On granitoid emplacement and related structures. A review

Granitoid magmas are emplaced at the upper crust under a complex interaction of gravitational processes and horizontal tectonics. Natural intrusive bodies show a wide variety of structural patterns that must be strongly related with their dynamic history of ascent and emplacement. Comparisons of natural structural patterns with experimental and numerical models are necessary to interpret in a coherent fashion the emplacement mechanism involved.From natural, experimental, numerical and theoretical considerations one can reach important conclusions on the problem of ascent and final emplacement of granitoid magmas in the Earth's crust. The present paper reviews the principal emplacement mechanisms referred to in the literature; that is, doming, diapirism, ballooning, stoping, cauldron subsidence and dike propagation.Dike propagation is the most effektive process in magma transport from deep zones in the crust and upper mantle. Extensional fractures for dike propagation and magma ascent can be developed at depth in the crust according to the modern dike propagation theory. In orogenic domains, magmas reach the upper crust through narrow channels or dikes and are accumulated in a final reservoir in the form of a discordant supracrustal pluton or a ballooning pluton if, during emplacement, any regional deformation acts simultaneously.

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Zusammenfassung Die Intrusion granitischer Magmen in die obere Krust ist das Ergebnis eines komplexen Zusammenspiels von schwerkraftbedingten Prozessen und horizontalen, tektonichen Bewegungen. Die gro\e Vielfalt tektonischer Strukturen von granitischen Plutonen spiegelt die Geschichte der Dynamik, ihres Aufstieges und ihrer Platznahme wider. Um den jeweils vorhandenen Intrusionsmechanismus zusammenhängend deuten zu können, sind Vergleiche der natürlichen, tektonischen Elemente mit experimentellen und numerischen Modellen notwendig. Hieraus lassen sich gegebenenfalls weitreichende Schlüsse zum Problem des Aufstiegs und der endgültigen Platznahme der Magmen in der Erkruste ziehen.In dieser Arbeit werden die wesentlichen Aufstiegsmechanismen von Magmen aus der Literatur diskutiert. Im Einzelnen sind dieses: Aufwölbung, Diapirismus, Aufweitung, Abbau, Kraterbildung und Gangentwicklung.Das Vordringen von Gängen ist der wirksamste Proze\ des Magmentransports aus tieferen Zonen der Kruste und des oberen Mantels. Ausdehnungsklüfte lassen sich als Ursache für das Vordringen von Gängen und den Magmenaufstieg nach der heutigen Theorie über die Entwicklung von Gängen in der tiefen Kruste herleiten. In orogenen Zonen erreichen Magmen die obere Erdkruste durch enge Kanäle oder Gänge und reichern sich dort auch in Form eines dikordanten, subkrustalen oder aufgweiteten Plutons an, wenn gleichzeitig mit der Platznahme regionaltektonische Deformationen ablaufen.

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Resumen Los magmas graníticos se emplazan en la corteza superior bajo una compleja interaccion entre procesos gravitatorios y tectónica horizontal. Los cuerpos intrusivos naturales muestran una amplia variedad de patrones estructurales que pueden estar directamente relacionados con la dinámica de ascenso y emplazamiento. Para explicar de forma cohérente el mecanismo de emplazamiento implicado en un plutón es necesario establecer comparaciones entre patrones estructurales de plutones y modelos experimentales y numéricos.A partir de consideraciones naturales, experimentales, numéricas y teóricas, se pueden extraer importantes conclusiones sobre el problema del ascenso y emplazamiento de magmas en la corteza. En este trabajo se revisan los principales mecanismos de emplazamiento referidos en la literatura; es decir, doming, diapirismo, ballooning, stoping, cauldron subsidence y propagación de diques.Propagación de diques es el proceso más efectivo en el transporte de magmas desde zonas profundas en la corteza y manto superior. De acuerdo con la moderna teoría de propagación de diques, las fracuras extensionales pueden producirse en profundidad en la corteza. En dominios orogénicos, los magmas alcanzan la corteza superior a través de estrechos canales o diques y se acumulan en un reservorio final, bien en forma de plutones discordantes supracrustales, o bien en la forma de un »ballooning pluton« si durante el emplazamiento actûa alguna deformación regional.

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Kinetics of reactions between aqueous sulfates and sulfides in hydrothermal systems

The rates of chemical reactions between aqueous sulfates and sulfides are essentially identical to sulfur isotopic exchange rates between them, because both the chemical and isotopic reactions involve simultaneous oxidation of sulfide-sulfur atoms and reduction of sulfate-sulfur. The rate of reaction can be expressed as a second order rate law: R = k·[∑SO₄^2?]·[∑S^2?], where R is the overall rate, k is the rate constant and [∑SO₄^2?] and [∑S^2?] are molal concentrations. We have computed the rate constants from the available experimental data on the partial exchange of sulfur isotopes between aqueous sulfates and sulfides using the rate law established by us: $\text{ln(}\text{α}{}^{\mathrm{e}}\text{? α}\text{α}{}^{\mathrm{e}}\text{? α}{}^0\text{) = ? kt([∑SO}{}_4{}^{\mathrm{2?}}\text{] + [∑S}{}^{\mathrm{2?}}\text{])}$, where t is time and α⁰, α, and α^e are, respectively, the fractionation factors at t = 0 (the initial condition), at the end of experiment, and at equilibrium. The equilibrium fractionation factor can be expressed as: $\text{1000 ln α}{}^{\mathrm{e}}\text{=}\text{6.463 × 10}{}^6\text{T}{}^2\text{+ 0.56 (±.5)}$ (T in Kelvin).The rate constants are strongly dependent on T and pH, but not in as simple a manner as suggested by Igumnov (1976). Our rate constants in Na-bearing hydrothermal solutions decrease by 1 order of magnitude with an increase in pH by 1 unit at pH's less than ~3, remain constant in the pH range of ~4 to ~7, and again decrease at pH >7. The activation energy for the reaction also depends on pH: 18.4 ± 1 kcal/mole at pH = 2, 29.6 ± 1 kcal/mole at pH = 4 to 7, and between 40 and 47 kcal/mole at pH around 9. The observed pH dependence of the rate constant and of the activation energy can be best explained by a model involving thiosulfate molecules as reaction intermediates, in which the intramolecular exchange of sulfur atoms in thiosulfates becomes the rate determining step.The rate constants obtained in this study were used to compute the changes in the isotopic fractionation factors between aqueous sulfates and sulfides during cooling of fluids. Comparisons with data of coexisting sulfate-sulfide minerals in hydrothermal deposits, suggest that simple cooling was not a likely mechanism for coprecipitation of sulfate and sulfide minerals at temperatures below 350°C. Mixing of sulfide-rich solutions with sulfate-rich solutions at or near the depositional sites is a more reasonable process for explaining the observed fractionation.The degree of attainment of chemical equilibrium between aqueous sulfates and sulfides in a hydrothermal system, and the applicability of a_O2-pH type diagrams to mineral deposits, depends on the ∑S content and the thermal history of the fluid, which in turn is controlled by the flow rate and the thermal gradient in the system.The rates of sulfate reduction by non-bacterial processes involving a variety of reductants are also dependent on T, pH, [∑SO₄^2?], and [∑S^2?], and appear to be fast enough to become geochemically important at temperatures above about 200°C.     

Frequency relationship for seismic Qβ of central southern Italy from accelerograms for the Irpinia earthquake (1980)

The frequency dependence of Q_β for seismic waves in a distance range with a maximum of 150 km from the epicentre of the Irpinia earthquake of November 23, 1980 has been sought using displacement spectral ratios computed from strong-motion accelerograms recorded in the region. The method has been applied to calculate the behaviour of Q_β as a function of frequency in the band 0.1–25 Hz, and to investigate whether azimuthal variations appear in seismic Q_β for the lithosphere in central southern Italy. The same result is obtained using data from stations in western south Italy as using data from eastern south Italy, namely,

$\text{Q}{}_{\mathrm{\beta }}\text{(f) = 40f (}\text{Hz}\text{)}$

The linear relationship suggest that apparent Q_β depends more on the scale of heterogeneity of the lithosphere, affecting reflection and scattering mechanisms, than on intrinsic energy losses related to the anelasticity of the materials through which the seismic waves propagate.The existence of a peak in Q_β^?1 has been investigated in the low-frequency band (0.1–2.5 Hz) using a higher resolution power. A stable result in this low-Q_β zone is not possible on the basis of the available data: only in six Q_β(f) profiles does an evident minimum exist, between 0.2 and 1 Hz, while in nine cases the curves are monotonically increasing from the lowest observable frequencies; a further nine cases appear of uncertain interpretation.     

Granulite-amphibolite facies metasediments from the Serre (Calabria,Southern Italy): their protoliths and the processes controlling their chemistry

In the northwestern Serre, a near continuous section through the Palaeozoic lower continental crust crops out. This paper deals with granulite facies metasedimentary rocks of this section. Fifty-five chemical analyses (major elements, Sc, V, Cr, Co, Ni, Rb, Sr, Y, Nb and Ba) are given. Chemical data indicate that the original sedimentary sequence was made up of arenites in the lower part and mainly Fe and Mg rich pelites in the upper part. The metapelites experienced anatexis and removal of some melt, whereas the meta-arenites suffered only incipient anatexis and became dehydration granulites. The various rock types display an overall relatively low K/Rb ratio due mainly to the stability of K- and Rb-retaining phases. A weighted mean composition of the fragment of the lower continental crust outcropping in the Serre has been established by integrating the chemical data for metasediments (55 analyses), metabasites (92 analyses) and dioritic and tonalitic gneisses (10 analyses) with the field data. This composition compared to the compositions of the bulk continental crust and of other sections considered as belonging to the lower crust, confirms the hypothesis that (1) the lower crust is heterogeneous, and (2) it is more basic than the continental crust.     

Analysis of the weightiness of site effects on reinforced concrete (RC) building seismic behaviour: The Adra town example (SE Spain)

The damage distribution in Adra town (south‐eastern Spain) during the 1993 and 1994 Adra earthquakes (5.0 magnitude), that reached a maximum intensity degree of VII (European Macroseismic Scale (EMS scale)), was concentrated mainly in the south‐east zone of the town and the most relevant damage occurred in reinforced concrete (RC) buildings with four or five storeys. In order to evaluate the influence of ground condition on RC building behaviour, geological, geomorphological and geophysical surveys were carried out, and a detailed map of ground surface structure was obtained. Short‐period microtremor observations were performed in 160 sites on a 100m × 100m dimension grid and Nakamura's method was applied in order to determine a distribution map of soil predominant periods. Shorter predominant periods (0.1–0.3 s) were found in mountainous and neighbouring zones and larger periods (greater than 0.5 s) in thicker Holocene alluvial fans. A relationship T = (0.049 ± 0.001)N, where T is the natural period of swaying motion and N is the number of storeys, has been empirically obtained by using microtremor measurements at the top of 38 RC buildings (ranging from 2 to 9 storeys). 1‐D simulation of strong motion on different soil conditions and for several typical RC buildings were computed, using the acceleration record in Adra town of the 1993 earthquake. It is noteworthy that all the aforementioned results show the influence of site effects in the degree and distribution of observed building damage. Copyright © 2007 John Wiley & Sons, Ltd.     

ON THE NUMBER OF FRACTIONS TO COMPUTE TRANSPORT OF SEDIMENT MIXTURES

1 INTRODUCTIONMany hydro-momhological mathematical models neglect the innuence of river bed maerialheterogeneity and its time and space changes during transport and related erosion/dePosition processes. Inthese models a rePresentative diameter of the river bed grain-size distribution (for examPle d5o) isspecified as initial data in each comPutational point of the modeled domain. Different d5o can be assignedto each ghd point but temPoral changes in bed material gradation cannot be simula…     

Natural and anthropogenic C2 to C6 hydrocarbons in the central-eastern Venezuelan atmosphere during the rainy season

The levels of low molecular weight hydrocarbons were measured at pristine sites and rural locations affected by hydrocarbon emissions from oil and gas producing fields in Venezuela. At the clean sites, lower concentrations of C₂ to C₆ alkanes were observed, whereas, in comparison with remotes sites, very much higher levels were measured at the polluted sites. Alkenes present relatively high concentrations, with isoprene being the most abundant, all over the study region. The main sources of alkenes are likely to be natural, mainly from vegetation. The levels of alkanes recorded at the clean sites and the alkene levels found everywhere in the region are in agreement with the values reported for other clean sites in the tropics. The increase of ozone production capacity due to the anthropogenic emissions of alkanes from oil and gas fields was estimated. Due to the presence in the atmosphere of important amounts of naturally emitted isoprene, ethene and propene, which makes a substantial contribution to the reactivity of the hydrocarbon mixture, a small increase (<5%) was estimated to occur in the capacity of the ozone production at a regional scale during the rainy season.     

Ondes de surface

Résumé Le but de ce mémoire est de démontrer quelques nouvelles propriétés générales d'une classe de fonctions (les ondes de surface) très importante par son rôle en physique et en géophysique.On commence par la démontration d'un théoréme fondamental qui établit l'identité de l'ensemble des ondes de surface et de l'ensemble des fonctions pour lesquelles, à tout instantt ₀ et en tout pointA ₀ de leur domaine d'existence, on peut écrire une proportionnalité entre intervalles de temps (situés, en général asymétriquement, de part et d'autre det ₀) et rayons des domaines circulaires centrés enA ₀, telle que les moyennes temporelles et spatiales correspondantes soient égales. Ce théorème permet d'écrire, en termes finis, la solution des équations aux dérivées partielles de toute onde de surface.On applique ensuite les résultats généraux: 1° à la variation diurne de la pression lce qui permet de voir que ce phénomène peut être considéré comme une onde de surface et donne la loi fondamentale en cos³ ( latitude) pour l'amplitude de l'onde semidiurne progressive]; 2° aux ondes de variation de la pression synoptique. Pour ces ondes de variation on établit les relations qui existent entre leurs paramètres caractéristiques et on détermine finalement leur configuration théorique.

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Summary The aim of this paper is to give the proof of some new general properties of a class of functions (the surface waves) which is very important in physics and geophysics.We first give the proof of a fundamental theorem establishing the identity of the set of all surface waves and the set of functions for which, at any momentt ₀ and at any pointA ₀ of their domain, there exists a proportionality between time intervals comprisingt ₀ (asymmetrically, in the general case) and the radius of the circular domains centered onA ₀, such that the corresponding temporal and spatial means are equal. This theorem allows to write in finite terms the solution of the partial differential equations of any surface wave.The general results are then applied: 1° to the diurnal pressure variation, showing that this phenomenon can be considered as a surface wave and giving the fundamental law cos³ ( latitude) for the amplitude of the progressive or travelling 12-hourly wave; 2° to the waves of the synoptic pressure variations. For these waves the relations between their characteristic parameters is first established and finally their theoretical spatial configuration or pattern is deduced.

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Communication faite le 23 Avril 1957 à la Cinquième Assemblée de la «Società Italiana di Geofisica e Meteorologia» (Genova, 23–25 Avril 1957).     

A system for large volume aerosol sampling in the stratosphere using electrostatic precipitation

Summary An instrumental system for securing aerosol samples in the stratosphere by electrostatic precipitation has been developed. The system is designed to be balloon borne to altitudes between 30 km and 45 km and to collect with high efficiency the aerosol content of the stratosphere at these altitudes. Volumetric sampling rates of one meter³ sec^–1 ambient air are obtained with the sampling configuration with collection efficiency in excess of 95 percent for particles between .01 microns (mmd) and 2 microns (mmd).Specially developed associated instrumentation for altitude and air flow measurement points to an important versatility in the application of gas discharges for low-pressure (or high altitude) altimetry and anemometry over a very wide range of air densities and tempertures.The theory, operation, and performance of the aerosol sampling system and associated subsytems are described. Certain new observations of low-density corona physics phenomena are reported and potential applications to other areas of research and technology are indicated.

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Zusammenfassung Es wurde ein Instrument entwickelt, mit dem man Aerosolproben aus der Stratosphäre durch elektrostatischen Niederschlag erhalten kann. Das System wird von einem Ballon in Höhen zwischen 30 und 45 km getragen und sammelt mit hoher Wirksamkeit Proben des Aerosolgehalts in diesen Höhen. Mit dem Instrument wird eine Sammelgeschwindigkeit von 1 m³/sek erreicht bei einer Sammelwirksamkeit von mehr als 95% für Partikel von Größen zwischen 0,01 und 2 Mikron.Besonders entwickelte angeschlossene Instrumente zur Messung der Höhe und der Luftströmungen zeigen die wesentliche Vielseitigkeit der Anwendung von Gasentladungen für die Höhenmessung und Windmessung bei niedrigem Druck (oder in großen Höhen) in einem großen Bereich der Luftdichte und der Temperatur.Es werden die Theorie, die Arbeitsweise und die Ausführung des Aerosolprobeninstrumentes und der angeschlossenen Hilfssysteme beschrieben. Es wird über einige neue Beobachtungen aus dem Bereich der Phänomene der Gasentladungen bei niedriger Dichte berichtet und neue mögliche Anwendungen in anderen Zweigen der Forschung und Technologie werden angegeben.

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Résumé On a construit un instrument au moyen duquel on peut obtenir des échantillons d'aérosole stratosphérique par précipitation électrostatique. Le système est emporté par un ballon à des altitudes de 30 à 45 km et rassemble avec efficacité des echantillons du contenu de l'aérosole à ces altitudes. Avec cet appareil, on obtient une vitesse de prise de 1 m³/sec avec une efficacité de plus de 95% pour les particules comprises entre 0,01 et 2 microns.Des appareils spéciaux annexes permettent de mesurer la hauteur et les courants d'air. Ils démontrent les possibilités multiples de l'utilisation de la décharge dans un gaz pour la mesure de l'altitude et des vents par pression très faible (ou à très haute altitude) dans un domaine étendu tant de la densité de l'air que de la température.On décrit dans ce mémoire la théorie, le mode de travail et l'exécution de cet instrument de prise d'échantillons d'aérosoles ainsi que des systèmes auxiliaires annexes. On rapporte sur quelques nouvelles observations faites dans le domaine des phénomènes connexes à la décharge dans un gaz par faible densité. On indique en outre de nouvelles possibilités d'utilisation du système dans d'autres branches de la recherche ou de la technologie.

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With 16 Figures

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This work has been supported by the Division of Biology and Medicine, U. S. Atomic Energy Commission, under contract at (30-1)-2363 with Del Electronics.     

Relations entre le creusement et le comblement des perturbations et leur déplacement

Résumé On commence par définir le creusement et le comblement d'une fonctionp(, t) du tempst et des points (, ) d'une surface régulière fermée en se donnant, sur cette surface, un vecteur vitesse d'advection ou de transfert tangent à . Le creusement (ou le comblement) est la variation dep sur les particules fictives se déplaçant constamment et partout à la vitesse , A chaque vecteur et pour un mêmep(, ,t) correspond naturellement une fonction creusementC (, ,t) admissible a priori; mais une condition analytique très générale (l'intégrale du creusement sur toute la surface fermée du champ est nulle à chaque instant), à laquelle satisfont les fonctions de perturbation sur les surfaces géopotentielles, permet de restreindre beaucoup la généralité des vecteurs d'advection admissibles a priori et conduit à des vecteurs de la forme: , oùT est un scalaire régulier, () une fonction régulière de la latitude , le vecteur unitaire des verticales ascendantes etR/2 une constante. Ces vecteurs sont donc une généralisation naturelle des vitesses géostrophiques attachées à tout scalaire régulier. Dans le cas oùp(, ,t) est la perturbation de la pression sur la surface du géoïde, le vecteur d'advection par rapport auquel on doit définir le creusement est précisément une vitesse géostrophique: on a alors ()=sin etT un certain champ bien défini de température moyenne.On déduit ensuite une formule générale de géométrie et de cinématique différentielles reliant la vitesse de déplacement d'un centre ou d'un col d'un champp(, ,t) à son champ de creusementC (, ,t) et au vecteur d'advection correspondant. Cette formule peut être transformée et prend la forme d'une relation générale entre le creusement (ou le comblement) d'un centre ou d'un col et la vitesse de son déplacement, sans que le vecteur d'advection intervienne explicitement. On analyse alors les conséquences de ces formules dans les cas suivants: 1^o) perturbations circulaires dans le voisinage du centre; 2^o) perturbations ayant, dans le voisinage du centre, un axe de symétrie normal ou tangent à la vitesse du centre; 3^o) évolution normale des cyclones tropicaux.Finalement, on examine les relations qui existent entre le creusement ou le comblement d'un champ, le vecteur d'advection et la configuration des iso-lignes du champ dans le voisinage d'un centre.Ces considérations permettent d'expliquer plusieurs propriétés bien connues du comportement des perturbations dans différentes régions.

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Summary The deepening and filling (development) of a functionp(, ,t) of the timet and the points (, ) of a regular closed surface is first of all defined, in respect to a given advection or transfer velocity field tangent to , as the variation ofp on any fictitious particle moving constantly and everywhere with the velocity . For a givenp(, ,t) and to any there corresponds a well defined development fieldC (, ,t). All theseC fields are a priori admissible, but a very general analytical condition of the perturbation fields in synoptic meteorology (the integral of the development fieldC (, ,t) on any geopotential surface vanishes at any moment), leads to an important restriction to advection vectors of the form: , whereT is any regular scalar, () any regular function of latitude, the unit vector of the ascending verticals andR/2 a constant. These vectors are a natural generalisation of the geostrophic velocities attached to any regular scalar. Whenp(, ,t) is the pressure perturbation at sea level, its development must be defined in respect to a geostrophic advection vector belonging to the above defined class of vectors with ()=sin andT a well defined mean temperature field.A general formula of the differential geometry and kinematics ofp(, ,t) is then derived, giving the velocity of any centre and col of ap(, ,t) as a function of the advection vector and the corresponding development fieldC (, ,t). This formula can be transformed and takes the form of a general relation between the deepening (and filling) of a centre (or a col) of ap(, ,t) and its displament velocity, the advection vector appearing no more explicitly. A detailed analysis of the consequences of these formulae is then given for the following cases: 1^o) circular perturbations in the vicinity of a centre; 2^o) perturbations having, in the vicinity of a centre, an axis of symmetry normal or tangent to the velocity of the centre; 3^o) normal evolution of the tropical cyclones.Finally, the relations between the developmentC (, ,t) of a fieldp(, ,t), the advection velocity vector and the configuration of the iso-lines in the vicinity of a centre are analysed.These theoretical results give a rational explanation of several well known properties of the behaviour of the perturbations in different geographical regions.

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Communication à la 2ème Assemblée de la «Società Italiana di Geofisica e Meteorologia» (Gênes, 23–25 Avril 1954).