Petrographic and trace element analysis of uranium-rich tufa calcite, middle Miocene Barstow Formation, California, USA

An integrated petrographic and spectroscopic (X‐ray diffraction, phosphor imaging and synchrotron X‐ray absorption spectroscopy) study of tufas from the Miocene Barstow Formation, California, relates sample morphology, mineralogy and geochemical composition. The tufas, composed mainly of calcite that formed at the interface between an ancient alkaline lake and ground or spring waters, have textures similar to those of microbially mediated terrestrial stromatolites and travertines. The tufas have elevated concentrations of a number of trace elements including Mn, Fe, Sr and U. Synchrotron X‐ray fluorescence analyses show that U concentrations can exceed 500 p.p.m. X‐ray absorption spectroscopy indicates that the U in these samples is incorporated as U(IV). It is suggested here that alkaline lake waters had a high U/Ca ratio and tufa calcite formed where groundwater or (possibly epithermal) springs brought in Ca and trace elements such as Sr. The rapid, and possibly microbially mediated, precipitation of calcite allowed for incorporation of high concentrations of trace metals as either structural substitutes or extremely fine‐scale inclusions.     

Contourite origin for shelf and upper slope sand sheet, offshore Antarctica

A widespread (3200 km²), thick (10 cm to > 100 cm) sand deposit exists on the continental shelf and upper slope offshore of the Pennell Coast, Antarctica. The sand body occurs at water depths between 200 and 1200 m. The mean grain size of the sand varies from 3·3 phi to 1·2 phi, and the composition is dominantly volcanic. The only source for this volcanic material is Cape Adare, a volcanic headland. Sands are transported up to 70 km from Cape Adare by a westward‐flowing circumpolar boundary current that impinges on the upper slope and shelf. Radiocarbon dates from the sand and from the glacial unit beneath it indicate that the deposit formed within the past 9000 years. The occurrence of this sand sheet demonstrates the ability of contour currents to assemble extensive sand bodies on the shelf and upper slope and the relatively rapid rate at which these deposits may form.     

Recent activity of Nisyros volcano (Greece) inferred from structural, geochemical and seismological data

This study summarizes the results of structural, geochemical and seismological surveys carried out at Nisyros volcano (Aegean Sea, Greece) during 1999–2001. Field mapping and mesostructural measurements at the summit caldera (Lakki plain) indicate that faults follow two main strikes: NE-SW and N-S. The N-S striking fault depicts extensional features accommodating the left-lateral component of motion of the NE-SW- striking main faults. The NE-SW preferred strike of the Lakki faults and of the mineral-filled veins as well as the distribution and NE-SW elongation of the hydrothermal craters indicate that tectonics plays a major role in controlling the fluid pathway in the Nisyros caldera. The same NE-SW trend is depicted by CO₂ anomalies revealed through detailed soil CO₂ flux surveys, thus indicating a structural control on the pattern of the hydrothermal degassing. Degassing processes account for a thermal energy release of about 43 MW, most of which occurs at Lofos dome, an area that was affected by hydrothermal eruptions in historical times. The seismic study was conducted in June 2001, using a deployment specifically aimed at detecting signals of magmatic-hydrothermal origin. Our instruments recorded local and regional earthquakes, a few local long-period events (LP), and bursts of monochromatic tremor. Local earthquake activity is concentrated beneath the caldera, at depths generally shallower than 6 km. Plane-wave decomposition of tremor signal indicates a shallow (<200 m) source located in the eastern part of the caldera. Conversely, LP events depict a source located beneath the central part of the caldera, in the area of Lofos dome, at depths in the 1–2-km range. In agreement with geochemical and structural measurements, these data suggest that both the deeper and shallower part of the hydrothermal system are subjected to instability in the fluid flow regimes, probably consequent to transient pressurization of the reservoir. These instabilities may be related to input of hot fluids from the deeper magmatic system, as suggested by the variations in geochemical parameters observed after the 1997–1999 unrest episode. The significance of seismological and geochemical indicators as precursors of hydrothermal explosive activity at Nisyros is discussed.Editorial responsibility: H. Shinohara     

Sensitivity of PSHA results to ground motion prediction relations and logic-tree weights

Epistemic uncertainty in ground motion prediction relations is recognized as an important factor to be considered in probabilistic seismic hazard analysis (PSHA), together with the aleatory variability that is incorporated directly into the hazard calculations through integration across the log-normal scatter in the ground motion relations. The epistemic uncertainty, which is revealed by the differences in median values of ground motion parameters obtained from relations derived for different regions, is accounted for by the inclusion of two or more ground motion prediction relations in a logic-tree formalism. The sensitivity of the hazard results to the relative weights assigned to the branches of the logic-tree, is explored through hazard analyses for two sites in Europe, in areas of high and moderate seismicity, respectively. The analyses reveal a strong influence of the ground motion models on the results of PSHA, particularly for low annual exceedance frequencies (long return periods) and higher confidence levels. The results also show, however, that as soon as four or more relations are included in the logic-tree, the relative weights, unless strongly biased towards one or two relations, do not significantly affect the hazard. The selection of appropriate prediction relations to include in the analysis, therefore, has a greater impact than the expert judgment applied in assigning relative weights to the branches of the logic-tree.     

Benthic microbial abundance and activities in an intensively trawled ecosystem (Thermaikos Gulf, Aegean Sea)

Abundance of benthic bacteria, heterotrophic nanoflagellates and ciliates, extracellular enzymatic activities, bacterial C production, C mineralisation and sediment community oxygen consumption rates were measured in the Thermaikos Gulf (Northeastern Mediterranean), before (September 2001), and during intense trawling activities (October 2001 and February 2002). The biochemical composition of sedimentary organic matter has revealed that bottom trawling had an effect on the trophic state of Thermaikos Gulf. Changes on the benthic microbial food web were also recorded, during the three sampling seasons. Even though trawling-induced sediment resuspension did not alter significantly the abundance of the microbial components, with the exception of the most impacted station, it determined changes regarding their relative importance. Thus, the ratios of bacterium to nanoflagellates and ciliate to nanoflagellates abundance increased in the trawled stations, causing a sudden increase in bacterial C production, in comparison to the non-trawled station. Four months later, the effects of trawling on the microbial food web were less evident, masked possibly by the drastic decrease in the water temperature. The results of the present work suggest that bottom trawling induces alteration of the sedimentological variables and can be considered as a factor affecting the function of the microbial food web in marine coastal ecosystems. These alterations cause faster mobilisation of organic C buried in the sediment and increase nutrient concentrations and availability in the system, thus inducing an effect that could lead to coastal eutrophication.     

Magma mixing in the subvolcanic environment: petrology of the Gerena interaction zone near Seville,Spain

The mechanisms by which felsic and mafic magmas interact and approach a uniform hybrid composition through the processes of mingling and mixing have been studied in a high-level subvolcanic setting in the Spanish Hercynian at Gerena, near Seville. The compositions involved are calc-alkaline and the situation is one of tonalite-quartz diorite synplutonic dykes injected into a granitic magma chamber. The resulting hybrids include dykes, pillows and globules of tonalite with chilled margins which are variously disrupted and homogenised with the host granite. The present investigation is based on field and petrographic observations of hybridization textures, the identification of different stages in the crystallisation history of the tonalite through mineral textures, and the characterization of mineral compositions at these various stages. Proportions of the end-member magmas involved were obtained by major-oxide mixing models and tested satisfactorily with trace elements. A mechanistic model is presented to account for these observations which involves the early quenching of the tonalite when it was emplaced into the granite magma chamber. After high temperature crystallization had occurred the two magmas attained thermal equilibrium and disruption of the tonalite in the high energy regime of this subvolcanic complex resulted in dispersion of fragments and crystals through the granite giving rise to hybrid granodiorite compositions. It is argued that such high-energy flow conditions are a necessary requirement for effective hybridization in this environment in contrast to most large-scale magma chamber settings where mixing is driven by thermal and buoyancy contrasts.     

57Fe Mössbauer study of the asbestiform silicates balangeroite and carlosturanite

⁵⁷FeMössbauer spectra of the two silicate minerals balangeroite (BAL) and carlosturanite (CST) have been collected at 80 and 295 K under normal and magic angle geometry. For both minerals the spectra have been fitted with two ferrous and two ferric doublets; Fe²⁺ accounts for 80 and 62% of Fe_tot in Bal and CST, respectively. The number of doublets used to fit the spectra supports the hypotheses that: (i) in the serpentine-like structure of CST iron occupies only octahedra which lie between the tetrahedral silicate strips; (ii) the octahedral framework of BAL (actually monoclinic) is satisfactorily described with an orthorhombic sub-cell.     

Statistical relations between source parameters for low and intermediate magnitudes (Friuli, 1976)

A data set of three-component short-period digital seismograms recorded in Friuli after the strong earthquake of 6th May 1976, allowed the local magnitude M_L and the seismic moment M₀ to be estimated in the range 0 < M_L < 2. The data set including the same parameters for the higher-magnitude Friuli events (M_L 5) shows two different slopes for the relation Log M₀ = CM_L + d for the two different ranges of M_L. One finds C ~ 1.0 (for 0 < M_L < 2) and C ~1.5 (for5 M_L 6.2), respectively.This implies that apparent stress release increases at low magnitudes, while it appears to be comparatively independent of the magnitude and to have an average value of about 100 bar for higher-magnitude earthquakes. Conversely, the fault dimensions do not appear to be magnitude-dependent for M_L < 2; for higher-magnitude events the linear fault dimensions range from about 1 km at M_L ~ 5 to about 12 km for the strong earthquake of 6th May 1976 (M_L = 6.2).     

Oxygen isotopes in mammal bone phosphate: A new tool for paleohydrological and paleoclimatological research?

Oxygen isotope analyses of water in blood of humans and domestic pigs indicate that the oxygen isotope fractionation effects between ingested water and body water are the same in all specimens of the same species. The δ¹⁸O of body water has been shown to vary linearly with the mean δ¹⁸O of local meteoric water. This conclusion also holds for the bone phosphate. Thus, δ¹⁸O(PO^3?₄) values of unaltered fossil bones from humans and domestic pigs can be used to reconstruct the δ¹⁸O values of local meteoric waters during the life-times of the mammals. Such data can be used for paleohydrological and paleoclimatological studies both on land and at sea.