Integrated Onshore‐Offshore Investigation of a Mediterranean Layered Coastal Aquifer

Most of the Mediterranean coastal porous aquifers are intensively exploited. Because of climatic and anthropogenic effects, understanding the physical and geological controls on groundwater distribution and flow dynamics in such aquifers is crucial. This study presents the results of a structural investigation of a system located along the coastline of the Gulf of Lions (NW Mediterranean). A key aspect of this study relies on an onshore‐offshore integrated approach combining outcrops, seismic profiles, and borehole data analysis. This multidisciplinary approach provides constraints on pore‐fluid salinity distribution and stratigraphic organization, which are crucial in assessing the modes of groundwater/seawater exchanges. Onshore, Lower Pliocene deposits dip gently seaward. They are unconformably overlain by Holocene clays in the lagoons. Offshore the Pliocene deposits either outcrop at the seabed or are buried below nonconsolidated sands infilling paleo‐valleys. Beneath the lido, the groundwater salinity distribution consists of salty pore water, overlying fresher pore water. Active circulation of groundwater masses is inferred from the geophysical results. In particular, offshore outcrops and paleo‐valleys may play an important role in salt water intrusion.     

Linking landscape morphological complexity and sediment connectivity

Connectivity relates to the coupling of landforms (e.g. hillslopes and channels) and the transfer of water and sediment between them. The degree to which parts of a catchment are connected depends largely on the morphological complexity of the catchment's landscape. Landscapes can have very different and distinct morphologies, such as terraces, V‐shaped valleys or broad floodplains. The objective of this study is to better understand and quantify the relation between landscape complexity and catchment connectivity. We hypothesize that connectivity decreases with increasing landscape morphological complexity. To quantify the connectivity–complexity relationship virtual digital elevation models (DEMs) with distinct morphologies were used as inputs into the landscape evolution model LAPSUS to simulate the sediment connectivity of each landscape. Additionally, the hypothesis was tested on six common real DEMs with widely different morphologies. Finally, the effects of different rainfall time series on catchment response were explored. Simulation results confirm the hypothesis and quantify the non‐linear relation. Results from the exploration of sediment connectivity in response to sequences of rainfall events indicate that feedback between erosion and deposition are more important for certain landscape morphologies than for others: for a given rainfall input, a more effective sediment connectivity and erosion response may be expected from rolling or V‐shaped catchments than from dissected or stepped landscapes. Awareness of the differences in the behaviour and response of different morphologies to catchment processes provides valuable information for the effective management of landscapes and ecosystems through efficiently designed soil and water conservation measures. Copyright © 2013 John Wiley & Sons, Ltd.     

The Lac Des Iles Palladium Deposit,Ontario, Canada part I. The effect of variable alteration on the Offset Zone

The recently discovered Offset Zone of the Mine Block Intrusion of the Lac des Iles Complex hosts palladium mineralization with unusually high Pd/Pt and Pd/Ir ratios in rocks that range from relatively unaltered norite to amphibolites and chlorite–actinolite–talc schist. Quantitative assessment of the effect of progressive alteration using mineral modes was done using total silicate H₂O as a monitor of reaction progress (ξ = moles H₂O added to form alteration minerals per 100 g of rock). Major mineral modal variations define three reaction regions: (1) ξ?=?0.00–0.03, characterized by epidote/clinozoisite formation and some amphibole; (2) ξ?=?0.03–0.23, characterized by formation of chlorite, amphibole, quartz muscovite/sericite, and calcite after plagioclase?+?pyroxene; and (3) ξ?=?0.23–0.28, characterized by the formation of talc after earlier formed amphibole. Epidote occurs as an incongruent product from the destruction of plagioclase that is itself lost as the reaction proceeds. Pyroxene is altered at about twice the rate of plagioclase, resulting in pyroxene-rich protoliths to be more altered than those relatively enriched in plagioclase. Major elements variations largely reflect variations in the plagioclase/pyroxene ratio of the protolith, but compositional trends suggest a loss of Na with reaction progress. The base metal sulfides chalcopyrite, pyrrhotite, and pentlandite show decreasing abundance with reaction progress, forming pyrite (± magnetite) as an intermediate reaction product that also is lost as the reaction proceeds. Millerite is overall low but increases slightly. A more limited data set on the platinum-group minerals suggests that platinum-group element (PGE)-arsenides increase whereas PGE-sulfides and PGE-Bi-tellurides decrease with reaction progress. Assuming ore element concentrations in the protolith were constant and similar to relatively fresh norites, Pd increases modestly, by 5 %, whereas Pt decreases by about 65 % in the most altered rocks. Similarly, Cu, Au, and S decrease by 60, 82, and 94 %, respectively, in the most altered rocks. The antithetical behavior of Pd and the fact that Pd enrichment is not seen in altered dikes suggest that the Pd originally was enriched in the more melanocratic protoliths that are most extensively altered and that Pd also was lost in part. These results are consistent with the mineralization having been a high-temperature event that predated the amphibolite/greenschist alteration.     

Vertical profiling of SO2 and SO above Venus’ clouds by SPICAV/SOIR solar occultations

New measurements of sulfur dioxide (SO₂) and monoxide (SO) in the atmosphere of Venus by SPICAV/SOIR instrument onboard Venus Express orbiter provide ample statistics to study the behavior of these gases above Venus’ clouds. The instrument (a set of three spectrometers) is capable to sound atmospheric structure above the clouds in several observation modes (nadir, solar and stellar occultations) either in the UV or in the near IR spectral ranges. We present the results from solar occultations in the absorption ranges of SO₂ (190–230 nm, and at 4 μm) and SO (190–230 nm). The dioxide was detected by the SOIR spectrometer at the altitudes of 65–80 km in the IR and by the SPICAV spectrometer at 85–105 km in the UV. The monoxide’s absorption was measured only by SPICAV at 85–105 km. We analyzed 39 sessions of solar occultation, where boresights of both spectrometers are oriented identically, to provide complete vertical profiling of SO₂ of the Venus’ mesosphere (65–105 km). Here we report the first firm detection and measurements of two SO₂ layers. In the lower layer SO₂ mixing ratio is within 0.02–0.5 ppmv. The upper layer, also conceivable from microwave measurements by Sandor et al. (Sandor, B.J., Todd Clancy, R., Moriarty-Schieven, G., Mills, F.P. [2010]. Icarus 208, 49–60) is characterized by SO₂ increasing with the altitude from 0.05 to 2 ppmv, and the [SO₂]/[SO] ratio varying from 1 to 5. The presence of the high-altitude SO_x species could be explained by H₂SO₄ photodissociation under somewhat warmer temperature conditions in Venus mesosphere. At 90–100 km the content of the sulfur dioxide correlates with temperature increasing from 0.1 ppmv at 165–170 K to 0.5–1 ppmv at 190–192 K. It supports the hypothesis of SO₂ production by the evaporation of H₂SO₄ from droplets and its subsequent photolysis at around 100 km.     

Modelling sediment dynamics due to hillslope–river interactions: incorporating fluvial behaviour in landscape evolution model LAPSUS

Landscape evolution models (LEMs) simulate the three‐dimensional development of landscapes over time. Different LEMs have different foci, e.g. erosional behaviour, river dynamics, the fluvial domain, hillslopes or a combination. LEM LAPSUS is a relatively simple cellular model operating on timescales of centuries to millennia and using annual timesteps that has had a hillslope focus. Our objective was to incorporate fluvial behaviour in LAPSUS without changing the existing model equations. The model should be able to reproduce alternating aggradation and incision in the floodplains of catchments, depending on simulated conditions. Testing was done using an artificial digital elevation model (DEM) and a demonstration of the ability for fluvial simulation was performed for a real landscape (Torrealvilla catchment, southeast Spain). Model equations to calculate sediment dynamics and water routing were similar for both hillslope and fluvial conditions, but different parameter values were used for these domains, defined based on annual discharge. Parameters changing between the domains are convergence factor p, which is used in the multiple flow algorithm to route water, and discharge and gradient exponents m and n, used in transport capacity calculations. Erodibility and ‘sedimentability’ factors K and P were changed between cold (little vegetation, high erodibility) and warm conditions (more vegetation, lower erodibility). Results show that the adapted parameters reproduced alternating aggradation – due to divergent flow in the floodplain and sediment supply under cold conditions – and incision due to reduced sediment supply and resulting clean water erosion during simulated warm conditions. The simulated results are due to interactions between hillslopes and floodplains, as the former provide the sediments that are deposited in the latter. Similar behaviour was demonstrated when using the real DEM. Sensitivity and resolution analysis showed that the model is sensitive to changes in m, n and p and that model behaviour is influenced by DEM resolution. Copyright © 2012 John Wiley & Sons, Ltd.     

Sedimentological and geochemical records of past trophic state and hypolimnetic anoxia in large,hard-water Lake Bourget,French Alps

Sedimentological, geochemical and particle-size analyses were used to reconstruct the evolution of both trophic state and hypolimnetic anoxia in Lake Bourget (French Alps) during the last century. Radionuclide dating (²¹⁰Pb, ¹³⁷Cs and ²⁴¹Am) confirmed the annual rhythm of laminations in the upper sediment profile. In Lake Bourget, biochemical varves are triplets composed of a diatom layer (spring lamina), a bio-precipitated calcite-rich layer (spring/summer lamina), and a layer rich in organic matter and detrital particles (winter lamina). The onset of eutrophication and the first appearance of an anoxic facies occurred simultaneously and were dated by laminae counting to AD 1943±1 year. Persistent anoxic conditions began in AD 1960. Eutrophication is characterised by drastic increases in the flux of biogenic silica (mostly diatoms), lacustrine organic matter, and larger calcite crystals (15–30 μm). The increase of organic matter also represents a marker of the onset of anoxic conditions in the hypolimnion. Our results show that eutrophication was the main factor controlling anoxia in the hypolimnion. This eutrophication was caused mostly by the inflow of untreated sewage effluents, and to a lesser extent, by input of fertilizer-derived phosphorus during floods of the Rhone River and run-off from the lake catchment. The Rhone River, however, can also be a source of re-oxygenation via underflows that originate during flood events. Oxygenation of the hypolimnion is also controlled by low winter temperatures, which enable turnover of the lake. Thus, global warming, associated with a forecasted reduction in precipitation, might reduce the efficiency of hypolimnetic re-oxygenation in Lake Bourget.     

The trace element compositions of S-type granites: evidence for disequilibrium melting and accessory phase entrainment in the source

Within individual plutons, the trace element concentrations in S-type granites generally increase with maficity (total iron and magnesium content and expressed as atomic Fe + Mg in this study); the degree of variability in trace element concentration also expands markedly with the same parameter. The strongly peraluminous, high-level S-type granites of the Peninsular Pluton (Cape Granite Suite, South Africa) are the product of biotite incongruent melting of a metasedimentary source near the base of the crust. Leucogranites within the suite represent close to pure melts from the anatectic source and more mafic varieties represent mixtures of melt and peritectic garnet and ilmenite. Trace elements such as Rb, Ba, Sr and Eu, that are concentrated in reactant minerals in the melting process, show considerable scatter within the granites. This is interpreted to reflect compositional variation in the source. In contrast, elements such as LREE, Zr and Hf, which are concentrated within refractory accessory phases (zircon and monazite), show well-defined negative correlations with increasing SiO₂ and increase linearly with increasing maficity. This is interpreted to reflect coupled co-entrainment of accessory minerals and peritectic phases to the melt: leucocratic rocks cannot have evolved from the more mafic compositions in the suite by a process of fractional crystallisation because in this case they would have inherited the zircon-saturated character of this hypothetical earlier magma. Trace element behaviour of granites from the Peninsular Pluton has been modelled via both equilibrium and disequilibrium trace element melting. In the disequilibrium case, melts are modelled as leaving the source with variable proportions of entrained peritectic phases and accessory minerals, but before the melt has dissolved any accessory minerals. Thus, the trace element signature of the melt is largely inherited from the reactants in the melting reaction, with no contribution from zircon and monazite dissolution. In the equilibrium case, melt leaves the source with entrained crystals, after reaching zircon and monazite saturation. A significant proportion of the rocks of the Peninsular Pluton have trace element concentrations below those predicted by zircon and monazite saturation. In the case of the most leucocratic rocks all compositions are zircon undersaturated; whilst the majority of the most mafic compositions are zircon oversaturated. However, in both cases, zircon is commonly xenocrystic. Thus, the leucocratic rocks represent close to pure melts, which escaped their sources rapidly enough that some very closely match the trace element disequilibrium melting model applied in this study. Zircon dissolution rates allow the residency time for the melt in the source to be conservatively estimated at less than 500 years.     

A multiplex imaging spectrometer for low energyX-ray astronomy

A multiplexX-ray image analyser is described. It consists in a time-modulated coded aperture associated with a solid state detector. The system combines the high efficiency and good spectral resolution of solid state spectrometers with the spatial resolution of the coded aperture (200 ).The device can be installed at the focus of a grazing incidence telescope to make images and spectra of faint astronomicalX-ray sources.     

Improving MODIS Spatial Resolution for Snow Mapping Using Wavelet Fusion and ARSIS Concept

We propose to fuse the high spatial content of two 250-m spectral bands of the moderate resolution imaging spectroradiometer (MODIS) into its five 500-m bands using wavelet-based multiresolution analysis. Our objective was to test the effectiveness of this technique to increase the accuracy of snow mapping in mountainous environments. To assess the performance of this approach, we took advantage of the simultaneity between the advanced spaceborne thermal emission and reflection radiometer (ASTER) and MODIS sensors. With a 15-m spatial resolution, the ASTER sensor provided reference snow maps, which were then compared to MODIS-derived snow maps. The benefit of the method was assessed through the investigation of various metrics, which showed an improvement from 3% to 20%. Therefore, the enhanced snow map is of great benefit for environmental and hydrological applications in steep terrain.