Seasonal variations in the speciation of dissolved iodine in the Chesapeake Bay

The speciation of dissolved iodine and the distributions of the iodine species in the deep Chesapeake Bay underwent seasonal variations in response to changes in the prevailing redox condition. In the deep water, the ratios of iodate to iodide and iodate to inorganic iodine decreased progressively from the Winter through the Summer as the deep water became more poorly oxygenated before they rebounded in the Fall when the deep water became re-oxygenated again. The composition of the surface water followed the same trend. However, in this case, the higher biological activities in the Spring and the Summer could also have enhanced the biologically mediated reduction of iodate to iodide by phytoplankton and contributed to the lower ratios found during those seasons. Superimposed on this redox cycle was a cycle of input and removal of dissolved iodine probably as a result of the interactions between the water column and the underlying sediments. Iodine was added to the Bay during the Summer when the deep water was more reducing and removed from the Bay in the Fall when the deep water became re-oxygenated. A third cycle was the inter-conversion between inorganic iodine and ‘dissolved organic iodine’, or ‘‘DOI’’. The conversion of inorganic iodine to ‘DOI’ was more prevalent in the Spring. As a result of these biogeochemical reactions in the Bay, during exchanges between the Bay and the North Atlantic, iodate-rich and ‘DOI’-poor water was imported into the Bay while iodide- and ‘DOI’-rich water was exported to the Atlantic. The export of iodide from these geochemically reactive systems along the land margins contributes to the enrichment of iodide in the surface open oceans.     

A NEW MODEL FOR PEBBLE BEACH TRACER DISPERSAL

A series of eight tracer experiments were carried out over one year (1983) on a low energy, macro-tidal beach in South Wales, UK. Tracer movement was monitored and 30 pebbles adjacent to coloured tracer pebbles were measured. Measurements were of the A, B, and C axes, roundness, Maximum Projection Sphericity and Oblate-Prolate indices. Analysis shows that through time, the percentage rejection of these properties increased. It is theorised that the surface tracers are 'misfits' or 'rejects' which have not found their equilibrium position in the pebble facies.     

Contaminant concentrations and toxicity of sea-surface microlayer near Los Angeles, California

Sea-surface microlayer samples were collected from six nearshore areas receiving different amounts of anthropogenic inputs. The samples were analyzed for selected trace metals, chlorinated hydrocarbons, and polycyclic aromatic hydrocarbons. The relative toxicities of the samples were determined with fish embryo bioassays.Contaminant concentrations generally increased from offshore to the inshore stations. Contaminant concentrations were several orders of magnitude higher in microlayer samples from the highly industrialized Los Angeles and Long Beach harbors compared to samples from a site 15km offshore. Microlayer samples from the inshore stations were significantly more toxic, and induced significantly more developmental abnormalities and chromosome aberrations, than samples from the offshore stations.     

High-resolution acoustic mapping of shallow gas in unconsolidated sediments beneath the strait of Georgia,British Columbia

Gassy sediments are detectable acoustically in subbottom profiles of Canada's Fraser Delta slope and prodelta areas. Interstitial gas is typically represented by zones of acoustic turbidity on high-resolution seismic profiles and by gas brightening on air-gun profiles. The top of the acoustically turbid zone is generally highest within the sediment column closest to the river mouths and lies within 10 ms (two-way travel time) of the sea floor in a nearly continuous area that covers over 530 km². Most of the gas is believed to be biogenic in origin, although thermogenic gas derived from underlying Tertiary sedimentary rocks may be present in places.     

Palaeo-carbonate seep structures above an oil reservoir, Gryphon Field, Tertiary, North Sea

Petrographic and geochemical analyses performed on a North Sea core from the Gryphon Field reveal the presence of palaeo-degassing features surrounded by injected sandstones in the Eocene interval. The injected sandstones are oil-stained and poorly cemented by carbonate and quartz. ¹⁸O isotope analyses indicate that carbonate cementation occurred during shallow burial (likely less than about 300 m). Depleted ¹³C (around –30 V-PDB) carbonate cement suggests that bicarbonate was derived from the microbial oxidation of oil and gas. Late quartz overgrowths enclose oil present in the injected units. The tubular degassing conduits are composed of zoned cements and have ¹⁸O and ¹³C isotope values similar to the injected sandstones, indicating that oil and gas seepage induced the precipitation of authigenic carbonate in the shallow subsurface. Oil inclusions in inter- and intra-crystal cement sites in both injected sandstones and degassing conduits indicate that oil seepage was an ongoing feature at shallow burial. A proposed model involves oil and gas seepage and the formation of the degassing conduits, followed by a sand injection phase. It seems likely that oil and gas continued to leak towards the seabed by exploiting the network of permeable injected sandstones and the horizons of porous degassing features.     

Nitrate reductase activity and the speciation of selenium at the mouth of Chesapeake bay

Nitrate reductase activity and the concentrations of selenite and selenate were monitored for six months at the mouth of Chesapeake Bay (USA). A positive correlation was found between nitrate reductase activity and the concentration of selenite, suggesting that selenite may be formed in coastal waters and nitrate reductase may be involved in the process.     

Effects of pulp bleach plant effluents on hepatic xenobiotic biotransformation enzymes in fish: Laboratory and field studies

The present preliminary report on studies of the influence of pulp bleach plant effluents on hepatic biotransformation enzymes in fish is a part of a major characterisation of biochemical and physiological effects of effluents from pulp industries in Sweden. Our studies on the xenobiotic biotransformation enzymes demonstrate, so far, that the pulp effluents have the potential to strongly induce 7-ethoxyresorufin-O-deethylase activity (EROD) in fish liver and that fish living in the receiving water of an effluent from a pulp bleach plant have induced hepatic EROD activities as well as higher hepatic UDP glucuronyltransferase activities than those living in an unpolluted area. It is thus apparent that measures of induction of biotransformation enzymes in fish liver may be a useful approach in monitoring the presence of potential hazardous compounds released from pulp industries.     

Application of cluster analysis to study the relationship between the fine stratification and the background hydrological conditions in the ocean

Cluster analysis is discussed in the context of its application to map various test areas in the sea. By analysing the correspondence of the identified categories to areas with specific hydrological conditions, an attempt is made to relate the types of fine structure to diverse background conditions. With two test areas mapped, a conclusion is made as to the possible application of cluster analysis to this end.Translated by Vladimir A. Puchkin.