Latitudinal variation of measured O3 photolysis frequencies J(O1D) and primary OH production rates over the Atlantic Ocean between 50° N and 30° S

The latitudinal variation of the photolysis frequency of ozone to O(¹D) atoms, J(O¹D), was measured using a filter radiometer during the cruise ANT VII/1 of the research vessel Polarstern in September/October 1988. The J(O¹D) noon values exhibited a maximum of 3.6×10^-5 s^-1 (2 sr) at the equator and decreased strongly towards higher latitudes. J(O¹D) reached highest values for clean marine background air with low aerosol load and almost cloudless sky. The J(O¹D) data, measured under these conditions and a temperature of 295 K, can be expressed by: % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXatLxBI9gBaerbd9wDYLwzYbItLDharqqtubsr% 4rNCHbGeaGqiVu0Je9sqqrpepC0xbbL8F4rqqrFfpeea0xe9Lq-Jc9% vqaqpepm0xbba9pwe9Q8fs0-yqaqpepae9pg0FirpepeKkFr0xfr-x% fr-xb9adbaqaaeGaciGaaiaabeqaamaabaabaaGcbaGaamOsaiaacI% cacaqGpbWaaWbaaSqabeaaiiaacqWF8baFaaGccaqGebGaaeykaiaa% bccacqWF9aqpcaqGGaGaaeyzaiaabIhacaqGWbGaaeiiaiaabUhacq% GHsislcaaI4aGaaiOlaiaaicdacaaIYaGaeyOeI0IaaGioaiaac6ca% caaI4aGaaiiEaiaaigdacaaIWaWaaWbaaSqabeaacqGHsislcaaIZa% aaaOGaaeiiaiaabIhacaqGGaGaam4uaiabgUcaRiaaiodacaGGUaGa% aGinaiaacIhacaaIXaGaaGimamaaCaaaleqabaGaeyOeI0IaaGOnaa% aakiaadofadaahaaWcbeqaaiaaikdaaaGccaGG9bGaaeikaiaaboha% daahaaWcbeqaaiabgkHiTiaaigdaaaGccaGGPaaaaa!5EE9!\[J({\text{O}}^| {\text{D) }} = {\text{ exp \{ }} - 8.02 - 8.8x10^{ - 3} {\text{ x }}S + 3.4x10^{ - 6} S^2 \} {\text{(s}}^{ - 1} )\] where S represents the product of the overhead ozone column (DU) and the secant of the solar zenith angle. The meridional profile of the primary OH radical production rate P(OH) was calculated from the J(O¹D) measurements and simultaneously recorded O₃ and H₂O mixing ratios. While the latitudinal distribution of J(O¹D) and water vapour was nearly symmetric to the equator, high tropospheric ozone levels up to 40 ppb were observed in the Southern Hemisphere, SH, resulting in higher P(OH) in the SH.     

A model for inferring canopy and underlying soil temperatures from multi-directional measurements

Thermal emission is modeled from a canopy/soil surface, where the soil and the leaves are at different temperatures,T _g andT _c respectively. The temperatureT _m corresponding to a radiometer reading is given by $$B_\lambda (T_m ) = \chi B_\lambda (T_g ) + (1 - \chi )B_\lambda (T_c ) ,$$ whereB _λ denotes the Planck blackbody function at wavelength λ, χ specifies the fraction of the field of view occupied by the soil at a given view direction, and an emissivity of 1.0 is assumed for the plants and the soil. The dependence of the soil-fraction χ on the view direction and the structure is expressed by the viewing-geometry parameter, which allows for concise and simple formulation. We observe from our model that at large view zenith angles, only the plants are effectively seen (that is, χ tends to zero), and thereforeT _c can be determined from observations at large zenith angles, to the extent that such observations are practical. Viewing from the zenith, χ = exp(-L _hc), whereL _hc is the projection of the canopy leaf-area (per unit surface area) on a horizontal plane. For off-zenith observations, the soil-fraction χ depends on the distribution in the azimuth of the projected areas of various leaf categories, in addition to the dependence on the sum total of these projections,L _hc.L _hc, rather than the leaf-area index, emerges as the parameter characterizing the optical thickness of the canopy. Inferring bothT _c andT _g from observations from the zenith and from large zenith angles is possible ifL _hc is known from other measurements. Drooping of leaves under water-stress conditions affects the observed temperatureT _m in a complicated way because a leaf-inclination change produces a change inL _hc (for the same leaf area) and also a change in the dependence of χ on the view direction. Water stress can produce an increase of the soil-fraction χ and thus tends to produce an exaggerated increase in the observed temperature compared to the actual increase in canopy temperature. These effects are analyzed for a simulated soybean canopy.     

Stable isotope (O and C) and pollen trends in eastern Lake Erie,evidence for a locally-induced climatic reversal of Younger Dryas age in the Great Lakes basin

A cool period from about 11000 to 10 500 BP (11 to 10.5 ka) is recognized in pollen records from the southern Great Lakes area by the return of Picea and Abies dominance and by the persistence of herbs. The area of cooling appears centred on the Upper Great Lakes. A high-resolution record (ca. 9 mm/y) from a borehole in eastern Lake Erie reveals, in the same time interval, this pollen anomaly, isotope evidence of meltwater presence (a — 3 per mil shift in ¹⁸O and a +1.1 per mil shift in ¹³C), increased sand, and reduced detrital calcite content, all suggesting concurrent cooling of Lake Erie. The onset of cooling is mainly attributed to the effect of enhanced meltwater inflow on the relatively large upstream Main Lake Algonquin during the first eastward discharge of glacial Lake Agassiz. Termination of the cooling coincides with drainage of Lake Algonquin, and is attributed to loss of its cooling effectiveness associated with a substantial reduction in its surface area. It is hypothesized that the cold extra inflow effectively prolonged the seasonal presence of lake ice and the period of spring overturn in Lake Algonquin. The deep mixing would have greatly increased the thermal conductive capacity of this extensive lake, causing suppression of summer surface lakewater temperatures and reduction of onshore growing-degree days. Alternatively, a rapid flow of meltwater, buoyed on sediment-charged (denser) lakewater, may have kept the lake surface cold in summer. Other factors such as wind-shifted pollen deposition and possible effects from the Younger Dryas North Atlantic cooling could have contributed to the Great Lakes climatic reversal, but further studies are needed to resolve their relative significance.Contribution to Climo Locarno — Past and Present Climate Dynamics; Conference September 1990, Swiss Academy of Sciences — National Climate ProgramGeological Survey of Canada Contribution 58 890     

The front of 8 October 1987 — Predictions of three mesoscale models

Summary The forntal passage of 8 October 1987, which was extensively sampled during the first intense observation period of the German Front Experiment, is simulated by aid of three mesoscale models. The results are intercompared and held against the manually and objectively analysed observations of the meso and meso- scales, respectively. The orographic impact is studied by comparing model runs with full and cut-off Alps. Implications regarding similar efforts in the future conclude the paper.With 11 Figures     

High-resolution numerical modelling of convective precipitation over Northern Italy

Summary A number of forecast experiments were performed in order to assess the capability of reproducing, by means of a limited-area numerical model, the highly structured mesoscale circulations occurring in the Po Valley of Northern Italy during a north-westerly cold front passage across the Alpine chain, with particular attention to the modelling of the effects of organized convection. The case-study occurred during summer 1987 and the model used throughout was the 1989 version of the UB/NMC Limited Area Model (University of Belgrade, National Meteorological Centre of Washington). The model was integrated both with eta, , and sigma, , as vertical coordinates and ECMWF initialized analyses were always used as initial conditions. ECMWF initialized analysis or operational forecast fields were also used for updating in time the lateral boundary conditions. Experiments show qualitative and quantitative agreement with observations, both in upper-air geopotential height fields, in MSLP and in cumulated precipitation. Several modelling issues were also investigated, e.g. sensitivity of the results to horizontal and vertical model resolution and to the influence of the lateral boundaries poitioning, finding large effects of the latter on quantitative precipitation fields. Difficulties in modelling very localized mesoscale phenomena, e.g. organized convective thunderstorms in the Po Valley and Alpine North Foehn in the Milan area, were generally encounted.     

Geochemical stratigraphy of the Huronian continental volcanics at Thessalon,Ontario: contributions of two-stage crustal fusion

The 1500 m thick sequence of Huronian continental volcanics at Thessalon, Ontario is subdivided into 4 volcanic cycles, each of which includes abundant early mafic end-members, central intermediate flows, and late rhyolite units. Major and trace element concentrations are dominated by extensive gabbroic fractionation trends that ultimately produced two types of felsic flows: (1) rhyolites with high light rare earth element (LREE) and relatively low large-ion lithophile element (LILE) concentrations (high-LREE, low-LILE rhyolites), and (2) following late separation of REE-rich accessory phases, rhyolites depleted in LREE (low-LREE, high-LILE rhyolites). Mafic end-members of individual volcanic cycle are progressively less siliceous and less enriched in LILE and LREE with height in the stratigraphic section. Ti/Zr ratios gradually rise from 35 in early mafic flows to stabilize at about 85 in late units, while average SiO₂ contents decrease from 56 to about 50% and Mg# rises from about 48 to 52. -Nd values are consistently negative, indicating variable degrees of pre-fractionation crustal contamination of the end-member magmas during their uprise through the crust. Mixing models are consistent with up to 50% contamination by crustal material of tonalitic hornblende-gneiss composition. A progressive increase in -Nd, from about-5.0 to-0.5 upward in the volcanic succession, reflects a decreasing degree of crustal contamination due to development of insulating layers along margins of the feeder system. Detailed stratigraphic variations suggest that successive magmas batches were intercepted by a progressively fractionating, periodically replenished magma source, giving rise to open-system magmatism. Despite the prevalence of crustal assimilation in the Huronian lavas, (La/Sr)N ratios are too low in least contaminated end-members to be explained by contamination of tholeiitic magmas. The late basalts resemble instead modern island are basalts, and it is suggested that the subcontinental mantle source was enriched by subduction-related processes during crustal formation. Within individual volcanic cycles gabbroic fractionation trends systematically deviate from calculated factors toward compositions characteristic of hornblende-gneiss. Such relations suggest that further crustal contamination of the magmas occurred simultaneous with crystal fractionation. probably within undulating sills at upper crustal levels. Quantitative analysis suggests assimilation/fractional crystallization (A/FC) ratios of about 0.45. As a result of extensive two-stage contamination, rhyolites from the initial volcanic cycle incorporate a total of over 60% of crust.     

Petrogenesis of anomalous K-enriched MORB from the Southwest Indian Ridge: 11°53′E to 14°38′E

Glassy pillow basalts with unusual geochemical characteristics for mid-ocean ridge basalt (MORB) have been dredge sampled from the Southwest Indian Ridge between 12 and 15°E during Leg ANT IV/4 of the F.S. POLARSTERN. Lavas from 4 of 6 dredges are moderately nepheline normative, highly K-enriched (0.5–1.77 wt% K₂O) alkali basalts and hawaiites. Mg-numbers indicate that many of the lavas are fairly primitive (Mg No.=63–67), yet show extreme enrichment in incompatible elements; e.g. Nb (24–60 ppm), Ba (170–470 ppm) and Sr (258–460 ppm). Incompatible-element ratios such as Zr/Nb (3–5) and Y/Nb (0.46–1.1) are extremely low even for E-type (enriched) MORB, whereas (La/Yb)_n ratios are particularly high (3.4–7.8). ⁸⁷Sr/⁸⁶Sr (0.70290–0.70368), ¹⁴³Nd/¹⁴⁴Nd (0.51302–0.51284) and ²⁰⁶Pb/²⁰⁴Pb (18.708–19.564) isotopic ratios further indicate the geochemically enriched nature of these lavas, which range from the compositional field for depleted N-type (normal) MORB towards the composition of Bouvet Island lavas. Mutually correlated incompatible-element and Sr-, Nd- and Pb-isotopic ratios allow a fairly well constrained model to be developed for the petrogenesis of these unusually alkalic mid-ocean ridge lavas. The alkalic nature and degree of enrichment in incompatible elements is ascribed to particularly low degrees of partial melting (3–5 wt%), at greater than usual depth, of a source region that has experienced prior geochemical enrichment (by veining) related to the upwelling Bouvet mantle plume. To account for the observed compositional variations, a model is proposed whereby mixing between partial melts derived from these geochemically enriched silicate veins, and an incipient to low percentage (±2%) melt from the surrounding geochemically depleted suboceanic asthenosphere occurs as a consequence of increasing degree of melting with adiabatic upwelling. Eruption of these alkalic lavas in this spreading ridge environment is attributed to a temporary hiatus in tholeiitic volcanism and associated spreading along this section of the Southwest Indian Ridge, related to readjustment of spreading direction to a more stable plate geometry.     

Geological,fluid inclusion and stable isotope studies of Mo mineralization,Galway Granite,Ireland

Mo mineralization within the Galway Granite at Mace Head and Murvey, Connemara, western Ireland, has many features of classic porphyry Mo deposits including a chemically evolved I-type granite host, associated K- and Si-rich alteration, quartz vein(Mace Head) and granite-hosted (Murvey) molybdenite, chalcopyrite, pyrite and magnetite mineralization and a gangue assemblage which includes quartz, muscovite and K-feldspar. Most fluid inclusions in quartz veins homogenize in the range 100–350°C and have a salinity of 1–13 eq. wt.% NaCl. They display Th-salinity covariation consistent with a hypothesis of dilution of magmatic water by influx of meteoric water. CO₂-bearing inclusions in an intensely mineralized vein at Mace Head provide an estimated minimum trapping temperature and pressure for the mineralizing fluid of 355°C and 1.2 kb and are interpreted to represent a H₂O-CO₂ fluid, weakly enriched in Mo, produced in a magma chamber by decompression-activated unmixing from a dense Mo-bearing NaCl-H₂O-CO₂ fluid. ³⁴S values of most sulphides range from c. 0 at Murvey to 3–4 at Mace Head and are consistent with a magmatic origin. Most quartz vein samples have ¹⁸O of 9–10.3 and were precipitated from a hydrothermal fluid with ¹⁸O of 4.6–6.7. Some have ¹⁸O of 6–7 and reflect introduction of meteoric water along vein margins. Quartz-muscovite oxygen isotope geothermometry combined with fluid inclusion data indicate precipitation of mineralized veins in the temperature range 360–450°C and between 1 and 2 kb. Whole rock granite samples display a clear ¹⁸O-D trend towards the composition of Connemara meteoric waters. The mineralization is interpreted as having been produced by highlyfractionated granite magma; meteoric water interaction postdates the main mineralizing event. The differences between the Mace Head and Murvey mineralizations reflect trapping of migrating mineralizing fluid in structural traps at Mace Head and precipitation of mineralization in the granite itself at Murvey.     

An exact solution of the equation of transfer with three-term scattering indicatrix in an exponential atmosphere

The general equation for radiative transfer in the Milne-Eddington model is considered here. The scattering function is assumed to be quadratically anisotropic in the cosine of the scattering angle and Planck's intensity function is assumed for thermal emission. Here we have taken Planck's function as a nonlinear function of optical depth, viz.,B _v(T)=b _o+b ₁ e ^–. The exact solution for emergent intensity from the bounding face is obtained by the method of the Laplace transform in combination with the Wiener-Hopf technique.     

Geology and tectonics of the Themis Regio-Lavinia Planitia-Alpha Regio-Lada Terra area,Venus: Results from Arecibo image data

New radar images obtained from the Arecibo Observatory (resolution 1.5–4.0 km) for portions of the southern hemisphere of Venus show that: the upland of Phoebe Regio contains the southern extension of Devana Chasma, a rift zone extending 4200 km south from Theia Mons and interpreted as a zone of extension; Alpha Regio, the only large region of tessera within the imaged area, is similar to tessera mapped elsewhere on the planet and covers a smaller percentage of the surface than that observed in the northern high latitudes; the upland made of Ushas, Innini and Hathor Montes consists of three distinct volcanic constructs; Themis Regio is mapped as an ovoid chain of radar-bright arcuate single and double ring structures, edifices and bright lineaments. This area is interpreted as a region of mantle upwelling and on the basis of apparent split and separated features, a zone of localized faulting and extension. Linear zones of deformation in Lavinia Planitia are characterized by lineament belts that are often locally elevated, are similar to ridge belts mapped in the northern high latitudes and are interpreted to be characterized mainly by compression; radar-bright lava complexes within Lavinia Planitia are unique to this part of the planet and are interpreted to represent areas of eruption of high volumes of extremely fluid lava; the upland of Lada Terra is bound to the north by a linear deformation zone interpreted as extensional, is characterized by large ovoids and coronae, is interpreted to be associated with an area of mantle upwelling, and is in contrast to the northern high latitude highland of Ishtar Terra. Regions of plains in the southern hemisphere cover about 78%; of the mapped area and are interpreted to be volcanic in origin. Located within the area imaged (10–78 S) are 52 craters interpreted to be of impact origin ranging from 8 to 157 km in diameter. On the basis of an overall crater density of 0.94 craters/10⁶ km², it is determined that the age of this part of the Venus surface is similar to the 0.3 to 1.0 billion year age calculated for the equatorial region and northern high latitudes. The geologic characteristics of the portion of the Venus southern hemisphere imaged by Arecibo are generally similar to those mapped elsewhere on the planet. This part of the planet is characterized by widespread volcanic plains, large volcanic edifices, and zones of linear belt deformation. The southern hemisphere of Venus differs from northern high latitudes in that tessera makes up only a small percentage of the surface area and the ovoid chain in Themis Regio is unique to this part of the planet. On the basis of the analysis presented here, the southern hemisphere of Venus is interpreted to be characterized by regions of mantle upwelling on a variety of scales (ovoids, region made up of Ushas, Innini and Hathor Montes), upwelling and extension (Themis Regio) and localized compression (lineament belts in Lavinia Planitia).