Geochemical and hydrologic controls on the mobilization of arsenic derived from herbicide application

The fate and transport of As was examined at an industrial site where soil- and groundwater contamination are derived from the application of As₂O₃ as a herbicide. Application of arsenical herbicides was discontinued in the 1970s and soils in the source area were partially excavated in 2003. Arsenic contamination (up to 280 mg/kg) remains in the source area soils and a plume of As-contaminated groundwater persists in the surficial aquifer downgradient of the source area with maximum observed As concentrations of 1200 μg/L near the source area. The spatial extent of As contamination as defined by the 10 μg/L contour appears to have remained relatively stable over the period 1996–2006; the boundary of the 1000 μg/L contour has retreated over the same time period indicating a decrease in total As mass in the surficial groundwater.In column experiments conducted with source area soil, the As concentrations in the column effluent were comparable to those observed in groundwater near the source area. A substantial fraction of the As could be leached from the source area soil with ammonium sulfate and ammonium phosphate. Exhaustive extraction with background groundwater removed most of the total As. These results indicate that As in the source area soils is geochemically labile. Source area soils are low in extractable Fe, Mn and Al, and characterization by X-ray absorption spectroscopy and electron microscopy indicated that As is present primarily as arsenate sorbed to (alumino)silicate minerals. Batch sorption experiments showed much less sorption on surficial aquifer sediments than on sediments from the Jackson Bluff Formation (JBF), a presumed confining layer. This limited capacity of the surficial aquifer sediments for As sorption is consistent with the similar As contents observed for these sediments within and upgradient of the As plume. The apparent stability of the As plume cannot be explained by sequestration of As within the surficial aquifer. Sorption to JBF sediments may contribute to As sequestration, but As enrichment in JBF sediments within the plume (i.e., as compared with JBF sediments upgradient) was not observed. These results indicate that neither the persistence of As in the source area soils or the apparent stability of the plume of As-contaminated groundwater at this site can be explained by geochemical controls on As mobility. The absence of demonstrable geochemical bases for such observations suggests that possible hydrologic controls should be further investigated at this site.     

Measurement of SIMS Instrumental Mass Fractionation of Pb Isotopes During Zircon Dating

An igneous zircon reference material (OG1) was characterised for U-Pb isotopes by ID-TIMS, and utilised to evaluate SIMS (SHRIMP) instrumental mass fractionation (IMF) of radiogenic Pb isotopes (²⁰⁷Pb*/²⁰⁶Pb*). The TIMS ²⁰⁷Pb*/²⁰⁶Pb* reference value for OG1 was 0.29907 ± 0.00011 (95% confidence limit), 3465.4 ± 0.6 Ma. The high ²⁰⁷Pb* (∼ 30 μg g⁻¹), negligible common Pb, and isotopic homogeneity permitted precise (± 1–2‰) ²⁰⁷Pb*/²⁰⁶Pb* measurements within the analytical sessions. External reproducibility of mean ²⁰⁷Pb*/²⁰⁶Pb* ratios between sessions was demonstrated for one instrument, yielding a mean IMF of +0.87 ± 0.49‰. The mean ²⁰⁷Pb*/²⁰⁶Pb* ratios between instruments were dispersed beyond uncertainties, with session IMF values from +3.6 ± 1.7‰ to −2.4 ± 1.3‰, and a grand mean IMF value (twenty-six sessions) of +0.70 ± 0.52‰, indicating a tendency towards elevated ²⁰⁷Pb*/²⁰⁶Pb*. The specific causes of variability in IMF are unclear, but generally reflect subtle differences in analytical conditions. The common practice in SIMS of assuming that IMF for Pb⁺ is insignificant could result in systematic age biases and underestimated uncertainties, of critical importance for precise correlation of Precambrian events. Nevertheless, a zircon RM such as OG1 can be readily incorporated into routine dating to improve ²⁰⁷Pb*/²⁰⁶Pb* accuracy and external reproducibility.     

Extensional Structures in the Ophiolites from Cuba and China: New Constraints to Slowly‐Spreading Ancient Oceanic Lithosphere

A group of low‐angle normal faults developed in banded gabbro of Moa Ophiolite, Cuba. The dark gabbro was cut into puddings by several normal faults, while light gabbro was just swelling in layer thickness. In Hongliuhe ophiolite at eastern segment of South Tien Shan Suture Zone in China, the extensional deformation concentrates on fine cumulus gabbro which is typically mylonitized. Abundant structural features were discovered in HLH ophiolite such as S‐C foliation, C’ foliation, extensional crenulation cleavage, small toughness normal fault, low‐angle normal faults and high‐angle normal faults. According to the above tectonic phenomenon from the ophiolite belts in Cuba and China, we will get the conclusion: the maximum principal compressive stress (b1) is vertical to cumulus bedding, and the maximum tensile stress (b3) is paralleling to cumulus bedding. Considering of the above evidence, the extensional tectonic event should developed at mid‐ocean ridge. Due to seafloor spreading, the maximum tensile stress is paralleling to cumulus layer, and extensional tectonic is kept in cumulus gabbro. In this way, normal faults developed in dark gabbro, while brittle‐ductile extensional developed in light gabbro. A large number of domes, folds paralleling to ocean ridge and detachment faults represented by low angle normal fault were discovered near ocean ridge in Indian Ocean and Atlantic Ocean. In this way, materials from deep oceanic lithosphere (e.g. gabbro, mantle peridotite) outcrop at the crust surface of ocean basin. The above evidences from China and Cuba are consistent with extensional tectonic and metamorphic core complex from slowly and super‐slowly spreading Indian Ocean and Atlantic Oceanic lithosphere based on ODP. Therefore, extensional deformation in the ophiolite belt is of significant meaning for clarifying the formation process and mechanism of ancient oceanic basin.     

Modelling the effects of changes in the Earth's magnetic field from 1957 to 1997 on the ionospheric hmF2 and foF2 parameters

We have modelled the effects of changes in the Earth's magnetic field on the ionosphere as have occurred from 1957 to 1997 using the NCAR Thermosphere–Ionosphere–Electrodynamics General Circulation Model. Previous studies that attempted to quantify these effects used a constant wind field, so that any electro-dynamical coupling processes could not be accounted for. Using TIE-GCM we can account for these processes. We find substantial changes in the F2 layer peak height hmF2 (up to ±20 km) and critical frequency foF2 (up to ±0.5 MHz) over the Atlantic Ocean and South America, purely due to changes in the Earth's magnetic field (i.e. unrelated to greenhouse gas cooling effects, which are often held responsible for long-term trends in hmf2 and fof2). These would make up a significant contribution to observed long-term trends in these areas and therefore must be taken into account in their interpretation. Modelled trends of hmF2 and foF2 exhibit a strong seasonal and diurnal variation, highlighting the importance of separating data with respect to season and local time. Most of the modelled changes in hmF2 and foF2 can be related to changes in plasma transport up or down magnetic field lines driven by neutral winds, changes, which are mostly caused by changes in the inclination of the field, though changes in declination and neutral wind also play a role. Changes in the vertical component of the E×B drift seem to have little effect on hmF2 and foF2.     

Riverine input and air–sea CO2 exchanges near the Changjiang (Yangtze River) Estuary: Status quo and implication on possible future changes in metabolic status

Due to anthropogenic activities, the nutrient loadings of the Changjiang (Yangtze River) are strickly on the rise. The high nutrient concentrations notwithstanding, river water was pCO₂ supersaturated in the inner estuary during summer 2003 but decreased quickly in the mid-estuary due to mixing with low pCO₂ waters from offshore. In addition, settling of particles in the estuary resulted in better light conditions so that phytoplankton bloomed, driving down pCO₂ to ∼200 μatm. In the outer estuary and outside of the bloom area, pCO₂ increased again to near or just below saturation. Literature data also reveal that the mainstream of the Changjiang is always supersaturated with respect to CO₂ probably because the decomposition of terrestrial organic matter overwhelms the consumption of CO₂ due to biological production.     

Effects of quasar feedback in galaxy groups

We study the effect of quasar feedback on distributions of baryons in galaxy groups using high-resolution numerical simulations. We use the entropy-conserving gadget code that includes gas cooling and star formation, modified to include a physically based model of quasar feedback. For a sample of 10 galaxy group-sized dark matter haloes with masses in the range of  1–5 × 10¹³ M_⊙  h ⁻¹  , star formation is suppressed by more than 50 per cent in the inner regions due to the additional pressure support by quasar feedback, while gas is driven from the inner region towards the outer region of the haloes. As a result, the average gas density is 50 per cent lower in the inner region and 10 per cent higher in the outer region in the simulation, compared to a similar simulation with no quasar feedback. Gas pressure is also higher in the outer region, while temperature and entropy are enhanced in the inner region. The total group gas fraction in the two simulations generally differs by less than 10 per cent. We also find a small change of the total thermal Sunyaev–Zeldovich distortion, leading to 10 per cent changes in the microwave angular power spectrum at angular scales below 2 arcmin.     

Performance characteristics of a new electronic snow water equivalent sensor in different climates

The US Army ERDC CRREL and the US Department of Agriculture Natural Resources Conservation Service developed a square electronic snow water equivalent (e‐SWE) sensor as an alternative to using fluid‐filled snow pillows to measure SWE. The sensors consist of a centre panel to measure SWE and eight outer panels to buffer edge stress concentrations. Seven 3 m square e‐SWE sensors were installed in five different climate zones. During the 2011–2012 winter, 1.8 and 1.2 m square e‐SWE sensors were installed and operated in Oregon. With the exception of New York State and Newfoundland, the e‐SWE sensors accurately measured SWE, with R² values between the sensor and manual SWE measurements of between 0.86 and 0.98. The e‐SWE sensor at Hogg Pass, Oregon, accurately measured SWE during the past 8 years of operations. In the thin, icy snow of New York during midwinter 2008–2009, the e‐SWE sensors overmeasured SWE because of edge stress concentrations associated with strong icy layers and a shallow snow cover. The New York e‐SWE sensors' measurement accuracy improved in spring 2009 and further improved during the 2011–2012 winter with operating experience. At Santiam Junction, measured SWE from the 1.8 and 1.2 m square e‐SWE sensors agreed well with the snow pillow, 3 m square e‐SWE sensor, and manual SWE measurements until February 2013, when dust and gravel blew onto the testing area resulting in anomalous measurements. © 2014 The Authors. Hydrological Processes published by John Wiley & Sons Ltd.     

The effects of sample scheduling and sample numbers on estimates of the annual fluxes of suspended sediment in fluvial systems

Since the 1970s, there has been both continuing and growing interest in developing accurate estimates of the annual fluvial transport (fluxes and loads) of suspended sediment and sediment‐associated chemical constituents. This study provides an evaluation of the effects of manual sample numbers (from 4 to 12 year^?1) and sample scheduling (random‐based, calendar‐based and hydrology‐based) on the precision, bias and accuracy of annual suspended sediment flux estimates. The evaluation is based on data from selected US Geological Survey daily suspended sediment stations in the USA and covers basins ranging in area from just over 900 km² to nearly 2 million km² and annual suspended sediment fluxes ranging from about 4 Kt year^?1 to about 200 Mt year^?1. The results appear to indicate that there is a scale effect for random‐based and calendar‐based sampling schemes, with larger sample numbers required as basin size decreases. All the sampling schemes evaluated display some level of positive (overestimates) or negative (underestimates) bias. The study further indicates that hydrology‐based sampling schemes are likely to generate the most accurate annual suspended sediment flux estimates with the fewest number of samples, regardless of basin size. This type of scheme seems most appropriate when the determination of suspended sediment concentrations, sediment‐associated chemical concentrations, annual suspended sediment and annual suspended sediment‐associated chemical fluxes only represent a few of the parameters of interest in multidisciplinary, multiparameter monitoring programmes. The results are just as applicable to the calibration of autosamplers/suspended sediment surrogates currently used to measure/estimate suspended sediment concentrations and ultimately, annual suspended sediment fluxes, because manual samples are required to adjust the sample data/measurements generated by these techniques so that they provide depth‐integrated and cross‐sectionally representative data. Published 2014. This article is a U.S. Government work and is in the public domain in the USA.