Deuterium content of humic acids from marine and non-marine environments

Deuterium values obtained for humic acids isolated from marine sediments from the NE Pacific are in the range of $\text{δ}\text{D}\text{= (?105 ± 5)‰}$, corresponding to values obtained for marine plankton from the same area. Soil humic acids have a much broader range of δD values (?57 to ?97‰), depending on the isotopic values of the precipitation and the isotopic composition of the parent plant precursor.Data obtained on hydrogen isotope distribution confirms previous hypotheses based on chemical analysis and on carbon isotopes, which indicated the authigenic nature of marine humates.     

Triangulating Social Multimedia Content for Event Localization using Flickr and Twitter

The analysis of social media content for the extraction of geospatial information and event‐related knowledge has recently received substantial attention. In this article we present an approach that leverages the complementary nature of social multimedia content by utilizing heterogeneous sources of social media feeds to assess the impact area of a natural disaster. More specifically, we introduce a novel social multimedia triangulation process that uses both Twitter and Flickr content in an integrated two‐step process: Twitter content is used to identify toponym references associated with a disaster; this information is then used to provide approximate orientation for the associated Flickr imagery, allowing us to delineate the impact area as the overlap of multiple view footprints. In this approach, we practically crowdsource approximate orientations from Twitter content and use this information to orient Flickr imagery accordingly and identify the impact area through viewshed analysis and viewpoint integration. This approach enables us to avoid computationally intensive image analysis tasks associated with traditional image orientation, while allowing us to triangulate numerous images by having them pointed towards the crowdsourced toponym location. The article presents our approach and demonstrates its performance using a real‐world wildfire event as a representative application case study.     

Laboratory examination of linearity in rainfall–runoff relationships

ABSTRACT

Certain rainfall–runoff models, e.g. the unit hydrograph, assume linear relationships between the variables. These are proportionality of runoff discharges to (net) rainfall depth and linear summations of discharges resulting from (net) rainfalls during different time intervals or over different sectors of a watershed. This study examines the validity of these assumptions by use of an extensive two-dimensional laboratory experimentation. The results indicate that proportionality would be found under high rainfall intensity through a long duration. Spatial summations would more likely yield correct discharges in cases where rainfall duration is equal to, or is longer than, the time of concentration. Temporal summations may yield correct discharges when rainfall duration is longer than one half of the time of concentration. Here, the time of concentration is determined at the beginning of gradual approach of the discharge towards the equilibrium state.     

The geochemical evolution of the Pleistocene Lake Lisan-Dead Sea system

The geochemical history of Lake Lisan, the Pleistocene precursor of the Dead Sea, has been studied by geological, chemical and isotopic methods.Aragonite laminae from the Lisan Formation yielded (equivalent) Sr/Ca ratios in the range 0.5 × 10^?2?1 × 10^?2, Na/Ca ratios from 3.6 × 10^?3 to 9.2 × 10^?3, $\text{δ}{}^{18}\text{O}{}_{\mathrm{PDB}}$ values between 1.5 and 7%. and $\text{δ}{}^{13}\text{C}{}_{\mathrm{PDB}}$ from ?7.7 to 3.4%..The distribution coefficient of Na⁺ between aragonite and aqueous solutions, $\text{λ}{}^{\mathrm{A}}{}_{\mathrm{Na}}$, is experimentally shown to be very sensitive to salinity and nearly temperature independent. Thus, Na/Ca in aragonite serves as a paleosalinity indicator.Sr/Ca ratios and $\text{δ}{}^{18}\text{O}$ values in aragonite provide good long-term monitors of a lake's evolution. They show Lake Lisan to be well mixed, highly evaporated and saline. Except for a diluted surface layer, the salinity of the lake was half that of the present Dead Sea (15 vs 31%).Lake Lisan evolved from a small, yet deep, hypersaline Dead Sea-like, water body. This initial lake was rapidly filled-up to its highest stand by fresh waters and existed for about 40,000 yr before shrinking back to the present Dead Sea. The chemistry of Lake Lisan at its stable stand represented a material balance between a Jordan-like input, an original large mass of salts and a chemical removal of aragonite. The weighted average depth of Lake Lisan is calculated, on a geochemical basis, to have been at least 400, preferably 600 m.The oxygen isotopic composition of Lake Lisan water, which was higher by at least 3%. than that of the Dead Sea, was probably dictated by a higher rate of evaporation.Na/Ca ratios in aragonite, which correlate well with $\text{δ}{}^{13}\text{C}$ values, but change frequently in time, reflect the existence of a short lived upper water layer of varying salinity in Lake Lisan.     

Combining field and modelling techniques to assess rockfall dynamics on a protection forest hillslope in the European Alps

Adequate management of a mountain forest that protects downslope areas against impacts of rockfall requires insight into the dynamics of the hillslope environment. Therefore, we applied a combined approach, using field and modelling techniques, to assess the determining factors for rockfall source areas, rockfall tracks and rockfall runout zones on a forested slope in mountainous terrain. The first objective of this study was to understand why rockfall occurs in the study area. The second objective was to translate the knowledge obtained in the field into a model that simulates rockfall dynamics on a forested slope realistically. The third objective was to assess which hillslope characteristics primarily determine the distribution of active rockfall tracks. To achieve these objectives, we made a geomorphological map of the whole study area, and we measured the major discontinuity planes in the bedrock that are exposed in the rockfall source areas. Furthermore, a test site for simulation modelling within the larger study area was defined in which both a forest and a hillslope inventory were carried out. The available data and our developed rockfall simulation model allowed us to assess the slope characteristics that mainly determine the distribution of areas affected by rockfall. We found that in decreasing order of importance, both standing and felled trees, the surface roughness and rockfall resistant shrubs primarily determine the distribution of rockfall-affected areas. Simulation tests without a forest cover produced similar rockfall runout zones as fossil rockfall events identified in the field. We believe that the combined field and modelling approach is a prerequisite for understanding how forests can protect against rockfall.     

Warming at 18,000 yr B.P. in the Tropical Andes

Palynological, paleopedological, and glacial geomorphological evidence from the area of the high plain of Bogotá in the Colombian Eastern Cordillera indicates a significant climatic warming around 18,000¹⁴C yr B.P. Comparison of dated vegetation changes, pedogenic episodes, and glacier fluctuations provides the basis for defining the so-called “La Laguna Interstadial” that lasted from 19,500 to 17,000 yr B.P. During this interstadial period, mean annual temperatures in the tropical Andes were up to 4°C higher than during the preceding and following stadial periods, when full-glacial conditions prevailed and temperatures were up to 8°C colder than at present.     

Methane derived organic matter and carbonates

¹³C depleted materials of three types are encountered in the south-eastern Mediterranean Coastal Plain of Israel and Northern Sinai. Sub-surface coarse carbonates associated with elemental sulfur have gd¹³C values of −50‰. Organic matter (humic substances and lipid soluble) in the Be'eri sulfur quarries have δ¹³C values of −80 to −90‰. Dissolved bicarbonate in groundwaters show δ¹³C values of −13 to −17‰.It is suggested that all these values can be explained by biogenic methane leaking from sub-surface reservoir which is oxidized under different depositional and environmental conditions.     

On the role of subducting oceanic plateaus in the development of shallow flat subduction

Oceanic plateaus, aseismic ridges or seamount chains all have a thickened crust and their subduction has been proposed as a possible mechanism to explain the occurrence of flat subduction and related absence of arc magmatism below Peru, Central Chile and at the Nankai Trough (Japan). Their extra compositional buoyancy could prohibit the slab from sinking into the mantle. With a numerical thermochemical convection model, we simulated the subduction of an oceanic lithosphere that contains an oceanic crustal plateau of 18-km thickness. With a systematic variation, we examined the required physical parameters to obtain shallow flat subduction. Metastability of the basaltic crust in the eclogite stability field is of crucial importance for the slab to remain buoyant throughout the subduction process. In a 44-Ma-old subducting plate, basalt must be able to survive a temperature of 600–700 °C to keep the plate buoyant sufficiently long to cause a flat-slab segment. We found that the maximum yield stress in the slab must be limited to about 600 MPa to allow for the necessary bending to the horizontal. Young slabs show flat subduction for larger parameter ranges than old slabs, since they are less gravitationally unstable and show less resistance against bending. Hydrous weakening of the mantle wedge area and lowermost continent are required to allow for the necessary deformation of a change in subduction style from steep to flat. The maximum flat slab extent is about 300 km, which is sufficient to explain the observed shallow flat subduction near the Nankai Trough (Japan). However, additional mechanisms, such as active overthrusting by an overriding continental plate, need to be invoked to explain the flat-slab segments up to 500 km long below Peru and Central Chile.