Gaseous and Particulate Oxidized and Reduced Nitrogen Species in the Atmospheric Boundary Layer in Scandinavia in Spring

Observations of the concentration of several nitrogen containing compounds at five rural Scandinavian sites during March–June 1993 are reported. Total nitrate (NO ₃ ^- + HNO₃) and total ammonium (NH ₄ ⁺ + NH₃) were measured by denuder and filter pack. In general the methods agree well. At all sites the particulate fraction dominated, with the largest fraction of NO ₃ ^- and the lowest of NH ₄ ⁺ at the sites which were closest to the emission sources. The fraction of NO ₃ ^- of total nitrate increased with increasing NO₂ concentrations, indicating that the nighttime conversion of NO₂ to NO ₃ ^- is an important route of formation for NO ₃ ^- . A positive correlation was found between HNO₃ and O₃ in June at all sites, while no correlation was found early in the spring. Model calculations were made with a lagrangian boundary layer photooxidant model for the whole period, and compared to the measured concentrations. The calculated ratio between mean observed and modelled daily maximum concentrations of ozone over the measurement period were within +/–10% at all sites. The models ability to describe the daily ozone maximum concentration was satisfactory with an average deviation of 19–22% from the observed concentrations. HNO₃ was underestimated by over 50% at all sites except the one closest to the emission sources. The correlation between modelled and observed concentrations was generally best for the sites with shortest transport distance from the sources of emission.     

Airborne geophysical prospecting for ultramafite associated talc, Altermark, northern Norway

Talc-rich rocks in Altermark occur as rims around magnetite bearing serpentinite lenses which are up to about 1 km wide. The content of magnetite in the serpentinite makes magnetic measurements possible as a method for talc-prospecting. In 1991 a helicopter-borne geophysical survey combined with geological and petrophysical mapping was carried out in the Altermark area. Several positive magnetic anomalies were detected. Positive magnetic anomalies with oval shapes, well defined boundaries and smooth anomaly curves were interpreted to be caused by serpentinite lenses. Laboratory measurements revealed susceptibilities for the serpentinites between 0.006−0.36 SI and a Q-value of approximately 0.3. Magnetic modelling of the Nakkan anomaly and subsequent drilling revealed that it was indeed a serpentinite body surrounded by talc rocks which was the cause of the anomaly. The shallowest part was located about 150 m below surface. The geophysical exploration led to the discovery of a talc-carbonate deposit with an anticipated in situ tonnage of more than 1 million tons. The present study consequently proved to be a classical case study where we were able to locate and establish the three-dimensional form of serpentinite bodies associated with talc deposits. We conclude that helicopter-borne geophysical surveying is an effective tool in the exploration of serpentinite cored talc bearing rocks in complex geological areas where exposures are poor or absent and accessibility difficult. The rough topography and dense vegetation in the Altermark area make this type of survey very cost effective.     

Use of biological traits for interpreting functional relationships in large rivers

Altogether 64 predominantly biological traits were coded for more than 600 macroinvertebrate species from European rivers. The main question was: Are biological traits able to reflect “biological functionality” in large rivers and if so, is it possible to deduce an assessment system based on functionality? Analysis of the raw trait structure of all species indicates that these traits are not completely independent from their higher systematic units. To avoid mis-interpretations when judging from mixtures of habitats (β-biocoenosis) we used for our investigations only sample series from -biocoenosis, pre-tested by a mathematical criterion of homogeneity. Within -biocoenosis, traits are shown to be able to compensate for drastic changes with respect to species number and species composition along a river continuum, demonstrating their functional quality. Long-term changes in the trait and species structures of German waterways were studied using multivariate methods, based on an analysis of 142 sampling series. A shift from traits typical for K-strategists to traits typical for r-strategists was detected to be the main background variable. The rK-strategy is regarded as a true functional character of species. We calculated the relative positions of all trait-coded species on this rK-scale, and plotted the functional diversity of our samples against the structural diversity of the species from several river systems. Rivers extremely dominated by r-strategists show a deficit in functional diversity. Rivers dominated by K-strategists also show deficits, possibly in concordance with modern ecological theories such as the intermediate disturbance theory. The quantitative proportions of extreme r- to K-Strategists in -biocoenosis can be used as a general disturbance measure.     

The acoustic signature of fluid flow in complex porous media

Effective medium approximations for the frequency-dependent and complex-valued effective stiffness tensors of cracked/porous rocks with multiple solid constituents are developed on the basis of the T-matrix approach (based on integral equation methods for quasi-static composites), the elastic–viscoelastic correspondence principle, and a unified treatment of the local and global flow mechanisms, which is consistent with the principle of fluid mass conservation. The main advantage of using the T-matrix approach, rather than the first-order approach of Eshelby or the second-order approach of Hudson, is that it produces physically plausible results even when the volume concentrations of inclusions or cavities are no longer small. The new formulae, which operates with an arbitrary homogeneous (anisotropic) reference medium and contains terms of all order in the volume concentrations of solid particles and communicating cavities, take explicitly account of inclusion shape and spatial distribution independently. We show analytically that an expansion of the T-matrix formulae to first order in the volume concentration of cavities (in agreement with the dilute estimate of Eshelby) has the correct dependence on the properties of the saturating fluid, in the sense that it is consistent with the Brown–Korringa relation, when the frequency is sufficiently low. We present numerical results for the (anisotropic) effective viscoelastic properties of a cracked permeable medium with finite storage porosity, indicating that the complete T-matrix formulae (including the higher-order terms) are generally consistent with the Brown–Korringa relation, at least if we assume the spatial distribution of cavities to be the same for all cavity pairs. We have found an efficient way to treat statistical correlations in the shapes and orientations of the communicating cavities, and also obtained a reasonable match between theoretical predictions (based on a dual porosity model for quartz–clay mixtures, involving relatively flat clay-related pores and more rounded quartz-related pores) and laboratory results for the ultrasonic velocity and attenuation spectra of a suite of typical reservoir rocks.     

Cooling of the Sverdrup Basin during Tertiary basin inversion: implications for hydrocarbon exploration

ABSTRACT The regional thermal history of the north‐eastern Sverdrup Basin, Canadian Arctic Archipelago, has been assessed using apatite fission‐track thermochronology and vitrinite reflectance data. Fission‐track data for 27 samples from six wells through the Mesozoic section on Axel Heiberg and Ellesmere Islands reveal significant Palaeocene cooling associated with basin inversion during the Eurekan Orogeny. Fission‐track data for 29 outcrop samples, ranging in stratigraphic age from Cambrian to Tertiary, also reveal significant Palaeocene cooling. Vitrinite reflectance data from carbonaceous shales and coal seams in well and outcrop samples are consistent with these conclusions. The degree of Palaeocene cooling observed is greatest for well and outcrop samples in the cores of anticlines or the hanging walls of thrust faults, such as the Fosheim anticline, and faults, such as the Lake Hazen fault system, and the East Cape and Vesle Fiord thrust faults. Palaeocene cooling is largely attributed to the denudation of structures during the Eurekan Orogeny. At one locality on north‐western Ellesmere Island, which is on the northern flank of the Sverdrup Basin, the underlying Franklinian basement rocks yield Early Cretaceous fission track ages with relatively long mean track lengths. This indicates that this part of the basin was uplifted at this time and that subsequent sedimentation and subsidence in the Cretaceous and early Tertiary were modest. This locality thus appears to be on the rift shoulder, which developed along the flank of the Amerasia Basin in the Lower Cretaceous. At a locality on western Axel Heiberg Island, which is downflank from the rift shoulder, the Upper Jurassic Awingak sandstone has a Late Cretaceous fission track age. This is best explained by heating above the total annealing temperature for fission‐tracks in apatite by extensive Lower Cretaceous intrusions and subsequent heat dissipation and cooling in the Late Cretaceous followed by further substantial cooling due to Tertiary denudation. These results indicate that maximum burial temperatures occurred in the presently exposed Mesozoic section prior to basin inversion during the Eurekan Orogeny. It can therefore be inferred that peak hydrocarbon generation and primary migration predated the formation of structural traps during the Tertiary at shallow depths within the northern Sverdrup Basin.     

Architecture of tunnel valleys in the southeastern North Sea: new insights from high-resolution seismic imaging

Tunnel valleys are assumed to form near the margin of ice sheets. Hence, they can be used to reconstruct the dynamics of former ice margins. The detailed formation and infill of tunnel valleys, however, are still not well understood. Here, we present a dense grid of high-resolution 2D multi-channel reflection seismic data from the German sector of the southeastern North Sea imaging tunnel valleys in very great detail. Three tunnel valley systems were traced over distances ranging between 11 and 21 km. All tunnel valleys are completely filled and buried. They differ in incision depth, incision width and number of incisions. The tunnel valleys cut 130–380 m deep into Neogene, Palaeogene and Cretaceous sediments; they show a lower V-shaped and an upper U-shaped morphology. For individual tunnel valleys, the overall incision direction ranges from east–west to northeast–southwest. Two tunnel valleys intersect at an oblique angle without reuse of the thalweg. These valleys incise into a pre-existing glaciotectonic complex consisting of thrust sheets in the northwest of the study area. The analysis of the glaciotectonic complex and the tunnel valleys leads us to assume that we identified several marginal positions of (pre-)Elsterian ice lobes in the southeastern North Sea.     

Pulsation–decline relationships in R Coronae Borealis stars

Decline onset times were measured in long-term visual light curves for five R Coronae Borealis (RCB) variable stars. These included RY Sgr and V854 Cen, the two RCB stars previously reported to have a relationship between dust formation events and pulsational variations. Analysis of the decline epochs showed that all decline onsets for a given star obey a linear ephemeris tied to the object's dominant radial pulsation period. Thus, in addition to confirming the pulsation–decline correlation for RY Sgr and V854 Cen, this same behaviour was demonstrated in UW Cen, R CrB and S Aps for the first time. This general result firmly establishes the connection between radial pulsation and mass loss in the RCB stars. The dominant pulsation period of ≈40 d for all of these objects therefore represents the characteristic time-scale on which these stars produce dust.     

SHEBA flux–profile relationships in the stable atmospheric boundary layer

Measurements of atmospheric turbulence made during the Surface Heat Budget of the Arctic Ocean Experiment (SHEBA) are used to examine the profile stability functions of momentum, φ _m , and sensible heat, φ _h , in the stably stratified boundary layer over the Arctic pack ice. Turbulent fluxes and mean meteorological data that cover different surface conditions and a wide range of stability conditions were continuously measured and reported hourly at five levels on a 20-m main tower for 11 months. The comprehensive dataset collected during SHEBA allows studying φ _m and φ _h in detail and includes ample data for the very stable case. New parameterizations for φ _m (ζ) and φ _h (ζ) in stable conditions are proposed to describe the SHEBA data; these cover the entire range of the stability parameter ζ = z/L from neutral to very stable conditions, where L is the Obukhov length and z is the measurement height. In the limit of very strong stability, φ _m follows a ζ ^1/3 dependence, whereas φ _h initially increases with increasing ζ, reaches a maximum at ζ ≈ 10, and then tends to level off with increasing ζ. The effects of self-correlation, which occur in plots of φ _m and φ _h versus ζ, are reduced by using an independent bin-averaging method instead of conventional averaging.     

Wave-trains in the solar wind

Applying an Alfvén-Wave-Extended-QRH-approximation and the method of characteristics, we solve the equations of motion for outwardly propagating Alfvén waves analytically for three different cases of an azimuthal dependence of the background solar wind, (a) for a pure fast-slow stream configuration, (b) for the situation where the high-speed stream originates from a diverging magnetic field region, and (c) for the case of (b) and an initially decreasing density configuration (‘coronal hole’). The reaction of these waves on the background state as well as mode-mode coupling effects are neglected. These three solar wind models are discussed shortly. For the superimposed Alfvén waves we find, on an average, that there is a strong azimuthal dependence of all relevant wave parameters which, correlated with the azimuthal distributions of the solar wind variables, leads to good agreements with observations. The signature of high-speed streams and these correlations could clearly indicate solar wind streams originating from ‘coronal holes’. Contrary to the purely radial dependent solar wind, where outwardly propagating Alfvén waves are exclusively refracted towards the radial direction, we now find a refraction nearly perpendicular to the direction of the interplanetary magnetic field in the compression region and closely towards the magnetic field direction down the trailing edge and in the low-speed regime.