Fine-scale acoustic tomographic imaging of shallow water sediments

In acoustic tomographic system capable of performing in situ two-dimensional (2D) acoustic imaging of shallow water sediments is described. This system is capable of resolving inhomogeneities greater than 10 cm and differentiating sound-speed variations greater than 2%, A tomographic inversion is performed in a 2D vertical slice of about 1 m ² (1 m×1 m) using three identical probes, with each consisting of 70 evenly distributed transducers. In normal deployments, two of the probes are oriented vertically and are separated by about 1 meter, and the third is positioned horizontally right above the two vertical probes. The additional horizontal probe greatly improves the horizontal resolution of the system compared to conventional crosshole tomographic setups. Numerical simulations are performed to evaluate the influences of arrival time detection error and transducer position error on the performance of the tomography system. For an arrival time of 500 ns (standard deviation) and a position error of 4 mm (standard deviation), sound-speed anomalies of greater than 0.8% can be correctly predicted near the upper portion (close to the horizontal probe) and are resolvable near the lower portion. A controlled laboratory experiment was conducted to evaluate the performance of the system. The location of a polyurethane block (Conap EN22) used as a known target is correctly predicted while the inverted sound speed is about 9% lower than that from its actual value. Field data taken from a saturated muddy site are presented and analyzed. The inverted mean sound speed and attenuation are about 1480 ms^-1 and 20 dBm^-1, respectively     

Black Sea chemocline oscillations during the Holocene: molecular and isotopic studies of marginal sediments

We measured δ¹³C values of free and sulfur-bound lipids and framboidal pyrite-size distributions in three sediment cores from the southern margins of the Black Sea. The margin cores show a marked difference in the occurrence of biomarkers from green sulfur bacteria compared with the deep-basin cores, as a result of deepening of the chemocline resulting from enhanced mixing and/or decreased light-penetration as a consequence of high turbidity and productivity in shelf waters. Quantitation of biomarkers suggests that photic-zone anoxia along the shelf margin was generally absent during the deposition of unit I, although occurred during the deposition of Unit IIb at two sites.     

Simulating saturation‐excess surface run‐off in a semi‐distributed hydrological model

The level of complexity, and the number of parameters, to include in a hydrological model is a relatively contentious issue in hydrological modelling. However, it can be argued that explicitly representing important run‐off generation processes can improve the practical value of a model's outputs. This paper explores the benefits of including a new function into an existing semi‐distributed hydrological model (the Pitman model) that is widely used in the sub‐Saharan Africa region. The new function was designed to represent saturation‐excess surface run‐off processes at subcatchment scales and was motivated by the evidence of dambo (low topography riparian areas) type features in many sub‐Saharan river basins. The results for uncertainty versions of the model, with and without the new function, were compared for 25 catchments, which were divided up into those where evidence of dambos exists and those where there is no such evidence. The results suggest that the new function certainly improves the model results for the catchments where dambos exist, but not in situations where saturation‐excess surface run‐off is not expected to occur. The overall conclusion is therefore that the addition of the new function is justified.     

Groundwater monitoring at the watershed scale: An evaluation of recharge and nonpoint source pollutant loading in the Clear Creek Watershed,Iowa

Determining the groundwater contribution of nonpoint source pollution at a watershed scale is a challenging issue. In this study, we utilized a top‐down approach to characterize representative groundwater response units (GRUs) based on land use and landscape position (e.g., upland, sideslope, or floodplain) in the 275‐km² Clear Creek Watershed, Iowa. Groundwater monitoring wells were then established along downslope transects in representative GRUs. This unique combination of top‐down/bottom‐up approaches allowed us to estimate groundwater pollutant loads at the watershed scale with minimal monitoring. For the 2015 study period, results indicated that more groundwater recharge occurred in the floodplain (404 mm) compared to the uplands or sideslopes (281 and 165 mm, respectively), irrespective of land use. Recharge in the floodplains consisted of 37% of the annual precipitation, whereas upland wells averaged 26% and sideslopes averaged 15% of the annual precipitation. Less recharge was found to occur beneath perennial grass compared to row crop and urbanized areas. Baseflow discharge accounted for 69% of the total NO₃‐N exported from the Clear Creek Watershed, with row crop areas contributing approximately 95% of the annual load. Orthophosphorus (OP) yields were approximately 0.72 kg/ha beneath urban and suburban areas, three times higher than those in row crop or perennial areas. Urban and suburban areas accounted for 21.4% of groundwater orthophosphorus and chloride loads in the watershed compared to only 8.5% of the land area. Overall, the groundwater load allocation model for baseflow nutrient discharge to Clear Creek can be used to target future nonpoint source load reduction strategies at the watershed scale. The use of GRUs can pinpoint better areas of concern for controlling nutrient loads.     

Provenance of altered carbon phases and impact history of the Stac Fada Member,NW Scotland

The Stac Fada Member (Stoer Group) is a ~1.2 Ga melt-rich impact breccia preserved and intermittently exposed along the NW coast of Scotland. Using a combination of x-ray diffraction and micro-Raman spectroscopy, we identify potential coesite that is spatially associated with micron-sized diamonds, as well as disordered carbon phases. Comparing the graphite G-band of disordered carbon phases in the impact breccia to samples from underlying units indicates that most of the carbon in the Stoer Group was ultimately derived from the underlying Lewisian basement. Disordered carbon phases within the Stac Fada Member have been modified by mild heating within a hot ejecta blanket rather than shock pressure. We also report the first evidence for impact diamonds discovered within the Stac Fada Member. These diamonds have an average Raman shift of 1328.5 cm⁻¹ and are present within both the impact breccia and the shocked gneiss clasts that are present in sandstones directly underlying the Stac Fada Member contact, and within sandstone rafts entrapped in the unit. These findings have implications for the timing of deposition of the Stac Fada Member, which must have occurred after ballistic ejection of Lewisian basement clasts during the impact event.     

Effects of climate change and urban development on the distribution and conservation of vegetation in a Mediterranean type ecosystem

Climate and land-use changes are projected to threaten biodiversity over this century. However, few studies have considered the spatial and temporal overlap of these threats to evaluate how ongoing land-use change could affect species ranges projected to shift outside conservation areas. We evaluated climate change and urban development effects on vegetation distribution in the Southwest ecoregion, California Floristic Province, USA. We also evaluated how well a conservation network protects suitable habitat for rare plant species under these change projections and identified primary sources of uncertainty. We used consensus-based maps from three species distribution models (SDMs) to project current and future suitable habitat for 19 species representing different functional types (defined by fire-response – obligate seeders, resprouting shrubs – and life forms – herbs, subshrubs), and range sizes (large/common, small/rare). We used one spatially explicit urban growth projection; two climate models, emission scenarios, and probability thresholds applied to SDMs; and high-resolution (90 m) environmental data. We projected that suitable habitat could disappear for 4 species and decrease for 15 by 2080. Averaged centroids of suitable habitat (all species) were projected to shift tens (up to hundreds) of kilometers. Herbs showed a small-projected response to climate change, while obligate seeders could suffer the greatest losses. Several rare species could lose suitable habitat inside conservation areas while increasing area outside. We concluded that (i) climate change is more important than urban development for vegetation habitat loss in this ecoregion through 2080 due to diminishing amounts of undeveloped private land in this region; (ii) the existing conservation plan, while extensive, may be inadequate to protect plant diversity under projected patterns of climate change and urban development, (iii) regional assessments of the dynamics of the drivers of biodiversity change based on high-resolution environmental data and consensus predictive mapping, such as this study, are necessary to identify the species expected to be the most vulnerable and to meaningfully inform regional-scale conservation.     

China's ascent and Africa's environment

China's unprecedented economic growth path over the last two decades has been paralleled by an exponential growth in the consumption of natural resources and in pollution. Initially, China mainly exploited domestic resources to fuel its rapid industrial development. But over the last decade, increasing shares of China's natural resources consumption and environmental impacts relate to peripheral regions, including sub-Saharan Africa. China's environmental impacts in peripheral regions seem in line with World-Systems Theory predictions for ascending world powers. This paper assesses the extent to which the World-Systems Theory idea of ‘environmentally unequal exchange’ between ascending world powers and peripheral economies reflects current behaviour of Chinese governmental authorities and companies in sub-Saharan Africa. It concludes that the theory only partly does so. Behaviour of Chinese governmental authorities and firms is conditioned and guided by environmental norms, as well. World-Systems Theory has to make conceptual space for such new environmental behaviour of ascending world powers, to understand the contemporary and future world-systems. At the same time, China has a long way to go before becoming the ‘green’ exemplar for the world to follow.