Sr and Pb isotopic composition of five USGS glasses (BHVO-2G, BIR-1G, BCR-2G, TB-1G, NKT-1G)

Sr isotopic compositions and Rb / Sr ratios of three USGS glasses (BHVO-2G, BIR-1G, BCR-2G) are identical to those of the original USGS reference materials. NKT-1G and TB-1G give values of 0.70351 and 0.70558, respectively. Pb isotopic ratios were measured by the standard-sample bracketing technique on an MC-ICP-MS, which give results that are comparable in accuracy and reproducibility to double spike analyses. However, assessment of the reproducibility of the technique is hampered by inhomogeneous contamination of all USGS reference materials analysed. This contamination is likely to be the reason why the USGS glasses do not all have the same Pb isotopic composition as their unfused originals. Powdered glasses, distributed for characterisation of the glasses by bulk analytical techniques, do not all have the same Pb isotopic compositions as the solid glass material, and can therefore not be used for this purpose.     

Analysis with C- and X-band satellite SAR data of the Portalet landslide area

This paper describes the use of the Stable Point Network technique, a Persistent Scatterer Interferometry SAR technique, for the analysis of the Portalet landslide area (Central Pyrenees, Spain). For this purpose, different SAR datasets acquired by ERS-1, ERS-2, ENVISAT and TerraSAR-X satellites have been analysed. The use of different SAR images acquired by satellite radar sensors operating at different microwave lengths has allowed for a comparative assessment and illustration of the advantages and disadvantages of these satellites for landslide detection and monitoring. In the introduction, differential interferometry and the study area are briefly described. Then the specifics of the SPN processing and the results of the different datasets are described and compared. In Analysis of the results: the Portalet landslide area, the Portalet landslide area is introduced and the radar displacement measurements are analysed with available geo-information data. Additionally, X-band measurements are compared with those gathered by a ground-based SAR for a previous project. Finally, the most relevant conclusions of this work are discussed.     

Pollution au plomb dans la Savoie antique (II–IIIe s. apr. J.-C.) en relation avec une installation métallurgique de la cité de Vienne

In Lake Anterne (NW French Alps), the Roman period is characterised by a lead contamination more important than that of the 1970s, due to the use of leaded gasoline. The maximum of this contamination period has been varve-dated 220 AD, i.e., during the optimum of Roman civilization in the Alps. Crossing palaeoenvironmental and archaeological evidences points out the economic importance of the town of Passy for the City of Vienne and yields a new example of lead contamination due to local metallurgical activity rather than distant impact of the exploitation of the Spanish Rio Tinto mine. To cite this article: F. Arnaud et al., C. R. Geoscience 338 (2005).     

Long-core profiles of137Cs,134Cs,60Co and210Pb in sediment near the Rhône River (Northwestern Mediterranean Sea)

Various anthropogenic radionuclides and²¹⁰Pb were analyzed in a 4.3-m-long core, sampled near the Rhône River mouth in March 1991, to evaluate the extent of industrial releases that accumulate in this area. The whole core was significantly marked by radionuclide inputs from the nuclear facilities located along the river (¹³⁷Cs,¹³⁴Cs,⁶⁰Co). Irregular profiles in natural and artificial radionuclides should be related to variations in their respective inputs from the Rhône River to the Mediterranean Sea. Minimum concentrations were found during high flow periods. Using both the¹³⁷Cs/¹³⁴Cs profile in the core and the range of this ratio in Rhône waters, mean apparent accumulation rates were estimated to range between 37 cm yr^?1 and 48 cm yr^?1. This core would then represent a sedimentary record over a 7–10 year period. However, the presence of a signal from the Chernobyl accident, which occurred on April 26, 1986, was not clearly observed in the core. Inventories of both artificial and natural radionuclides were greater than expected from atmospheric inputs. The increased sedimentation occurring in close vicinity to the mouth of the Rhône River is thus responsible for trapping of elements transported by the river to the Mediterranean Sea. In this area, inventories of artificial radionuclides are well in excess of aerial deposition from Chernobyl and atmospheric weapons tests and are linked primarily to industrial releases.     

Subduction of the South Chile active spreading ridge: A 17 Ma to 3 Ma magmatic record in central Patagonia (western edge of Meseta del Lago Buenos Aires,Argentina)

The Chile Triple Junction is a natural laboratory to study the interactions between magmatism and tectonics during the subduction of an active spreading ridge beneath a continent. The MLBA plateau (Meseta del Lago Buenos Aires) is one of the Neogene alkali basaltic plateaus located in the back-arc region of the Andean Cordillera at the latitude of the current Chile Triple Junction. The genesis of MLBA can be related with successive opening of slabs windows beneath Patagonia: within the subducting Nazca Plate itself and between the Nazca and Antarctic plates. Detailed ⁴⁰Ar/³⁹Ar dating and geochemical analysis of bimodal magmatism from the western flank of the MLBA show major changes in the back-arc magmatism which occurred between 14.5 Ma and 12.5 Ma with the transition from calc-alkaline lavas (Cerro Plomo) to alkaline lavas (MLBA) in relation with slab window opening. In a second step, at 4–3 Ma, alkaline felsic intrusions were emplaced in the western flank of the MLBA coevally with the MLBA basalts with which they are genetically related. These late OIB-like alkaline to transitional basalts were generated by partial melting of the subslab asthenosphere of the subducting Nazca plate during the opening of the South Chile spreading ridge-related slab window. These basalts differentiated with small amounts of assimilation in shallow magma chambers emplaced along transtensional to extensional zones. The close association of bimodal magmatism with extensional tectonic features in the western MLBA is a strong support to the model of Patagonian collapse event proposed to have taken place between 5 and 3 Ma as a consequence of the presence of the asthenospheric window (SCR-1 segment of South Chile Ridge) below the MLBA area.     

The Lac Des Iles Palladium Deposit,Ontario, Canada part I. The effect of variable alteration on the Offset Zone

The recently discovered Offset Zone of the Mine Block Intrusion of the Lac des Iles Complex hosts palladium mineralization with unusually high Pd/Pt and Pd/Ir ratios in rocks that range from relatively unaltered norite to amphibolites and chlorite–actinolite–talc schist. Quantitative assessment of the effect of progressive alteration using mineral modes was done using total silicate H₂O as a monitor of reaction progress (ξ = moles H₂O added to form alteration minerals per 100 g of rock). Major mineral modal variations define three reaction regions: (1) ξ?=?0.00–0.03, characterized by epidote/clinozoisite formation and some amphibole; (2) ξ?=?0.03–0.23, characterized by formation of chlorite, amphibole, quartz muscovite/sericite, and calcite after plagioclase?+?pyroxene; and (3) ξ?=?0.23–0.28, characterized by the formation of talc after earlier formed amphibole. Epidote occurs as an incongruent product from the destruction of plagioclase that is itself lost as the reaction proceeds. Pyroxene is altered at about twice the rate of plagioclase, resulting in pyroxene-rich protoliths to be more altered than those relatively enriched in plagioclase. Major elements variations largely reflect variations in the plagioclase/pyroxene ratio of the protolith, but compositional trends suggest a loss of Na with reaction progress. The base metal sulfides chalcopyrite, pyrrhotite, and pentlandite show decreasing abundance with reaction progress, forming pyrite (± magnetite) as an intermediate reaction product that also is lost as the reaction proceeds. Millerite is overall low but increases slightly. A more limited data set on the platinum-group minerals suggests that platinum-group element (PGE)-arsenides increase whereas PGE-sulfides and PGE-Bi-tellurides decrease with reaction progress. Assuming ore element concentrations in the protolith were constant and similar to relatively fresh norites, Pd increases modestly, by 5 %, whereas Pt decreases by about 65 % in the most altered rocks. Similarly, Cu, Au, and S decrease by 60, 82, and 94 %, respectively, in the most altered rocks. The antithetical behavior of Pd and the fact that Pd enrichment is not seen in altered dikes suggest that the Pd originally was enriched in the more melanocratic protoliths that are most extensively altered and that Pd also was lost in part. These results are consistent with the mineralization having been a high-temperature event that predated the amphibolite/greenschist alteration.     

The grain-size characterisation of coastal sand from the Somme estuary to Belgium: Sediment sorting processes and mixing in a tide- and storm-dominated setting

Sand-rich Holocene to modern clastic deposits in the eastern English Channel and the southern North Sea coasts of France and Belgium occur extensively as nearshore-sand bank, estuarine-tidal flat, aeolian dune and beach sub-environments. Sand samples (n = 665) collected from these deposits suggest the presence of three different populations: a largely dominant (83%) medium to fine quartz sand population (“b”), and finer- (14%) and coarser-grained (4%) populations (respectively “c” and “a”). The distribution of these populations among the four sub-environments reflects tide- and storm-dominated sorting and transport processes and a variable degree of mixing. These populations are derived from a mixture of very fine- to very coarse-grained fluvial, outwash and paraglacial sediments deposited on the beds of the eastern English Channel and southern North Sea during the late Pleistocene lowstand. The nearshore-sand bank environment, which also corresponds to the main offshore source area of the coastal deposits, exhibits population heterogeneity reflecting the variability of hydrodynamic conditions and sediment sorting in this zone. The nearshore topography of tidal ridges, banks and troughs in these tidal seas leads to variable bed and tide- and storm-induced shear stress conditions. These conditions only allow for the mobilisation and onshore transport of some of the finer fractions (populations “b” and “c”), leaving an offshore mixture of these finer populations with coarser, less mobilisable sediments (population “a”). Once in the coastal zone, these two finer populations undergo further hydrodynamic sorting and segregation. Variably sorted very fine sands to silts (population “c”) are trapped in the low-energy estuarine-tidal flat sub-environment, while the highly homogeneous population “b” is further sorted in aeolian dune and beach sub-environments. This sorting occurs via a coastal sand transport pathway linking the Somme estuary mouth to the southern North Sea bight where tidal range and wave energy decrease relative to the English Channel. Since this sand transport pathway enables longshore transport of hydrodynamically sorted medium to fine sand derived directly from the immediate nearshore zone, it has further contributed to a net flux of this sand population from the eastern English Channel sea bed to the southern North Sea.     

Using Climber's Guidebooks to Assess Rock Fall Patterns Over Large Spatial and Decadal Temporal Scales: An Example from the Swiss Alps

High‐mountain geomorphic processes enjoy increasing scientific and societal interest. This is because these processes are perceived to be changing more than elsewhere and because their effects on infrastructure and tourism are significant. Rock fall is among the processes that receive most attention due to its presumed intimate relation with permafrost, which is widely degrading. However, over decadal temporal scales and for entire mountain ranges, there is very limited information on the changes in frequency and location of rock fall. This hampers our understanding. Here, I assess the value of information contained in a 146‐year record of climber's guidebooks of the Bernese Alps in Switzerland to derive changes in rock fall danger. The results show that guidebooks’ authors, themselves experienced climbers, perceived increases in rates and changes in positions of rock fall. The increases were mainly reported since the year 2000. It appears that datasets derived from guidebooks can provide valuable context for more detailed, higher resolution data sources.     

40Ar–39Ar geochronology across Archean and Paleoproterozoic terranes from southeastern Guiana Shield (north of Amazonian Craton,Brazil): Evidence for contrasting cooling histories

A ⁴⁰Ar/³⁹Ar geochronological study was performed on amphibole and biotite from some representative units of distinct tectonic domains of the southeastern Guiana Shield, north of the Amazonian Craton, the Amapá Block and the Carecuru Domain. In the Amapá Block, an Archean continental block involved in the Transamazonian orogenesis (2.26–1.95 Ga), the investigated minerals, from rocks of the Archean high-grade basement assemblage, give only Paleoproterozoic ages, indicating their complete resetting during the Transamazonian orogenic event. Amphibole ages vary from 2087 ± 3 to 2047 ± 20 Ma, and biotite ages spread mainly between 2079 ± 18 and 2033 ± 13 Ma. In the Carecuru Domain, in which the geodynamic evolution is related to Paleoproterozoic magmatic arc setting during the Transamazonian event, calc-alkaline granitoids yield amphibole age of 2074 ± 17 Ma, and biotite ages of 1928 ± 19 Ma and 1833 ± 13 Ma.These data reinforce the importance of the Transamazonian orogenic cycle in the investigated area, and indicate that the rocks were not significantly affected by post-Transamazonian events. When coupled with available U–Th–Pb monazite and Pb–Pb zircon geochronological records and petro-structural observations, the new ⁴⁰Ar/³⁹Ar data delineate contrasting cooling and exhumation histories for the tectonic domains. In the Amapá Block, the data suggest nearly vertical T–t paths that reflect fast cooling rates, which indicate tectonically controlled exhumation, related to collisional stages of the Transamazonian event, between 2.10 and 2.08 Ga. Conversely, in the Carecuru Domain, low cooling rates suggest that the arc-related granitoids underwent slow and monotonous cooling since their emplacement until reaching the biotite isotopic closure temperature.