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171.
Regina M.B.O. Duarte Casimiro A. Pio Armando C. Duarte 《Journal of Atmospheric Chemistry》2004,48(2):157-171
Three-dimensional excitation–emission matrix (EEM) fluorescence spectra of water-soluble organic compounds (WSOC) from aerosol samples were measured and compared with those reported in the literature for natural dissolved organic matter. The EEM profiles of the WSOC presented three characteristic excitation/emission (Exc/Em) peaks: 240/405 nm, 310/405 nm and 280/340 nm. The fluorescence intensities at Exc/Em240/405 nm and Exc/Em310/405 nm are located at wavelengths shorter than those reported for aquatic humic substances, indicating a smaller content of both aromatic structures and condensed unsaturated bond systems in the WSOC fraction. The EEM profiles of fractions obtained by the isolation procedure of the WSOC by the XAD resins showed that a fractionation has occurred and the XAD-8 eluate is highly representative of the total WSOC of collected aerosol. Synchronous scan spectra were more detailed than conventional fluorescence emission spectra, appearing more suitable for studying multicomponent samples such as the WSOC from atmospheric aerosols. 相似文献
172.
In this paper we study the interaction of rotation with convection in a deep compressible spherical shell as the Sun's convection zone. We examine how the energy transport and the large scale motions can be affected by rotation. In particular we study how a large scale meridional circulation can give rise to variations of angular velocity with latitude and depth.It is assumed that the energy transport is only due to convection and that the mixing-length theory gives an adequate representation of it. Furthermore we assume that rotation acts as a perturbation of the turbulent convective flux through its transport coefficient.The equations involved in the model are integrated numerically in the limit of large viscosity and slow rotation. After having expanded all physical quantities to the first order in terms of Legendre polynomials, the fitting with the observed solar differential rotation gives the expansion parameter, which represents the coupling constant between rotation and convection.The results show a three-cell circulation extending from the poles to the equator. The first one is located in the lower half of the convection zone with the fluid rising at the equator and sinking at the poles. In the second one the direction of the motion is reversed while the third one, located in a thin upper layer, shows the same characteristics of the first one. The meridional velocities at the surface are directed towards the poles and are about 20 cm s-1. In the other cells the meridional velocities are typically of a few cm s-1 while the radial velocities are of the order of a few tenths of cm s-1.The heat flux relative variation at the surface is about 10-4 (3 × 10-3 at the bottom) with a polar excess. The temperature variation at the surface is of the same order, with an equatorial excess however. The convection seems to be stabilized stronger at the equator. The angular velocity increases inwards and varies about 6% between the surface and the bottom of the convection zone.An attempt is made for explaining the picture which emerges. In particular the negligible flux and temperature variations at the surface are explained in terms of equalization by the particular structure of the latitudinal flow. This configuration of large scale circulation is attributed to the high stratification of the convection zone with depth. 相似文献
173.
Voyager full-disk images of Io, available at solar phase angle of α = 2?29° and 101?159°, allow comparisons of the satellite's near-opposition photometric behavior with Earth-based results and the determination of the phase curve out to very high phase angles. The near-opposition data were reduced iteratively for self-consistent phase and rotation curves in each Voyager filter; the resulting phase coefficients, geometric albedos, and rotational lightcurves are consistent with Earth-based findings, except for a previously noted tendency for Voyager to yield somewhat redder spectral information. The derived near-opposition phase coefficients, ranging between 0.016 and 0.024 mag/ deg, decrease with increasing wavelength, a trend weakly noted in some Earth-based observations. The full, α = 2?159° phase curves allow the first direct determination of the phase integral of Io at several wavelengths: q rises from ≈0.7 in the ultraviolet to ≈0.8 in the orange. Combination of the Voyager phase integrals with Earth-based albedo information leads to a best estimate of the bolometric Bond albedo of 0.50 ± 0.10, a value consistent with, but slightly below, previous estimates. 相似文献
174.
Michele Lustrino Leone Melluso Pietro Brotzu Celso B. Gomes Lucio Morbidelli Rossana Muzio Excelso Ruberti Colombo C.G. Tassinari 《Lithos》2005,82(3-4):407-434
The early Cretaceous (130 Ma) igneous complex of Valle Chico (SE Uruguay) is made up of felsic plutonic and subordinate volcanic rocks and dykes cropping out over an area of about 250 km2. This complex is strictly linked with the formation of the Paraná–Etendeka Igneous Province and the first stages of the South Atlantic Ocean rifting. The plutonic rocks range from quartz-monzonite to syenite, quartz-syenite and granite. The volcanic rocks and the dykes range from quartz-latite to trachyte and rhyolite; no substantial differences in term of chemical composition have been found between plutonic and volcanic rocks. Only a sample of basaltic composition (with tholeiitic affinity) has been sampled associated with the felsic rocks. The Agpaitic Index of the Valle Chico felsic rocks range from 0.72 to 1.34, with the peralkaline terms confined in the most evolved samples (SiO2>65 wt.%). Initial 87Sr/86Sr(130) of the felsic rocks range from 0.7046 to 0.7201, but the range of 87Sr/86Sr of low-Rb/Sr samples cluster at 0.7083; 143Nd/144Nd(130) ratios range from 0.5121 (syenite) to 0.5117 (granite). The tholeiitic basalt show more depleted isotopic compositions (87Sr/86Sr(130)=0.7061; 143Nd/144Nd(130)=0.5122), and plots in the field of other early Cretaceous low-Ti basaltic rocks of SE Uruguay. The radiogenic Sr and unradiogenic Nd of the Valle Chico felsic rocks require involvement of lower crustal material in their genesis either as melt contaminant or as protolith (crustal anatexis). In particular, most of the Valle Chico (VC) felsic rocks define a near-vertical array in Sr–Nd isotopic spaces, pointing toward classical EMI-type composition; this feature is considered to reflect a lower crust involvement as observed for other mafic and felsic rocks of the Paraná–Etendeka Igneous Province. Decompression melting of the lower crust related to Gondwana continental rifting before the opening of the South Atlantic Ocean or the presence of thermal anomalies related to the Tristan plume may have induced the lower crust to partially melt. Alternative hypothesis considers contamination of upper mantle by a mafic/ultramafic keel composed of lower crust and uppermost mantle after delamination and detachment processes. This interaction may have occurred after the continent–continent collision during the last stages of the Panafrican Orogeny. This “lower crust” model does not exclude active involvement of upper crust as contaminant, necessary to explain the strongly radiogenic 87Sr/86Sr(130) isotopic composition of some VC SiO2-rich rocks. Mineralogical (sporadic presence of pigeonite, Ca–Na and Na clinopyroxene, calcic- and calco-sodic amphibole) and geochemical evidences (major and trace element as well as Sr–Nd isotopic similarities with the felsic early Cretaceous volcanic rocks of the Arequita Formation in SE Uruguay) allow us to propose for the VC rocks a transitional rock series (the most abundant rock types are of syenitic/trachytic composition) preferentially evolving towards SiO2-oversaturated compositions (granite/rhyolite) also with a strong upper crustal contribution as melt contaminant. This conclusion is in contrast with previous studies according which the VC complex had clear alkaline affinity. Many similarities between VC and the coeval Paresis granitoids (Etendeka, Namibia) are evidenced in this paper. The genetic similarities between VC and the rhyolites (s.l.) of SE Uruguay may find counterparts with the genetic link existing between the early Cretaceous tholeiitic-alkaline Messum complex and the quartz latites (s.l.) of the Awahab Formation (Etendeka region, Namibia). 相似文献
175.
Mauro Di Vito Lucio Lirer Giuseppe Mastrolorenzo Giuseppe Rolandi 《Bulletin of Volcanology》1987,49(4):608-615
On 29 September 1538 a week-long eruption began in Campi Flegrei forming a new volcano, Monte Nuovo. From contemporary accounts of the eruption, it has been possible to reconstruct the main phases of activity. These phases may be correlated with different depositional units identified in the field. The eruption opened with a hydromagmatic phase, during which a large amount of external water (meteoric or sea water) was able to interact with the magma. The exhaustion of the water supply and decrease in volatile content initiated a change in the dynamic conditions of eruption, which became more purely magmatic in character and less explosive. 相似文献
176.
177.
Résumé On examine les performances des schémas numériques utilisés habituellements dans les simulations lagrangiennes réalisées à partir de modèles eulériens. Deux problèmes sont essentiellement abordés : la consistance numérique de la trajectoire lagrangienne et la fiabilité des statistique d'ensemble sur les grandeurs représentatives de la dynamique. Un critère de qualité concernant la trajectoire est proposé et analysé en fonction des degrés de régularité des schémas d'interpolation spatiale. 相似文献
178.
Lucio Pedroni 《Climate Policy》2013,13(4):407-418
Abstract The role of sinks in the clean development mechanism (CDM) has been a subject of controversy for several reasons; one being that temporary carbon storage in forests appeared to prevent any opportunity to use them as an option to reduce permanent greenhouse gas (GHG) emissions. In Milan (December 2003), the Conference of the Parties (CoP) decided to address this problem by introducing two types of expiring units: temporary CERs (tCERs) and long-term CERs (lCERs). Countries committed to emission reductions may acquire these units to temporarily offset their emissions and thus to postpone permanent emission reductions. As further decided by the CoP, baseline emissions of GHGs and the enhancement of sinks outside the project boundary will not be accounted for in the calculation of tCERs or lCERs. The contribution of CDM-sink projects to GHG emissions abatement will therefore be greater than what will be credited to them. On the other hand, permanent GHG emissions that may result as a consequence of the implementation of sink project activities are treated as non-permanent. If these emissions are above avoided baseline emissions, CDM-sinks will result in net increases of GHG emissions into the atmosphere. After briefly reassessing the non-permanence problem, this article explains how tCERs and lCERs should be quantified according to Decision 19/CP.9 of CoP-9 and how calculations are implemented in the forthcoming software CO2 Land. Using a simple numerical example, it illustrates how the GHG accounting rule adopted at CoP-9 may result in net increases of GHG emissions. In the conclusion, a possible solution to this problem is proposed. 相似文献
179.
A.?NyrowEmail author C.?Sternemann M.?Wilke R.?A.?Gordon K.?Mende H.?Yava? L.?Simonelli N.?Hiraoka Ch.?J.?Sahle S.?Huotari G.?B.?Andreozzi A.?B.?Woodland M.?Tolan J.?S.?Tse 《Contributions to Mineralogy and Petrology》2014,167(5):1012
We present a spectroscopic study of the iron \(\hbox{M}_{2/3}\)-edge for several minerals and compounds to reveal information about the oxidation state and the local coordination of iron. We describe a novel approach to probe the iron \(\hbox{M}_{2/3}\)-edge bulk sensitively using X-ray Raman scattering. Significant changes in the onset and shape of the Fe \(\hbox{M}_{2/3}\)-edge were observed on ferrous and ferric model compounds with Fe in octahedral and tetrahedral coordination. Simulation of the spectra is possible using an atomic multiplet code, which potentially allows determination of, e.g., crystal-field parameters in a quantitative manner. A protocol is discussed for determination of the Fe oxidation state in compounds by linear combination of spectra of ferric and ferrous end members. The presented results demonstrate the capabilities of Fe \(\hbox{M}_{2/3}\)-edge spectroscopy by X-ray Raman scattering to extract information on the ratio of trivalent to total iron \(\hbox{Fe}^{3+}/\sum \hbox{Fe}\) and local coordination. As X-ray Raman scattering is performed with hard X-rays, this approach is suitable for in situ experiments at high pressure and temperature. It thus may provide indispensable information on oxidation state, electronic structure and local structure of materials that are important for physical and chemical processes of the deep Earth. 相似文献
180.
Ma Carmen Ávila-López J. Martín Hernández-Ayón Víctor F. Camacho-Ibar Armando Félix Bermúdez Adan Mejía-Trejo Isaí Pacheco-Ruiz Jose M. Sandoval-Gil 《Estuaries and Coasts》2017,40(3):792-806
The present study examines the temporal variability of air–water CO2 fluxes (FCO2) and seawater carbonate chemistry in a Baja California coastal lagoon during an exceptionally warm anomaly that was developed in Northeast Pacific coasts during 2014. This oceanographic condition led to a summer-like season (weak upwelling condition) during the study period, which reached a maximum surface temperature anomaly of 2 °C in September 2014. San Quintín Bay acts as a source of CO2 to the atmosphere in 2014 (3.3 ± 4.8 mmol C m?2 day?1) with the higher positive fluxes mainly observed in summer months (9.0 ± 5.3 mmol C m?2 day?1). Net ecosystem production (NEP) switched seasonally between net heterotrophy and net autotrophy during the study period, with an annual average of 2.2 ± 7.1 mmol C m?2 day?1, which indicates that San Quintín Bay was a net autotrophic system during the atypical warm oceanographic condition in 2014. This pattern of seasonal variations in the carbon balance at San Quintín Bay appears to be linked to the life cycle of benthic communities, which play an important role in the whole-ecosystem metabolism. Under the limited input from external sources coupled with an increase in seawater temperatures, the recycled benthic carbon and nutrient fluxes play a major role to sustain water-column processes within the bay. Since the upwelling condition may influence the magnitude of the air–water CO2 fluxes, our results clearly indicated that San Quintín Bay is a net source of carbon to the atmosphere regardless of the adjacent oceanic conditions. Our study sheds light on the carbon dynamics and its metabolic implications in a shallow coastal ecosystem under a regional warm anomaly and contributes potentially relevant information in view of the likely future scenario of global climate change. 相似文献