The use of sulfur to extract hydrogen from coal

The world's recoverable coal reserves contain about 3 × 10¹⁰ tons of hydrogen. The reaction of sulfur vapor with medium-volatile bituminous coal produces hydrogen sulfide in yields up to 97% (based on sulfur), and utilizes 70–75% of the hydrogen from the coal. The conversion of hydrogen sulfide to hydrogen can be effected through commercially proven processes; several laboratory-scale processes could also be scaled up for future use. The solid by-product of the coal–sulfur reaction meets or exceeds specifications for fixed carbon, ash, and friability of conventional metallurgical coke, though produced at lower temperatures than typical by-product coke ovens. A conceptual process is presented in which sulfur is converted to hydrogen sulfide by reaction with coal, the hydrogen sulfide in turn is converted to the desired hydrogen and to sulfur, and the sulfur is recycled through the reactor. The by-product is a good quality coke, but may also have other applications as a carbon material.     

River channel response to short-term human-induced change in landscape connectivity in Andean ecosystems

The drainage basin of the Deleg River (88 km²), located in the southern Ecuadorian Andes, was studied to assess the geomorphic and hydrologic response of a fluvial system to human-induced environmental change in its contributing area. Historical data on land use, channel morphology and sedimentology were collected, based on a spatial analysis of aerial photographs (1963–1995) and a field survey (2002). Analysis of channel cross-sectional profiles and sedimentological data revealed a major change in morphology and sedimentology of the Deleg River during the past four decades: (i) the active river channel narrowed by over 45%, (ii) the riverbed incised on average by over 1.0 m and (iii) the median grain size of the bed surface decreased from 13.2 cm to 4.7 cm. The spatial pattern of land cover within the Deleg catchment also changed considerably: highly degraded agricultural land in the low-lying areas was abandoned and partially afforested for timber and wood production, whereas secondary upland forest was increasingly cleared for expansion of cropland and pastures. Notwithstanding large changes in the spatial organization of land use within the catchment, the overall land use did not change significantly during the past four decades. This suggests that the response of the Deleg River to land-use change not only depends on the overall land-use change, but also on the spatial pattern of land-use/cover change within the catchment. Although forestation and regeneration of bare gully slopes and floors throughout the catchment only represented a minor part of the total land-use change, these land-use/cover changes had a major impact on the hydrological and sediment connectivity in the landscape.     

Influence of dynamic soil–structure interaction on the nonlinear response and seismic reliability of multistorey systems

A set of reinforced concrete structures with gravitational loads and mechanical properties (strength and stiffness) representative of systems designed for earthquake resistance in accordance with current criteria and methods is selected to study the influence of dynamic soil–structure interaction on seismic response, ductility demands and reliability levels. The buildings are considered located at soft soil sites in the Valley of Mexico and subjected to ground motion time histories simulated in accordance with characteristic parameters of the maximum probable earthquake likely to occur during the system's expected life. For the near‐resonance condition the effects of soil–structure interaction on the ductility demands depend mainly on radiation damping. According to the geometry of the structures studied this damping is strongly correlated with the aspect ratio, obtained by dividing the building height by its width. In this way, for structures with aspect ratio greater than 1.4 the storey and global ductility demands increase with respect to those obtained with the same structures but on rigid base, while for structures with aspect ratio less than 1.4 the ductility demands decrease with respect to those for the structures on rigid base. For the cases when the fundamental period of the structure has values very different from the dominant ground period, soil–structure interaction leads in all cases to a reduction of the ductility demands, independently of the aspect ratio. The reliability index β is obtained as a function of the base shear ratio and of the seismic intensity acting on the nonlinear systems subjected to the simulated motions. The resulting reliability functions are very similar for systems on rigid or on flexible foundation, provided that in the latter case the base rotation and the lateral displacement are removed from the total response of the system. Copyright © 2006 John Wiley & Sons, Ltd.     

The final Galileo SSI observations of Io: orbits G28-I33

We present the observations of Io acquired by the Solid State Imaging (SSI) experiment during the Galileo Millennium Mission (GMM) and the strategy we used to plan the exploration of Io. Despite Galileo's tight restrictions on data volume and downlink capability and several spacecraft and camera anomalies due to the intense radiation close to Jupiter, there were many successful SSI observations during GMM. Four giant, high-latitude plumes, including the largest plume ever observed on Io, were documented over a period of eight months; only faint evidence of such plumes had been seen since the Voyager 2 encounter, despite monitoring by Galileo during the previous five years. Moreover, the source of one of the plumes was Tvashtar Catena, demonstrating that a single site can exhibit remarkably diverse eruption styles—from a curtain of lava fountains, to extensive surface flows, and finally a ∼400 km high plume—over a relatively short period of time (∼13 months between orbits I25 and G29). Despite this substantial activity, no evidence of any truly new volcanic center was seen during the six years of Galileo observations. The recent observations also revealed details of mass wasting processes acting on Io. Slumping and landsliding dominate and occur in close proximity to each other, demonstrating spatial variation in material properties over distances of several kilometers. However, despite the ubiquitous evidence for mass wasting, the rate of volcanic resurfacing seems to dominate; the floors of paterae in proximity to mountains are generally free of debris. Finally, the highest resolution observations obtained during Galileo's final encounters with Io provided further evidence for a wide diversity of surface processes at work on Io.     

Cultural Globalization,Global English,and Geography Journals

In this paper we review the debate on cultural globalization and examine the rise of English as a form of global communication. The implications of these trends for the geographical community are discussed in an analysis of the use of English in geography journals. We note the increasing number of journals published in English, measure the proportion of contributions from non‐English‐speaking countries in English language journals, and note the language practice of selected journals. We conclude that there has been a trend towards linguistic homogenization and raise the question: what are the implications of a geographical discourse dominated by just one language?     

K-ar ages of the yemen plateau

The temporal evolution of the Yemen Trap series is examined in the light of K-Ar radiometric data.Rifting and volcanic activity characterize the Yemen plateau between 30 and 20 m.y. confirming a fairly common history of the Afro-Arabian plate on both sides of the Red Sea.     

Seasonal abundance and diversity of spiders in two intertidal marsh plant communities

The spiders of two Mississippi marsh communities were studied from January 1982 through March 1983. Monthly collections were made in two adjacent marsh plant zones dominated bySpartina cynosuroides (L.) Roth andJuncus roemerianus Scheele respectively. A total of 38 species of spiders (36 inSpartina, 33 inJuncus) representing 13 families were collected. The dominant species in theSpartina zone includedPirata mayaca Gertsch,Lycosa watsoni Gertsch (Lycosidae),Clubiona saltitans Emerton,Scotinella formica (Banks) (Clubionidae),Floricormus sp. (Linyphiidae),Dictyna sylvania Chamberlin & Ivie (Dictynidae),Paramaevia hobbsae (Barnes) (Salticidae), andAgelenopsis barrowsi Gertsch (Agelenidae). The dominant species in theJuncus zone includedLycosa watsoni, Pirata mayaca, Clubiona saltitans andSarinda hentzi (Banks) (Salticidae). Density, biomass, species richness and equitability peaked in May in theJuncus zone and in June in theSpartina zone. Peak levels of density and biomass corresponded to the reproductive activity of the common species, while diversity patterns were attributable to the reproductive activity of the less common species. Mean values of density and biomass over the study period were 84.8 spiders per m² and 155.6 mg per m² in theSpartina zone and 39.4 spiders per m² and 133.0 mg per m² inJuncus zone. The Juncus zone was flooded more frequently, contained less litter, and supported lower overall density and diversity of spiders.     

3D multivalued travel time and amplitude maps

An algorithm for computing multivalued maps for travel time, amplitude and any other ray related variable in 3D smooth velocity models is presented. It is based on the construction of successive isochrons by tracing a uniformly dense discrete set of rays by fixed travel-time steps. Ray tracing is based on Hamiltonian formulation and includes computation of paraxial matrices. A ray density criterion ensures uniform ray density along isochrons over the entire ray field including caustics. Applications to complex models are shown.