Hydrogeological research on intensively exploited deep aquifers in the ‘Loma de Úbeda’ area (Jaén, southern Spain)

The intensive use of groundwater for irrigation in the area of Úbeda (‘Loma de Úbeda’, Jaén, southern Spain) has transformed an area of traditionally rain-fed dry farmland into fields with some of the highest olive oil productivity in the world. Early hydrogeological research studies, initiated just after the beginning of the groundwater exploitation, revealed that the water was collected from three different overlapping aquifers occupying an area of over 1,100 km², with the lower aquifers located at depths from 300 to over 700 m in an area of 440 km². Multidisciplinary research, based on geological characterization, and piezometric, hydrochemical and isotopic data, has led to a conceptual model of functioning in this complex hydrogeological system. The proposed model allows for the identification of the recharge areas, and the discharge, which is at present mainly associated with the groundwater pumping. Areas of mixing of waters from the different aquifers and the main hydrogeochemical processes affecting groundwater quality are described.     

Assessment of the availability of near-real time open weather data provided by networks of surface stations in Spain

The aims of this research are: (i) to check availability of weather observations from automated stations in Spain, (ii) to qualitatively and quantitatively describe the networks identified, (iii) to analyze availability of the observations gathered for 3 different networks [two government (GOV): AEMET with national coverage and CASTILLA Y LEÓN on a regional level; and METEOCLIMATIC, a network of volunteer weather observation (VWO) stations on a national level], and (iv) to undertake a spatial redundancy and lacunarity analysis of them. The results reveal: the existence of heterogeneous VWO networks complementing the GOV, differences within and among networks as far as data acquisition frequency, varying delays in their publication, and semantic differences in the observations made. An inventory was made of 24 networks (16 GOV and 8 VWO) with 3,908 stations deployed in Spain. An analysis of observations from 3 networks reveals that 88 % of the stations in the volunteer network record more than two observations per hour. 56 % of the AEMET stations report more than 48 observations every day, 31 % report between 25 and 48 observations a day. Conversely, the CASTILLA Y LEÓN network records data every half hour. The redundancy analysis reveals a 3,429-drop in the number of unduplicated stations. Following the lacunarity analysis of spatial distribution, it is possible to conclude that 60.72 % of the cells do not contain any stations.     

Effect of the dilution process on the attenuation of contaminants in aquifers

This paper discusses the effects of the dilution process on levels of aquifer contamination attenuation, developing analytical equations for application in theoretical and practical cases. The key finding is that, in aquifers, the dilution process causes a reduction of the contaminant concentration. Analytical equations for the assessment of the contaminant attenuation capacity, by means of the dilution process in an aquifer, are put forward. In particular, the attenuation of the contaminant concentration in an aquifer, and thus the dilution, is described by the volumetric flow rate per unit width perpendicular to the flow direction (q _u). Moreover, a classification of q _u was developed, considering six classes of attenuation capacity due to dilution. For the equations validation, nitrate contamination attenuation due to dilution was analysed in two sample areas in Piedmont (North-West Italy). The results confirmed the hypothesis, evidencing high nitrate concentrations in areas with low q _u values, connected to low dilution rate of the contaminant in the groundwater; vice versa, low nitrate concentrations were evidenced in areas with high q _u values, due to a high nitrate dilution rate.     

Correspondence between f(G) gravity and holographic dark energy via power-law solution

In this paper, we discuss cosmological application of holographic Dark Energy (HDE) in the framework of f(G) modified gravity. For this purpose, we construct f(G) model with the inclusion of HDE and a well-known power law form of the scale factor a(t). The reconstructed f(G) is found to satisfy a sufficient condition for a realistic modified gravity model. We find quintessence behavior of effective equation of state (EoS) parameter ω _DE through energy conditions in this context. Moreover, we observe that the squared speed of sound $v_{s}^{2}$ remains negative, which indicates the instability of HDE f(G) model.     

Multi-stage evolution of a sub-aerial volcanic ridge over the last 1.3 Myr: S. Jorge Island, Azores Triple Junction

New K/Ar dating and geochemical analyses have been carried out on the WNW–ESE elongated oceanic island of S. Jorge to reconstruct the volcanic evolution of a linear ridge developed close to the Azores triple junction. We show that S. Jorge sub-aerial construction encompasses the last 1.3 Myr, a time interval far much longer than previously reported. The early development of the ridge involved a sub-aerial building phase exposed in the southeast end of the island and now constrained between 1.32 ± 0.02 and 1.21 ± 0.02 Ma. Basic lavas from this older stage are alkaline and enriched in incompatible elements, reflecting partial melting of an enriched mantle source. At least three differentiation cycles from alkaline basalts to mugearites are documented within this stage. The successive episodes of magma rising, storage and evolution suggest an intermittent re-opening of the magma feeding system, possibly due to recurrent tensional or trans-tensional tectonic events. Present data show a gap in sub-aerial volcanism before a second main ongoing building phase starting at about 750 ka. Sub-aerial construction of the S. Jorge ridge migrated progressively towards the west, but involved several overlapping volcanic episodes constrained along the main WNW–ESE structural axis of the island. Mafic magmas erupted during the second phase have been also generated by partial melting of an enriched mantle source. Trace element data suggest, however, variable and lower degrees of partial melting of a shallower mantle domain, which is interpreted as an increasing control of lithospheric deformation on the genesis and extraction of primitive melts during the last 750 kyr. The multi-stage development of the S. Jorge volcanic ridge over the last 1.3 Myr has most likely been greatly influenced by regional tectonics, controlled by deformation along the diffuse boundary between the Nubian and the Eurasian plates, and the increasing effect of sea-floor spreading at the Mid-Atlantic Ridge.     

Multivariate discriminant analysis distinguishes metal- from non metal-related biomarker responses in the clam Chamaelea gallina

Molecular biomarkers are among the most sensitive and earliest responses to pollutants. However, lack of detailed knowledge on variability of responses and their possible seasonal variation limit their use. In addition, the seasonality of biological processes modulates the response of organisms to pollutant stressors. Using multivariate statistics, we have studied the influence of environmental and biological factors on the response of a battery of molecular biomarkers in the clam Chamaelea gallina collected along the South-Spanish littoral. Multivariate discriminant analysis clearly distinguished biomarker response between clean and polluted areas, using heavy metals as indicator of pollution. Such differences disappeared when the dataset was normalised for metal content, thus indicating that pollution was the main significant cause of the changes observed between clean and polluted sites. In conclusion, this work shows that, when applying a complete biomarker panel, multivariate statistical tools can be used to discern pollutant- from non pollutant-related responses.     

Bioremediation of petroleum hydrocarbons in anoxic marine sediments: Consequences on the speciation of heavy metals

We investigated the effects of biostimulation and bioagumentation strategies applied to harbor sediments displaying reducing conditions and high concentrations of petroleum hydrocarbons and heavy metals. We compared the microbial efficiency of hydrocarbon removal from sediments maintained for 60 days in anoxic conditions and inoculated with acetate, sulfate-reducing bacterial strains and acetate and sulfate-reducing bacteria. All treatments determined a significant increase in the microbial growth and significant decreases of hydrocarbon contents and of redox potential values. The addition of sulfate-reducing bacterial strains to the sediment was the most efficient treatment for the hydrocarbon removal. In all experiments, significant changes of the heavy metals’ phase repartition were observed. The results reported here suggest that the biodegradation of petroleum hydrocarbons in anoxic marine sediments may be enhanced by stimulating microbial anaerobic metabolism, but care should be applied to monitor the potential changes in the mobility and bioavailability of heavy metals induced by bio-treatments.     

Coseismic Three-Dimensional Displacements Determined Using SAR Data: Theory and an Application Test

We present a methodology to construct three-dimensional deformation maps using different parameters that can be extracted using SAR data. We apply the methodology using ENVISAT SAR data before and after the December 26^th, 2003 M_w 6.6 Bam earthquake in Iran to determine spatial quasi-continuous three-dimensional coseismic deformation maps. Two near vertical deformation offset components are computed using Envisat ASAR differential interferometry (DInSAR), while two horizontal deformation offset components are measured using sub-pixel correlation techniques applied to ASAR amplitude images. Using the presented methodology, we combine four unevenly precise independent projections of surface coseismic deformation to obtain the full three-dimensional coseismic deformation field caused by an earthquake. The full 3-D coseismic displacement vector is modeled using elastic deformation models constraining details of the fault geometry and slip distribution at depth. Results from the inversion are interpreted in the framework of the Iranian present-day tectonism. Full exploitation of dense 3-D coseismic surface deformation using SAR data, even for moderate earthquakes, should facilitate distinguishing between different interpretations of the mechanical properties of seismically active areas and within the inherent ambiguity of the geophysical inversion solutions.