Oxygen-isotope systematics of a strongly recrystallized granitic rock complex,Grenvillian Belt,SW Sweden

In the eastern, external part of the Grenvillian Belt in SW Sweden, five formations of granitic rocks were found in the basement of the Dalslandian Supracrustal Group. The granitic rocks have been strongly recrystallized but have preserved most of their granitic texture in the process. Most magmatic crystals have been pseudomorphed by metamorphic minerals: quartz, albite, chlorite, biotite, white mica, epidote, titanite, hematite, pyrite and carbonate. Two of the formations have subsequently been affected by a cataclastic deformation and at present consist of mylogneisses. ¹⁸O whole-rock values for the granitic rocks vary from +3.0 to +11.1. Quartz-apatite, quartz-zircon and quartz-titanite pairs show ¹⁸O/¹⁶O fractionations corresponding to equilibrium temperatures of 550–700° C, which are believed to reflect in the main continued closed-system isotopic exchange at high temperatures following solidification. In contrast highly positive ¹⁸O/¹⁶O fractionations for quartz-K-feldspar, quartz-biotite, quartz-chlorite and quartz-sericite pairs in some granitic samples indicate that these rocks have exchanged oxygen with heated, meteoric, H₂O dominated fluids. Other granitic samples, however, show virtually undisturbed magmatic ¹⁸O/¹⁶O fractionation values for the same mineral pairs, even though these rocks are equally altered.It is concluded that all granitic rock units recrystallized under greenschist facies conditions during the infiltration of fluids under the influence of hydrothermal convection systems set up by the intrusion of the granitic plutons. The fluids probably had a range of ¹⁸O values from ca. -14 to ca. +10, indicating the mixing of distinct fluid reservoirs, one of meteoric origin and the others of magmatic and/or metamorphic origin. The temperature of alteration is estimated at 450–500° C.Estimation of pre-alteration ¹⁸O whole rock values for the five granitic units suggests that three units should be assigned a dominantly S-type origin, where as the other two units may partly or wholly have an I-type origin.     

Cyclic terpenoids of contemporary resinous plant detritus and of fossil woods, ambers and coals

Cyclic terpenoids present in the solvent extractable material of fossil woods, ambers and brown coals have been analyzed. The sample series chosen consisted of wood remains preserved in Holocene to Jurassic sediments and a set of of ambers from the Philippines (copalite), Israel, Canada and Dominican Republic. The brown coals selected were from the Fortuna Garsdorf Mine and Miocene formations on Fiji.The fossil wood extracts contained dominant diterpenoid or sesquiterpenoid skeletons, and aromatized species were present at high concentrations, with a major amount of two-ring aromatic compounds. Tricyclic diterpenoids were the predominant compounds in the ambers. Aromatized derivatives were the major components, consisting of one or two aromatic ring species with the abietane and occasionally pimarane skeletons. The saturated structures were comprised primarily of the abietane and pimarane skeletons having from three to five carbon (C₁, C₂, etc.) substituents. Kaurane and phyllocladane isomers were present in only minor amounts. Bicyclic sesquiterpenoids as saturated and partial or fully aromatized forms were also common in these samples, but only traces of sesterterpenoids and triterpenoid derivatives were found.The brown coal extracts were composed of major amounts of one- and two-ring aromatized terpenoids, with a greater proportion of triterpenoid derivatives than in the case of the woods and ambers. This was especially noticeable for the German coal, where the triterpenoids were predominant. Open C-ring aromatized structures were also present in this coal. Steroid compounds were not detectable, but some hopanes were found as minor components in the German brown coal.An overview of the skeletal structure classes identified in each sample, as well as the general mass spectrometric characteristics of the unknown compounds are included in the present paper. It can be concluded from these structural distributions that aromatization is the main process for the transformation of terrestrial cyclic terpenoids during diagenesis, constituting a general pathway for all terpenoids.     

Radiochemical Determination of Gold in Rocks

A method developed for radiochemical determination of gold in rock samples has been applied to six Bulgarian, four ZGI (GDR) and one USGS geostandards. The method is based on acid dissolution of the sample, followed by extraction of gold with copper diethyldithiocarbamate solution in CHCl₃. The chemical yield was determined by using ¹⁹⁹Au tracer. The present data are compared with published values for the ZGI and USGS samples.     

Relationships between crustal contamination and crystallisation in continental flood basalt magmas with special reference to the Deccan Traps of the Western Ghats, India

The upper part of the Deccan Traps sequence (Bushe to Mahabaleshwar Formations) shows a statistically significant tendency for the most mafic lavas to be the most contaminated by crustal materials. This is the reverse of the relationship shown by suites evolving by contamination accompanied by fractional crystallisation (AFC). The observed correlations (e.g. between Mg-number and Sr isotope initial ratios) are partly an accidental consequence of the fact that the most mafic lavas are more abundant in the lower part of the sequence, while contaminant availability declines in the upper part. It is probable, however, that the correlations are augmented by increased contamination of hotter magma batches during ascent through dykes, a process during which fractional crystallisation is suppressed by magmatic turbulence. The absence of AFC relationships suggests that most of the contamination took place during the ascent stage rather than in a magma chamber. Other continental flood basalt provinces such as the Parana and Etendeka do show AFC relationships, and it is speculated that this may be a result of magma chamber contamination coupled with flow rates which prevent contamination during ascent.     

Magnetic order in grunerite,Fe7Si8O22(OH)2A quasi-one dimensional antiferromagnet with a spin canting transition

Magnetization and neutron diffraction measurements have been made on grunerite, Fe₇Si₈O₂₂(OH)₂, a monoclinic double-chain silicate with Fe²⁺ octahedral bands. The mineral orders antiferromagnetically at 47K into a collinear structure with a second transition at 8K to a canted arrangement. The magnetic susceptibility follows a Curie-Weiss Law above 120K, with a paramagnetic Curie temeprature ?_p=67K. Magnetization measurements below 47K indicate a spin-flop or metamagnetic transition in an applied field of about 12KOe. Powder neutron diffraction measurements between 8–45K reveal that all the Fe²⁺ spins within an octahedral band are ferromagnetically coupled parallel to the b axis, with each band antiferromagnetically coupled to neighboring bands. Below 8K Fe²⁺ spins at the M1 and M4 sites are canted away from the b axis, whereas those at the M2 and M3 sites are not significantly affected. The ordered Fe²⁺ moment on the M4 site is substantially lower than those on the other sites, most likely indicating strong covalency effects, i.e. considerable spin transfer to neighboring oxygen atoms.     

Comparison of the magnetic properties of glass from Luna 20 with similar properties of glass from the Apollo missions

Magnetic susceptibility measurements have been made on four glass spherules and fragments from the Luna 20 fines; two at 300°K and two from 300°K to 4°K. From these data the magnetic susceptibility extrapolated to infinite field, the magnetization at low fields and also the saturation magnetization at high fields, the Curie constant, the Weiss temperature, and the temperature-independent susceptibility were determined. Using a model previously proposed for the Apollo specimens, the Curie constant of the antiferromagnetic inclusions and a zero field splitting parameter were calculated for the same specimens. The data show the relatively low concentration of iron in all forms in these specimens. In addition, the Weiss temperature is lower than that measured for the Apollo specimens, and can be attributed almost entirely to the ligand field distortion about the Fe²⁺ ions in the glassy phase. The data further suggest that the Luna 20 specimens cooled more slowly than those of the Apollo missions, and that some of the antiferromagnetic inclusions in the glass may have crystallized from the glass during cooling.     

Oceanic ridges and transform faults: Their intersection angles and resistance to plate motion

The persistent near-orthogonal pattern formed by oceanic ridges and transform faults defies explanation in terms of rigid plates because it probably depends on the energy associated with deformation. For passive spreading, it is likely that the ridges and transforms adjust to a configuration offering minimum resistance to plate separation. This leads to a simple geometric model which yields conditions for the occurrence of transform faults and an aid to interpretation of structural patterns in the sea floor. Under reasonable assumptions, it is much more difficult for diverging plates to spread a kilometer of ridge than to slip a kilometer of transform fault, and the patterns observed at spreading centers might extend to lithospheric depths. Under these conditions, the resisting force at spreading centers could play a significant role in the dynamics of plate-tectonic systems.     

Metamorphic assemblages and the direction of flow of metamorphic fluids in four instances of serpentinization

Fluids related to Serpentinization are of at least three types. The first reported (Barnes and O'Neil, 1969) is a fluid of local meteoric origin, the chemical and thermodynamic properties of which are entirely controlled by olivine, orthopyroxene, brucite, and serpentine reactions. It is a Ca⁺²-OH^–1 type and is shown experimentally to be capable of reacting with albite to yield calcium hydroxy silicates. Rodingites may form where the Ca⁺²-OH^–1 type waters flow across the ultramafic contact and react with siliceous country rock.The second type of fluid has its chemical composition largely controlled before it enters the ultramafic rocks, but reactions within the ultramafic rocks fix the thermodynamic properties by reactions of orthopyroxene, olivine, calcite, brucite, and serpentine. The precipitation of brucite from this fluid clearly shows that fluid flow allows reaction products to be deposited at a distance from the point of solution. Thus, textural evidence for volume relations during Serpentinization may not be valid.The third type of fluid has its chemical properties fixed in part before the reactions with ultramafic rocks, in part by the reactions of orthopyroxene, olivine, and serpentine and in part by reactions with siliceous country rock at the contact. The reactions of the ultramafic rock and country rock with the fluid must be contemporaneous and require flow to be along the contact. This third type of fluid is grossly supersaturated with talc and tremolite, both found along the contact. The occurrence of magadiite, kenyaite, mountainite, and rhodesite along the contact is probably due to a late stage low-temperature reaction of fluids of the same thermodynamic properties as those that formed the talc and tremolite at higher temperatures. Oxygen isotope analyses of some of these minerals supports this conclusion.Rodingites form from Ca⁺²-rich fluids flowing across the contact; talc and tremolite form from silica-rich fluids flowing along the contact.Isotopic analyses of the fluids indicate varied origins including unaltered local meteoric water and connate water. Complexion Spring water may be a sample of only slightly altered Jurassic or Cretaceous sea water.Publication authorized by the Director, U.S. Geological Survey.