Contrasting interactions of sodium and potassium with H<Subscript>2</Subscript>O in haplogranitic liquids and glasses at 200 MPa from hydration–diffusion experiments

This study examines hydration–diffusion in the metaluminous haplogranite system at 200 MPa H₂O and 800–300°C. At 800°C hydration is accompanied by melting and uphill diffusion of sodium from anhydrous glass toward the region of hydration and melting, whereas potassium diffuses away from the hydration front and into anhydrous glass. Silicon and aluminum are simply diluted upon hydration. There is no change in molecular Al/(Na + K) throughout the entire hydration-diffusion aureole and, therefore, (1) there is no loss of alkalis to the vapor, and (2) K migrates to replace Na in order to maintain local charge balance required by ^IVAl. Alkali diffusion occurs over a viscosity contrast from 10^4.1 Pa s in hydrous liquid to 10^11.8–10^13.5 Pa s in anhydrous glass. From these results, we interpret that: (1) Na is structurally or energetically favored over K as a charge-balancing cation for ^IVAl in hydrous granitic liquids, whereas the opposite behavior has been observed for anhydrous melts, and (2) the diffusion of alkalis through silicate melts is largely independent of viscosity. Results from 600°C are similar to those at 800°C, but hydration at 300°C involves a loss of Na and concomitant increase in molar Al/(Na + K) in the hydration zone due to hydrogen-alkali exchange between fluid and glass. Hydration behavior at 400°C is transitional between those at 300°C and 600°C, suggesting that the change in hydration mechanism occurs near the glass transition.     

Periodic Behavior and Stochastic Fluctuations of Solar Activity: Proper Orthogonal Decomposition Analysis

We use the Proper Orthogonal Decomposition (POD) to investigate the spatiotemporal features of the solar activity. Daily observation in the period 1949–1996 of the green coronal emission line at 530.3 nm are used as indicators of the activity behavior. We show that few POD modes suffice in describing both the space and time main periodicities. In particular, being affected by a strongly energetic stochastic behavior, daily data are described by five POD modes, while two POD modes are enough to describe the butterfly diagram in monthly averaged data. Apart from the basic period T₀ = 11 years, using daily data we found evidences for intercycle temporal periodicities.     

Experiments on the kinetics of partial melting of a leucogranite at 200 MPa H<Subscript>2</Subscript>O and 690–800°C: compositional variability of melts during the onset of H<Subscript>2</Subscript>O-saturated crustal anatexis

We have experimentally investigated the kinetics of melting of an aplitic leucogranite (quartz+sodic plagioclase of ≈Ab₉₀+K-feldspar+traces of biotite) at 690, 740, and 800°C, all at 200 MPa H₂O. Leucogranite cylinders, 3.5 mm in diameter and 7 mm in length, were run in the presence of excess H₂O using cold-seal pressure vessels for 11–2,925 h. At 690 and 740°C and any experimental time, and 800°C and short run times, silicate glass (melt at run conditions) occurs as interconnected films along most of the mineral boundaries and in fractures, with the predominant volume occurring along quartz/feldspars boundaries and quartz/plagioclase/K-feldspar triple junctions. Glass film thickness is roughly constant throughout a given experimental charge and increases with experimental temperature and run duration. The results indicate that H₂O-saturated partial melting of a quartzo-feldspathic protolith will produce an interconnected melt phase even at very low degrees (<5 vol%) of partial melting. Crystal grain boundaries are therefore completely occluded with melt films even at the lowest degrees of partial melting, resulting in a change in the mechanism of mass transport through the rock from advection of aqueous vapor to diffusion through silicate melt. At 690 and 740°C the compositions of glasses are homogeneous and (at both temperatures) close to, but not on, the H₂O-saturated 200 MPa haplogranite eutectic; glass compositions do not change with run duration. At 800°C glasses are heterogeneous and plot away from the minimum, although their molar ratios ASI (=mol Al₂O₃/CaO+Na₂O+K₂O) and Al/Na are constant throughout the entire charge at any experimental time. Glass compositions within individual 800°C experiments form linear trends in (wt%) normative quartz–albite–orthoclase space. The linear trends are oriented perpendicular to the 200 MPa H₂O haplogranite cotectic line, reflecting nearly constant albite/orthoclase ratio versus variable quartz/feldspar ratio, and have endpoints between the 800°C isotherms on the quartz and feldspar liquidus surfaces. With increasing experimental duration the trends migrate from the potassic side of the minimum toward the bulk rock composition located on the sodic side, due to more rapid (and complete) dissolution of K-feldspar relative to plagioclase. The results indicate that partial melting at or slightly above the solidus (690–740°C) is interface reaction-controlled, and produces disequilibrium melts of near-minimum composition that persist metastably for up to at least 3 months. Relict feldspars show no change in composition or texture, and equilibration between melt and feldspars might take from a few to tens of millions of years. Partial melting at temperatures well above the solidus (800°C) produces heterogeneous, disequilibrium liquids whose compositions are determined by the diffusive transport properties of the melt and local equilibrium with neighboring mineral phases. Feldspars recrystallize and change composition rapidly. Partial melting and equilibration between liquids and feldspars might take from a few to tens of years (H₂O-saturated conditions) at these temperatures well above the solidus.     

The persistent water problems of Lima,Peru: Neoliberalism,institutional failures and social inequalities

The contingent relation between water governance and nature neoliberalization has defined most interventions in the water sector around the world in recent years. In the case of the Peruvian capital Lima, the provision of water and sanitation services in the last two decades has been the object of investments and institutional reforms strongly influenced by economic neoliberalism. This essay examines the evolution of these neoliberalizing tendencies, noting the internal disputes, necessary adjustments and underlying problems of water sufficiency in the metropolitan region. The empirical results suggest that, rather than a straightforward process, the neoliberalization of water in Lima has advanced according to political opportunities and technico‐operational constraints. The water reforms implemented in the 1990s – when the goal of privatization met political opposition – can be contrasted with the more recent phase in the 2000s, when more flexible mechanisms, such as public‐private partnerships, have facilitated public acceptance. Despite the renovation of the infrastructure, the modernization of the water sector has failed to address persistent water management problems, namely the discriminatory treatment of low income residents, the chaotic expansion of the metropolitan area and the risk of future water shortages.     

The influence of upper-crust lithology on topographic development in the central Coast Ranges of California

A fundamental geological tenet is that as landscapes evolve over graded to geologic time, geologic structures control patterns of topographic distribution in mountainous areas such that terrain underlain by competent rock will be higher than terrain underlain by incompetent rock. This paper shows that in active orogens where markedly weak and markedly strong rocks are juxtaposed along contacts that parallel regional structures, relatively high topography can form where strain is localized in the weak rock. Such a relationship is illustrated by the topography of the central Coast Ranges between the Pacific coastline and the San Andreas fault zone (SAFZ), and along the length of the Gabilan Mesa (the “Gabilan Mesa segment” of the central Coast Ranges). Within the Gabilan Mesa segment, the granitic upper crust of the Salinian terrane is in contact with the accretionary-prism mélange upper crust of the Nacimiento terrane along the inactive Nacimiento fault zone. A prominent topographic lineament is present along most of this lithologic boundary, approximately 50 to 65 km southwest of the SAFZ, with the higher topography formed in the mélange on the southwest side of the Nacimiento fault.This paper investigates factors influencing the pattern of topographic development in the Gabilan Mesa segment of the central Coast Ranges by correlating shortening magnitude with the upper-crust compositions of the Salinian and Nacimiento terranes. The fluvial geomorphology of two valleys in the Gabilan Mesa, which is within the Salinian terrane, and alluvial geochronology based on optically-stimulated luminescence (OSL) age estimates, reveal that the magnitude of shortening accommodated by down-to-the-southwest tilting of the mesa since 400 ka is less than 1 to 2 m. Our results, combined with those of previous studies, indicate that at least 63% to 78% of late-Cenozoic, northeast-southwest directed, upper-crustal shortening across the Gabilan Mesa segment has been accommodated within the Nacimiento terrane. This is significant because perpendicular to orogenic strike the Nacimiento terrane constitutes less than ¼ of the distance between the coast and the SAFZ, and the other ¾ (or greater) of the distance between the coast and the SAFZ is underlain by the granitic upper crust of the Salinian terrane. We propose that strain and mountain building are localized within the Nacimiento terrane because it consists predominantly of the relatively weak Franciscan Complex mélange, and because the upper crust of the Salinian terrane is composed of relatively strong granitic rocks. Our hypothesis is supported by the distribution of post-seismic surface uplift associated with the 2003, 6.5 M_W San Simeon earthquake, which mimics the topography of the southwestern part of the Gabilan Mesa segment of the central Coast Ranges.     

Techniques for the Eduction of Coherent Structures from Flow Measurements in the Atmospheric Boundary Layer

Two empirical methods to detect coherent motions embedded in the flow field have been compared, namely the variable interval time average (VITA) method and a wavelet-based technique, both with artificial signals as well as velocity measurements from the atmospheric boundary layer over a forest canopy. It has been found that the wavelet method is slightly better than the VITA approach in coherent structure eduction, even if the results of both techniques are comparable. Also the application of the present approach to simultaneous conditionally sampled wind data has highlighted some important features of coherent structures and gust generation in canopy flows.     

Climatic trends and impact of climate change on agriculture in an arid Andean valley

Little is known about climate change and its impacts for the arid coastal and mountainous regions in northern Chile. The Elqui river basin, part of the Norte Chico of Chile between 27oS and 33oS latitude, is located south of the hyper-arid Atacama desert. Despite water scarcity, agricultural development in this region has been enhanced by agronomic practices and the marketing of valuable products. This paper characterizes the actual climate conditions and presents an overview and analyses of past climate variability, and future possible climate trends, emphasizing those relevant to agriculture. Precipitation shows an important decrease during the first decades of the past century. Runoff shows decreasing trends for the first half of the past century and increases for 1960 to 1985. Drought appears to be increasing. Statistical downscaling was accomplished using the Long Ashton Research Station Weather Generator. Both future periods of 2011 to 2030 and 2046–65 showed trends to higher minimum and maximum temperature. The number of hot days (maximum temperature greater than or equal to 30°C) has a strong increasing trend during October to April. Even though the downscaled results for precipitation do not show trends, the continuation of the present trend of low amounts is a concern. We discuss some implications of climatic changes for agriculture and we emphasize the importance of adaptation, especially to deal with water scarcity.     

Extreme climatic events in the Amazon basin

During 2009 the Amazon basin was hit by a heavy flooding with a magnitude and duration few times observed in several decades. Torrential rain in northern and eastern Amazonia during the austral summer of 2008–2009 swelled the Amazon River and its tributaries. By July 2009, water levels of the Rio Negro, a major Amazon tributary, reached at Manaus harbor a new record, the highest mark of the last 107?years. During the 2008–2009 hydrological year, the rainy season on northern and northwestern Amazonia started prematurely, and was followed by a longer-than-normal rainy season. An anomalously southward migration of the ITCZ during May–June 2009, due to the warmer than normal surface waters in the tropical South Atlantic, was responsible for abundant rainfall in large regions of eastern Amazonia and Northeast Brazil from May to July 2009. We also compared the flood of 2009 with other major events recorded in 1989 and 1999. The hydrological consequences of this pattern were earlier than normal floods in Amazon northern tributaries, which peak discharges at their confluences with the main stem almost coincided with the peaks of southern tributaries. Since the time displacement of the contribution to the main stem of northern and southern Amazon tributaries is fundamental for damping flood waves in the main stem, the simultaneous combinations of peak discharges of tributaries resulted in an extreme flood.     

The effect of Congo River freshwater discharge on Eastern Equatorial Atlantic climate variability

The surface ocean explains a considerable part of the inter-annual Tropical Atlantic variability. The present work makes use of observational datasets to investigate the effect of freshwater flow on sea surface salinity (SSS) and temperature (SST) in the Gulf of Guinea. In particular, the Congo River discharges a huge amount of freshwater into the ocean, affecting SSS in the Eastern Equatorial Atlantic (EEA) and stratifying the surface layers. The hypothesis is that an excess of river runoff emphasize stratification, influencing the ocean temperature. In fact, our findings show that SSTs in the Gulf of Guinea are warmer in summers following an anomalously high Congo spring discharge. Vice versa, when the river discharges low freshwater, a cold anomaly appears in the Gulf. The response of SST is not linear: temperature anomalies are considerable and long-lasting in the event of large freshwater flow, while in dry years they are less remarkable, although still significant. An excess of freshwater seems able to form a barrier layer, which inhibits vertical mixing and the entrainment of the cold thermocline water into the surface. Other processes may contribute to SST variability, among which the net input of atmospheric freshwater falling over EEA. Likewise the case of continental runoff from Congo River, warm anomalies occur after anomalously rainy seasons and low temperatures follow dry seasons, confirming the effect of freshwater on SST. However, the two sources of freshwater anomaly are not in phase, so that it is possible to split between atypical SST following continental freshwater anomalies and rainfall anomalies. Also, variations in air-sea fluxes can produce heating and cooling of the Gulf of Guinea. Nevertheless, atypical SSTs cannot be ascribed to fluxes, since the temperature variation induced by them is not sufficient to explain the SST anomalies appearing in the Gulf after anomalous peak discharges. The interaction processes between river runoff, sea surface salinity and temperature play an effective role in the interannual variability in the EEA region. Our results add a new source of variability in the area, which was often neglected by previous studies.