Mechanism of pyroxene and amphibole weathering—I. Experimental studies of iron-free minerals

The short term (2–40 days) dissolution of enstatite, diopside, and tremolite in aqueous solution at low temperatures (20–60°C) and pH 1–6 has been studied in the laboratory by means of chemical analyses of reacting solutions for Ca²⁺, Mg²⁺, and Si(OH)₄ and by the use of X-ray photoelectron spectroscopy (XPS) for detecting changes in surface chemistry of the minerals. All three minerals were found to release silica at a constant rate (linear kinetics) providing that ultrafine particles, produced by grinding, were removed initially by HF treatment. All three also underwent incongruent dissolution with preferential release of Ca and/or Mg relative to Si from their outermost surfaces. The preferential release of Ca, but not Mg for diopside at pH 6 was found by both XPS and solution chemistry verifying the theoretical prediction of greater mobility of cations located in M₂ structural sites. Loss mainly from M₂ sites also explains the degree of preferential loss of Mg from enstatite at pH 6; similar structural arguments apply to the loss of Ca and Mg from the surface of tremolite. In the case of diopside and tremolite initial incongruency was followed by essentially congruent cation-plus-silica dissolution indicating rapid formation of a constant-thickness, cation-depleted surface layer. Cation depletion at elevated temperature and low pH (~ 1) for enstatite and diopside was much greater than at low temperature and neutral pH, and continued reaction resulted in the formation of a surface precipitate of pure silica as indicated by solubility calculations, XPS analyses, and scanning electron microscopy.From XPS results at pH 6, model calculations indicate a cation-depleted altered surface layer of only a few atoms thickness in all three minerals. Also, lack of shifts in XPS peak energies for Si, Ca, and Mg, along with undersaturation of solutions with respect to all known Mg and Ca silicate minerals, suggest that cation depletion results from the substitution of hydrogen ion for Ca²⁺ and/or Mg²⁺ in a modified silicate structure and not from the precipitation of a new, radically different surface phase. These results, combined with findings of high activation energies for dissolution, a non-linear dependence on a_H⁺ for silica release from enstatite and diopside, and the occurrence of etch pitting, all point to surface chemical reaction and not bulk diffusion (either in solution or through altered surface layers) as the rate controlling mechanism of iron-free pyroxene and amphibole dissolution at earth surface temperatures.     

Precise geoid determination over Sweden using the Stokes–Helmert method and improved topographic corrections

 Four different implementations of Stokes' formula are employed for the estimation of geoid heights over Sweden: the Vincent and Marsh (1974) model with the high-degree reference gravity field but no kernel modifications; modified Wong and Gore (1969) and Molodenskii et al. (1962) models, which use a high-degree reference gravity field and modification of Stokes' kernel; and a least-squares (LS) spectral weighting proposed by Sj?berg (1991). Classical topographic correction formulae are improved to consider long-wavelength contributions. The effect of a Bouguer shell is also included in the formulae, which is neglected in classical formulae due to planar approximation. The gravimetric geoid is compared with global positioning system (GPS)-levelling-derived geoid heights at 23 Swedish Permanent GPS Network SWEPOS stations distributed over Sweden. The LS method is in best agreement, with a 10.1-cm mean and ±5.5-cm standard deviation in the differences between gravimetric and GPS geoid heights. The gravimetric geoid was also fitted to the GPS-levelling-derived geoid using a four-parameter transformation model. The results after fitting also show the best consistency for the LS method, with the standard deviation of differences reduced to ±1.1 cm. For comparison, the NKG96 geoid yields a 17-cm mean and ±8-cm standard deviation of agreement with the same SWEPOS stations. After four-parameter fitting to the GPS stations, the standard deviation reduces to ±6.1 cm for the NKG96 geoid. It is concluded that the new corrections in this study improve the accuracy of the geoid. The final geoid heights range from 17.22 to 43.62 m with a mean value of 29.01 m. The standard errors of the computed geoid heights, through a simple error propagation of standard errors of mean anomalies, are also computed. They range from ±7.02 to ±13.05 cm. The global root-mean-square error of the LS model is the other estimation of the accuracy of the final geoid, and is computed to be ±28.6 cm. Received: 15 September 1999 / Accepted: 6 November 2000     

Åland GPS levelling campaign in 1987

In October 1987 a four day satellite GPS campaign was performed over the Åland archipelago to test the possibility of connecting the Swedish and Finnish national height systems. This paper summarizes the gained experiences using 5 WM 101 GPS receivers and the PoPS software.The computing results for the connection between the two height systems are considerably dependent on the choice of geoidal undulation model and systematic error parameter model. Using the NKG Scandinavian geoid 1989, which is probably the most accurate geoid available for the region, and a bias and tilt parameter model the difference between the Swedish RH70 system and the Finnish N60 system is estimated to 11.4 ± 4.0 cm. An independent check is provided by two connecting border bench marks in northern Scandinavia yielding the difference 19.2 ± 4.2 cm. In view of that merely single frequency GPS receivers were used together with the PoPS software, we consider this result most satisfactory.     

The convergence of harmonic reduction to an internal sphere

The boundary value problem of physical geodesy has been solved with the use of a harmonic reduction down to an internal sphere using a discrete procedure. (For gravity cf. Bjerhammar 1964 and for the potential cf. Bjerhammar 1968). This was a finite-dimensional approach mostly with one-to-one correspondence between observations and unknowns on the sphere. Earlier studies were made with the use of surface elements (on the sphere) with constantgravity. Integration over the surface elements was replaced by a discrete approach with the use of the distance to a point in the centre of the surface element. See Bjerhammar (1968) and (1969). This approach was later presented as a “reflexive prediction” technique for a weakly stationary stochastic process. Bjerhammar (1974, 1976). Krarup (1969) minimized the L²-norm of the potential on the internal sphere. It will here be proved that the two solutions are identical for a proper choice of the radii of the internal spheres. The proof is given for a spherical earth with selected choice of “carrier points”. The convergence problem is discussed. The L²-norm solution is found convergent for the fully harmonic case. Uniform convergence is obtained in the non-harmonic case with the use of the original procedure applied in accordance with the theorems of Keldych-Lavrentieff and Yamabe.     

The genesis of Pb‐Zn sulphide occurrences in the Lower Devonian Buchan Group,Victoria

Six minor sulphide occurrences hosted by the Lower Devonian Buchan Group have been investigated. Sulphide minerals and associated phases are hosted by both dolostone and limestone lithologies along stylolitized bedding planes, cross‐cutting fractures, low angle minor faults and in cavities. Mineralization was closely associated with minor structures of inferred Tabberabberan age (Middle Devonian), which it appears to have post‐dated, but was largely strata‐bound in nature. The mineralogy of the occurrences is simple and characterized by the following generalized paragenesis which reflects the increasing oxidation state and pH of the mineralizing fluids: pyrite (pseudomorphous after marcasite)‐galena ± sphalerite ± pyrite‐dolomite ± barite‐calcite ± fluorite ± dolomite.

The sulphur isotope composition of sulphide minerals varies from ‐32.1 to +4.1‰, with iron and base metal sulphide minerals forming two distinct populations around ‐25‰ and 0‰, respectively. A single barite sample gives a sulphur isotope composition of +22.4‰, which is similar to that estimated for Early Devonian seawater. Fluid inclusions in fluorite and calcite homogenize at temperatures in the range 160 to 212° C and have average salinities of approximately 10 wt% NaCI eq. Sphalerite contains up to 1.81 wt% iron which correlates with colour, and up to 1.43 wt% cadmium. The Pb isotopic pattern of galena suggests a source region with U/Pb(= μ) lower than the crustal average, and a high Th/U.

A genetic hypothesis is proposed which involves the circulation of saline fluids through the Snowy River Volcanics, which directly underlie the Buchan Group, during or at some time after the Tabberabberan Orogeny. Although the Buchan occurrences show features characteristic of both Mississippi Valley‐type and stratiform ore deposits, they are most directly comparable to the epigenetic zones of Irish carbonate‐hosted base‐metal deposits. However, Pb‐Zn sulphide mineralization at Buchan appears to have been associated with minor compressional structures, suggesting that a simple correlation with the Irish deposits is not directly applicable.     

A Local Least-Squares Modification of Stokes’ Formula

The combination of Stokes formula and an Earth Gravity Model (EGM) for geoid determination has become a standard procedure. However, the way of modifying Stokes formula vary from author to author, and numerous methods of modification exist. Most methods are deterministic, with the primary goal of reducing the truncation bias committed by limiting the area of Stokes integration around the computation point, but there are also some stochastic methods with the explicit goal to reduce the global mean square error of the geoid height estimator stemming from the truncation bias as well as the random errors of the EGM and the gravity data. The latter estimators are thus, at least from a theoretical point of view, optimal in a global mean sense, but in a local sense they may be far from optimality.Here we take advantage of the error variance-covariance matrices of the EGM and the terrestrial gravity data to derive the modification parameters of Stokes kernel in a local least-squares sense. The solution is given for the unbiased type of modification of Stokes formula of Sjöberg (1991).     

Airborne geophysical prospecting for ultramafite associated talc, Altermark, northern Norway

Talc-rich rocks in Altermark occur as rims around magnetite bearing serpentinite lenses which are up to about 1 km wide. The content of magnetite in the serpentinite makes magnetic measurements possible as a method for talc-prospecting. In 1991 a helicopter-borne geophysical survey combined with geological and petrophysical mapping was carried out in the Altermark area. Several positive magnetic anomalies were detected. Positive magnetic anomalies with oval shapes, well defined boundaries and smooth anomaly curves were interpreted to be caused by serpentinite lenses. Laboratory measurements revealed susceptibilities for the serpentinites between 0.006−0.36 SI and a Q-value of approximately 0.3. Magnetic modelling of the Nakkan anomaly and subsequent drilling revealed that it was indeed a serpentinite body surrounded by talc rocks which was the cause of the anomaly. The shallowest part was located about 150 m below surface. The geophysical exploration led to the discovery of a talc-carbonate deposit with an anticipated in situ tonnage of more than 1 million tons. The present study consequently proved to be a classical case study where we were able to locate and establish the three-dimensional form of serpentinite bodies associated with talc deposits. We conclude that helicopter-borne geophysical surveying is an effective tool in the exploration of serpentinite cored talc bearing rocks in complex geological areas where exposures are poor or absent and accessibility difficult. The rough topography and dense vegetation in the Altermark area make this type of survey very cost effective.     

The changing social relations of a community-based mangrove forest project in Zanzibar

Coastal areas in East Africa are experiencing rapid economic, resource management, demographic and technological shifts. In response diverse Community-based Natural Resource Management (CBNRM) applications have been embraced to provide mutual conservation and use benefits. These initiatives have met with mixed success in practice. Reflecting on the limitations of past research using common pool resources theory theory to study CBNRM we use insights from actor oriented theory combined with satellite image analysis to describe and discuss the forces dynamically influencing institutional and mangrove forest cover change at Kisakasaka, Zanzibar focussing on the formal CBNRM project period between 1996 and 2001, but also considering the period before and after this. We examine the shifting social relations that affected the performance and viability of the formal CBNRM arrangements. An integrated approach was taken to the presentation and discussion of results where it was possible to enrich and expand explanations of socio-environmental change, which was driven by a lack of government support, the undermining effects of party political divisions, and the lack of institutional adaptive capacity. We conclude that this was a useful approach to explain CBNRM intervention events at Kisakasaka.     

A first approach to calculate BIOCLIM variables and climate zones for Antarctica

Theoretical and Applied Climatology - For testing the hypothesis that macroclimatological factors determine the occurrence, biodiversity, and species specificity of both symbiotic partners of...