central Poland. The δ³⁴S_V-CDT and δ¹⁸O_V-SMOW of soluble sulfates (n = 40) varied from 0.5‰ to 18.1‰ and from 3.5‰ to 12.2‰, respectively. The average δ³⁴S values are closely similar to those of rainwater, soils and rocks (comprising scattered pyrite). This suggests that soluble sulfates in the springs originated from mixing of recent and historic deposition, sulfates derived from pyrite oxidation, and CS-mineralization in soils and debris. An additional anthropogenic sulfur input (inorganic fertilizer) occurs in the water of spring S-61 located in the ?wi?tokrzyski National Park buffer zone. The δ¹⁸O_V-SMOW of spring waters (n = 4) were in the range of −10.6‰ to −10.2‰ indicating that they are derived from vadose groundwater in ?NP. This was the first isotope study of spring waters in the national parks of Poland. It enabled the determination of sulfur pathways and discrimination between natural and anthropogenic sources of this element in a relatively pristine area.     

Adsorption of Sr and Ba at the cleaved mica-water interface: Free energy profiles and interfacial structure

Monte Carlo simulations show that the adsorption position of the Sr²⁺ or Ba²⁺ ion on the cleaved muscovite surface is determined by the radius of the ion’s first hydration shell, hydrogen bonding of the first shell water molecules with the basal oxygens of muscovite as well as a requirement of minimization of the number of muscovite’s lattice cations in the ion’s first coordination shell. Accordingly, Sr²⁺ or Ba²⁺ adsorbs in ditrigonal cavities at a distance of 1.12 Å or 1.35 Å, respectively, from the basal surface on dehydrated mica and above tetrahedral substitutions at a height of 1.93 ± 0.02 Å or 2.15 ± 0.03 Å, respectively, at the highest simulated water coverage of 28 H₂O per ion. The ion’s displacement from a ditrigonal cavity occurs upon adsorption of 2 H₂O per ion for Sr²⁺ and 3 H₂O per ion for Ba²⁺. At a coverage of 28 H₂O per ion, outer-sphere adsorption of Sr²⁺ or Ba²⁺ at a height of 3.9 ± 0.2 Å or 4.17 ± 0.07 Å, respectively, is possible albeit unfavorable on the free energy scale by 107 ± 7 kJ/mol or 89 ± 13 kJ/mol, respectively, as compared to inner-sphere adsorption. Activation energies for the transformation between inner-sphere and outer-sphere adsorptions are calculated to be 121 ± 3 kJ/mol for Sr²⁺ and 99 ± 10 kJ/mol for Ba²⁺. A comparison of these values with those reported recently for Mg²⁺ and Ca²⁺ results in an adsorption affinity sequence Mg²⁺ > Ca²⁺ > Sr²⁺ > Ba²⁺ in agreement with the sequence predicted recently for low dielectric constant solids (which include mica) (Sverjensky, 2006). A recent resonant anomalous X-ray reflectivity study of Sr²⁺ adsorption on muscovite (Park et al., 2006) has questioned the common assumption (Stumm, 1992), which is supported by the present simulation results, that inner-sphere adsorption is stronger than outer-sphere adsorption. A modification of the cleaved muscovite surface as a result of Sr²⁺ adsorption in muscovite’s ditrigonal cavities and related destabilization of muscovite’s hydroxyl groups is proposed as a possible reason for this controversy.     

‘Human-dolphin (Tursiops truncatus Montagu, 1821) cooperative fishery’ and its influence on cast net fishing activities in Barra de Imbé/Tramandaí, Southern Brazil

‘Human-dolphin (Tursiops truncatus Montagu, 1821) cooperative fishery’ and its influence on cast net fishing activities in Barra de Imbé/Tramandaí, Southern Brazil - aims to describe ‘fishing with dolphins’ or ‘botos’ (Tursiops truncatus Montagu, 1821), its importance in mullet fishing in conjunction with the traditional knowledge of artisanal fishermen, and the negative economic impact that tourism has had on mullet fishing in Barra de Imbé/Tramandaí (29°58′S 50°07′W). In November and December of 2009, 22 artisanal fishermen associated with the Tramandaí Fishermen’s Union were interviewed. During these interviews, questionnaires were employed utilizing both open and closed questions that dealt with behavioral ecology, biological and interactional issues related to bottlenose dolphins, and small-scale fishing in the region. All those interviewed described “boto fishing,” in which bottlenose dolphins “helped out the fishermen.” According to these interviews, this kind of fishing, marked by close interaction between humans and ‘botos,’ allows nets to be cast fewer times and with captured fish yields that are greater than, when there is no dolphin is present. The fishermen maintain that this increased productivity results from ‘botos’ showing them exactly where the schools of fish are located below the water surface. This has made it possible to observe the impact that dolphin fishing has on the monthly incomes of these fishermen, and there is concern among fishermen, that the intense tourism may one day contribute to the disappearance of the ‘boto,’ a situation, they believe would negatively affect their fishing activities.     

Ceilometer observations of the boundary layer over Warsaw,Poland

Jenoptik’s CHM 15k ceilometer was used to monitor the vertical structure of the atmospheric boundary layer (ABL) over Warsaw, from 2008 until 2011, on Mondays and Thursdays, in 24h periods. Hereby, we present an assessment of the signal-to-noise ratio along with a sensitivity study of signal smoothing methods developed in-house. With the proposed averaging, ceilometer attenuated-backscatter signals reached the high troposphere, which makes this sensor competitive to a single-wavelength elastic lidar. The smoothed signals were employed as an input for algorithms developed to automatically detect the ABL height, clouds, fog, and precipitation in the lower troposphere. The classification of weather conditions was validated by the METAR reports from the Warsaw Airport. The obtained ABL heights were compared to those assessed from radio-soundings from a nearby meteorological station WMO12374 in Legionowo. An inter-comparison of the ABL heights, derived by using the Jenoptik’s automated routine against the in-house developed algorithms, is in favor of the latter. The presented four annual cycles of the ABL height, obtained with various derivative-based methods, are the first such long-term results reported using the CHM 15k sensor in Eastern Europe.     

The Late Vistulian and Holocene evolution of Jezioro Lake: a record of environmental change in southern Poland found in deposits and landforms

Jezioro Lake is the only natural lake in southern Poland outside mountainous areas to have existed continuously since the Pleistocene. The record of environmental change in the Late Vistulian (Weichselian) and Holocene is preserved in the deposits and landforms around the lake. This paper presents the results of paleogeographical and paleoecological research that emabled us to reconstruct the history of the Jezioro Lake. At the end of the Vistulian period, the outlet of the lake was blocked by a parabolic dune moving in from the west. Limnic sedimentation was evident in the sediment core at all levels from the Holocene, with remains of Cladocera, Chironomidae larvae, and aquatic plants. The lake did not disappear at that time, although its area decreased by a factor of 12 by the end of the period. Paleobotanical research permitted the reconstruction of sequences of plant communities and changes in nutrient status and water level. An initial oligotrophic lake, as indicated by the presence of Iso?tes lacustris L., changed to a eutrophic lake, as indicated by the presence of Potamogeton natans L. and Nuphar sp., then the lake progressed to the present-day dystrophic lake that is surrounded by a swamp. The profile of organic deposits contains a record of environmental change at least since the Younger Dryas in southern Poland.     

Chemical and isotopic variations in the Wiśniówka Mała mine pit water,Holy Cross Mountains (south-central Poland)

In 2005 and 2006, hydrogeochemical study was carried out in the bipartite Wiśniówka Mała pit lake of the Holy Cross Mountains (south-central Poland). This is the largest acidic water body in Poland. This report presents the element concentrations in the water and sediment, stable sulfur and oxygen isotope ratios in the soluble sulfates, and stable oxygen isotope ratio in the water. The scope of the investigation also encompassed mineralogical examinations (scanning electron microscope, X-ray diffraction) of the sediment. The results of this study show that there is a spatial and temporal variability in concentrations of most elements and sulfur isotope ratios in the examined pit lake. The water of the western pond displayed a lower pH with a mean of 3.73 and higher conductivity (390 μS cm⁻¹) as well as higher concentrations of sulfates (156 mg L⁻¹) and most of the cations and anions. The concentrations of Fe²⁺ and Fe³⁺ averaged 0.8 and 0.4 mg·L⁻¹. In contrast, the eastern pond water revealed a higher pH (mean of 4.36), lower conductivity (293 μS cm⁻¹) and lower sulfate (90 mg L⁻¹) and trace metal levels. Similar variations were recorded in the stable sulfur isotope ratios. The δ³⁴S_V-CDT(SO₄ ²⁻) values in the water of the western pit pond were in the range of −6.7 to −4.6‰ (mean of −5.6‰), whereas that in the eastern pit pond ranged from −2.2 to −0.9‰ (−1.6‰). The alkalinity of the entire lake water was below 0.1 mg·L⁻¹ CaCO₃. No distinct difference in the δ¹⁸O_V-SMOW(SO₄ ²⁻) was noted between the western and eastern pit ponds. Compared to the Purple Pond in the Sudetes (Poland) and similar sites throughout the world, the examined pit lake is highlighted by distinctly low concentrations of sulfates, iron and other trace metals. Based on this and other studies performed in the Holy Cross Mountains, a conclusion can be drawn that the SO₄ ²⁻ in the Wiśniówka Mała pit lake water is a mixture of SO₄ ²⁻ derived from the following sources: (1) pyrite oxidation (especially in the western pond water), (2) leaching of soluble sulfates from soils and waste material, as well as (3) subordinate deposition of airborne sulfate precipitation.     

Base isolation for retrofitting historic buildings: Evaluation of seismic performance through experimental investigation

An experimental test program on a full‐scale model representing a sub‐assemblage of the cloister facade of the Sao Vicente de Fora monastery, retrofitted through base isolation, has been recently carried out at the European Laboratory for Structural Assessment of the Joint Research Centre of the European Commission. In this paper an overview of the laboratory model and the experimental results is provided. In particular, firstly the test model is described, including the geometry and mechanical properties of the masonry specimen and the design of the isolation devices; then the testing method and the sub‐structuring of the isolation system are described and the seismic inputs adopted for the pseudo‐dynamic tests are defined. Finally, the experimental results are discussed and compared to the analogous results obtained on the ‘as is’, fixed‐base sub‐assemblage model. The implications of the test outcomes are emphasized and developments of this research line are presented. Copyright © 2001 John Wiley & Sons, Ltd.