Environmental Characteristics of Lake Tecocomulco, northern basin of Mexico, for the last 50,000 years

Paleoenvironmental studies have documented the late Pleistocene to Holocene evolution of the lakes in the central and southern parts of the basin of Mexico (Texcoco and Chalco). No information was available, however, for the lakes in the north-eastern part of this basin. The north-eastern and the central and southern areas represent, at present, different environmental conditions: an important gradient exists between the dry north and the moister south. To investigate the late Pleistocene to Holocene characteristics of the north-eastern lakes in the basin of Mexico two parallel cores (TA and TB) were drilled at the SE shore of Lake Tecocomulco. Stratigraphy, magnetic properties, granulometry, diatom and pollen analyses performed on these sediments indicate that the lake experienced a series of changes between ca. > 42,000 yr BP and present. Chronological control is given by five radiocarbon determinations. The base of the record is represented by a thick, rhyolitic air-fall tephra that could be older than ca. 50,000 yr BP. After this Plininan event, and until ca. 42,000 yr BP, Lake Tecocomulco was a moderately deep, freshwater lake surrounded by extended pine forests that suggest the presence of cooler and moister conditions than present. Between ca. 42,000 and 37,000 yr BP, the lake became shallower but with important fluctuations and pollen suggests slightly warmer conditions. Between ca. 37,000 and 30,000 yr BP the lake experienced two relatively deep phases separated by a dry interval. A second Plinian eruption, represented in the sequence by a dacitic an air-fall tephra layer dated at 31,000 yr BP, occurred in the area by the end of this dry episode. Between ca. 30,000 and 25,7000 yr BP Tecocomulco was a fresh to slightly alkaline lake with a trend towards lower level. After ca. 25,700 yr BP very low lake levels are inferred, and after ca. 16,000 yr BP the data indicate the presence of a very dry environment that was persistent until the middle Holocene. After 3,500 yr BP lacustrine conditions were re-established and the vegetation cover shows a change towards higher percentages of herbaceous taxa.     

Jobs and the Single Parent: An Analysis of Accessibility to Employment in Toronto

Abstract

In this article, we undertake an analysis of accessibility to jobs from the perspective of single-parent household members. Individuals in this demographic segment are of interest due to the fact they often face the double burden of household and employment responsibilities. A case study of the city of Toronto in Canada, an urban area that has seen an increase in absolute and relative numbers of single-parent households in recent years, is presented. Analysis is based on the application of relative accessibility deprivation indicators (RADI), which are calculated using model-based estimates of distance traveled for various population segments, as well as employment data for the city and its surroundings. The results of the analysis indicate that there are substantial differences in the levels of accessibility to jobs between members of single-parent households, in particular females, and members of other types of households.     

Structure of the rift basins in the central Gulf of California: Kinematic implications for oblique rifting

We use structural and seismostratigraphic interpretation of multichannel seismic reflection data to understand the structure and kinematic history of the central Gulf of California. Our analysis reveals that oblique strain in the central Gulf formed two tectono–sedimentary domains during distinct deformation stages. The eastern domain, offshore Sonora, is bounded by the East and West Pedro Nolasco faults that may constitute the southernmost segments of the Tiburón Fault System. Within this domain, the dip-slip Yaqui Fault controlled deposition of 3.9 km of sediments in the half-graben Yaqui Basin. The western domain, offshore Baja California, is bounded by the Guaymas Transform Fault, which controlled the accumulation of 1.45 km of sediments within a half-graben that formed the early Guaymas Basin. The tectono–sedimentary activity offshore Sonoran likely ranges from Late Miocene–Pliocene to Late Pliocene time, while activity in the Guaymas Basin commenced in Late Pliocene time. Extinction of the main faults offshore Sonora was nearly coeval to the initiation of the Guaymas Transform Fault. Our results suggest that oblique strain has been accommodated by strain partition since the onset of rifting in the central Gulf. The Guaymas Basin is now a nascent spreading center, but prior to this, it evolved as a half-graben controlled by the Guaymas Transform Fault; such drastic transition is not constrained, but likely occurred during the Pleistocene time and must be localized < 30 km north of the axial troughs. The faults within the central Gulf transpose the Miocene N–S oriented grabens of Basin and Range style preserved onshore in the conjugate rifted margins.     

Assessment of the topsoil heavy metals pollution in the Sarno River basin,south Italy

The Sarno River basin area is one of the most polluted in Europe and it is due to the waste products of the tomato industry, the leather tanneries and the pharmaceutical industry. This area also has been densely populated and urbanized since the Middle Bronze Age, as testified by the presence of numerous archeological sites, including the ancient Pompeii town, and environmental degradation that characterizes the area is absolutely unacceptable. This paper represents a detailed study to assess the potentially harmful element content of topsoils. In total, 283 soil samples were collected and analyzed, after an aqua regia extraction, by a combination of inductively coupled plasma atomic emission and inductively coupled plasma mass spectrometry for 53 elements. Univariate and multivariate analyses were carried out to show the single-element geochemical distribution and the distribution of factor scores of the elemental associations resulting from R-mode factor analysis. Maps showing elements and the association factor score distributions have been obtained using GeoDAS and ArcGIS software. The assessment of the soil contamination was also carried out using the contamination factor and degree of contamination. The results obtained indicate that soil pollution has different anthropogenic sources. Specifically, Cr pollution derives from tanneries discharging wastewaters in the main water bodies of the basin while Cu contamination seems to depend on widespread agricultural practices. Tin, Pb, Hg, Zn, Cd, Sb anomalies are found mainly in urban and industrial areas, sometimes close to roads with high traffic levels while there is a substantial coincidence with background values for other elements (Co, Ni, Se, Tl and V).     

Metal distributions and their fluxes at the coastal boundary of a semi-enclosed ria

Water column samples have been collected in the outer channel of the Ferrol Ria (NW Spain) during four occasions over a tidal cycle. The objective was to study the exchange of dissolved and particulate Cd, Cu, Pb and Zn and particulate Al, Fe and Si between the ria and the adjacent coastal waters. This study provides the first extensive dataset on dissolved and particulate metal concentrations in the water column of a Galician ria. Typical concentrations of dissolved Cd (96 ± 31 pM), Cu (8 ± 4 nM), Pb (270 ± 170 pM) and Zn (21 ± 10 nM) were similar than in other European Atlantic shelf and coastal waters. The fraction of metals in the particulate phase followed the trend: Pb > Cu Zn > Cd. The outgoing water from the ria was enriched in dissolved and particulate Cu, Pb and Zn compared with incoming waters, whereas Cd concentrations were similar for both waters. The suspended particulate matter was composed of a mixture of marine and continental material. The latter end-member was found to arise from the metal-rich ria bed sediments, which is diluted by the dominant metal-poor marine end-member. The net output flux of Cu from the channel is balanced by the freshwater inputs to the ria, and the net Zn flux gave a positive output to coastal waters. For Pb, the net flux to the coastal waters is less than that input from the rivers, as a result of its particle reactivity and deposition in sediments. On the contrary, a net input flux of dissolved Cd from coastal waters was observed, highlighting the oceanic source of this metal in the Galician rias. Results from the budget calculations are in agreement with the differential geochemical behavior of these elements in coastal waters.     

Winter and summer characterization of biogenic enantiomeric monoterpenes and anthropogenic BTEX compounds at a Mediterranean Stone Pine forest site

Measurements of biogenic gases including enantiomeric monoterpenes and isoprene, and anthropogenic gases such as benzene, toluene, ethylbenzene, ortho-, meta- and para- xylene (BTEX) compounds were made by GC-MS in November and December 2008 within a stone pine (Pinus pinea L) forest located on the Southwest coast of Spain (37.10°N, 6.70°W). Mixing ratios of the biogenic species were found to be low (mean circa 10 pptv) consistent with previously observed low wintertime regional forest emission rates. In contrast, anthropogenic species were significantly higher (mean 10–156 pptv), the dominant emissions originating from the city of Huelva and associated petrochemical activities, located 25 km north west of the measurement site. In wintertime the monoterpene (?)-α-pinene was found to be in slight enantiomeric excess over (+)-α-pinene at night but by day the measured ratio was closer to one i.e. racemic. Samples taken the following summer in the same location showed much higher monoterpene mixing ratios and revealed a strong enantiomeric excess of (?)-α-pinene. This indicates a strong seasonal variance in the enantiomeric emission ratio which is not manifested in the day/night temperature cycles in wintertime. Mixing ratios of the xylene isomers (meta- and para-) and ethylbenzene, which are all well resolved on the beta-cyclodextrin column, were exploited to estimate average OH radical exposures to VOCs from the Huelva industrial area. These were compared to empirical estimates of OH based on JNO₂ measured at the site. The deficiencies of each estimation method are discussed.     

Altimetry with GNSS-R interferometry: first proof of concept experiment

The Global Navigation Satellite System Reflectometry (GNSS-R) concept was conceived as a means to densify radar altimeter measurements of the sea surface. Until now, the GNSS-R concept relied on open access to GNSS transmitted codes. Recently, it has been proposed that the ranging capability of the technique for ocean altimetric applications can be improved by using all the signals transmitted in the bandwidth allocated to GNSS, which includes open access as well as encrypted signals. The main objective of this study is to provide experimental proof of this enhancement through a 2-day experiment on the Zeeland Bridge (The Netherlands). In the experiment, we used a custom built GNSS-R system, composed of high gain GPS antennas, calibration subsystem, and an FPGA-based signal processor which implemented the new concepts, an X-band radar altimeter and a local geodetic network. The results obtained indicate that the new approach produces a significant improvement in GNSS-R altimetric performance.