Mapping Phytoplankton Community Physiology on a River Impacted Continental Shelf: Testing a Multifaceted Approach

Seasonal phosphorus limitation occurs on the Louisiana continental shelf as a result of high nitrogen loads in the spring and early summer. Prior studies have assessed such nutrient limitation by laborious and time-consuming nutrient analyses, enzyme assays, and nutrient addition bioassays. We undertook surface (0.5–1 m) mapping of fast repetition rate fluorescence (FRRF) parameters to assess nutrient limitation in real time on the Louisiana continental shelf and Mississippi River plume from 29 June to 08 July, 2002 in an effort to further understand phytoplankton productivity in this region, as well as to better inform effective nutrient management strategies. Surface nutrient concentrations (NO₃⁻, NO₂⁻, NH₄⁺, PO₄³⁻), chlorophyll a biomass, alkaline phosphatase (AP) activity, and four FRRF parameters: the maximum quantum yield of photochemistry (F _v /F _m ), the functional absorption cross section for PSII, the time constant for Q _A reoxidation, and the connectivity factor, were measured during continuous underway mapping. Results from traditional methods to assess phytoplankton nutrient stress indicated widespread phosphorus limitation from the Mississippi River plume to the Atchafalaya River, manifested as high inorganic N/P ratios and elevated AP activities associated with phytoplankton biomass. The FRRF data indicated complex patterns of phytoplankton physiology that were likely driven by the rapidly changing conditions in local surface waters and heterogeneous phytoplankton community structure. Correlations of nutrient data and enzyme assays with FRRF parameters were significant but low, potentially due to differences in the manner and time scale with which nutrient limitation affects the different techniques used, indicating that further work is needed to interpret FRRF parameters in large, heterogeneous environments such as estuaries and continental shelves.     

A seismogenic zone in the deep crust indicated by pseudotachylytes and ultramylonites in granulite-facies rocks of Calabria (Southern Italy)

Pseudotachylyte veins frequently associated with mylonites and ultramylonites occur within migmatitic paragneisses, metamonzodiorites, as well as felsic and mafic granulites at the base of the section of the Hercynian lower crust exposed in Calabria (Southern Italy). The crustal section is tectonically superposed on lower grade units. Ultramylonites and pseudotachylytes are particularly well developed in migmatitic paragneisses, whereas sparse fault-related pseudotachylytes and thin mylonite/ultramylonite bands occur in granulite-facies rocks. The presence of sillimanite and clinopyroxene in ultramylonites and mylonites indicates that relatively high-temperature conditions preceded the formation of pseudotachylytes. We have analysed pseudotachylytes from different rock types to ascertain their deep crustal origin and to better understand the relationships between brittle and ductile processes during deformation of the deeper crust. Different protoliths were selected to test how lithology controls pseudotachylyte composition and textures. In migmatites and felsic granulites, euhedral or cauliflower-shaped garnets directly crystallized from pseudotachylyte melts of near andesitic composition. This indicates that pseudotachylytes originated at deep crustal conditions (>0.75 GPa). In mafic protoliths, quenched needle-to-feather-shaped high-alumina orthopyroxene occurs in contact with newly crystallized plagioclase. The pyroxene crystallizes in garnet-free and garnet-bearing veins. The simultaneous growth of orthopyroxene and plagioclase as well as almandine, suggests lower crustal origin, with pressures in excess of 0.85 GPa. The existence of melts of different composition in the same vein indicates the stepwise, non-equilibrium conditions of frictional melting. Melt formed and intruded into pre-existing anisotropies. In mafic granulites, brittle faulting is localized in a previously formed thin high-temperature mylonite bands. migmatitic gneisses are deformed into ultramylonite domains characterized by s-c fabric. Small grain size and fluids lowered the effective stress on the c planes favouring a seismic event and the consequent melt generation. Microstructures and ductile deformation of pseudotachylytes suggest continuous ductile flow punctuated by episodes of high-strain rate, leading to seismic events and melting.     

Characterization of acid mine drainage sources in the Iberian Pyrite Belt: base methodology for quantifying affected areas and for environmental management

The present work aims to propose a methodology for quantifying the sources of acid mine drainage (AMD) and to characterize the magnitude of the affected areas in the Iberian Pyrite Belt (SW Spain). Such an approach allows the creation of a support tool for managing land and natural resources valorization, which may be easily applied in similar mining regions. The motivation and usefulness of this work can be realized by focusing on two main emerging strategic issues: (1) water resources management, with the example of Alcolea dam that will receive water from affected areas in the Iberian Pyrite Belt; and (2) mineral resources valorization, especially, regarding copper exploration due to increasing market prices. The used methodology included the following general steps: it started with an inventory of the mines in the Iberian Pyrite Belt, followed by field cartography campaigns and finally the quantification of affected areas and contaminant discharges. The results of the present work serve to confirm and quantify the magnitude of the AMD pollution in the Pyrite Belt. A total affected area of about 4,847 ha was estimated. Taking into account this figure and combining it with the annual average precipitation (650 L/m²) results in an estimation of 31,503,680 m³/year of discharging water affected by the presence of sulphides. In this scenario, a total annual contribution of 260,056 tonnes/year was obtained for sulphates, which means more than 712 tonnes a day. In the case of arsenic, a toxic element, the total annual contribution is more than 20 tonnes, or close to 55 kg/day. Regarding copper, this economically interesting metal translates into total contributions of 10,364 tonnes/year in the generating medium. This gave more than 28 tonnes/day, which today sits at 8,200 dollars/tonne. This result suggests that solutions aimed at recovering this resource should be searched. It may represent a financial return at the same time that it would mean overcome environmental liabilities.     

Lunar X-ray fluorescence observations by the Chandrayaan-1 X-ray Spectrometer (C1XS): Results from the nearside southern highlands

The Chandrayaan-1 X-ray Spectrometer (C1XS) flown on-board the first Indian lunar mission Chandrayaan-1, measured X-ray fluorescence spectra during several episodes of solar flares during its operational period of ∼9 months. The accompanying X-ray Solar Monitor (XSM) provided simultaneous spectra of solar X-rays incident on the Moon which are essential to derive elemental chemistry. In this paper, we present the surface abundances of Mg, Al, Si, Ca and Fe, derived from C1XS data for a highland region on the southern nearside of the Moon. Analysis techniques are described in detail including absolute X-ray line flux derivation and conversion into elemental abundance. The results are consistent with a composition rich in plagioclase with a slight mafic mineral enhancement and a Ca/Al ratio that is significantly lower than measured in lunar returned samples. We suggest various possible scenarios to explain the deviations.     

MarcoPolo-R near earth asteroid sample return mission

MarcoPolo-R is a sample return mission to a primitive Near-Earth Asteroid (NEA) proposed in collaboration with NASA. It will rendezvous with a primitive NEA, scientifically characterize it at multiple scales, and return a unique sample to Earth unaltered by the atmospheric entry process or terrestrial weathering. MarcoPolo-R will return bulk samples (up to 2?kg) from an organic-rich binary asteroid to Earth for laboratory analyses, allowing us to: explore the origin of planetary materials and initial stages of habitable planet formation; identify and characterize the organics and volatiles in a primitive asteroid; understand the unique geomorphology, dynamics and evolution of a binary NEA. This project is based on the previous Marco Polo mission study, which was selected for the Assessment Phase of the first round of Cosmic Vision. Its scientific rationale was highly ranked by ESA committees and it was not selected only because the estimated cost was higher than the allotted amount for an M class mission. The cost of MarcoPolo-R will be reduced to within the ESA medium mission budget by collaboration with APL (John Hopkins University) and JPL in the NASA program for coordination with ESA’s Cosmic Vision Call. The baseline target is a binary asteroid (175706) 1996 FG3, which offers a very efficient operational and technical mission profile. A binary target also provides enhanced science return. The choice of this target will allow new investigations to be performed more easily than at a single object, and also enables investigations of the fascinating geology and geophysics of asteroids that are impossible at a single object. Several launch windows have been identified in the time-span 2020–2024. A number of other possible primitive single targets of high scientific interest have been identified covering a wide range of possible launch dates. The baseline mission scenario of MarcoPolo-R to 1996 FG3 is as follows: a single primary spacecraft provided by ESA, carrying the Earth Re-entry Capsule, sample acquisition and transfer system provided by NASA, will be launched by a Soyuz-Fregat rocket from Kourou into GTO and using two space segment stages. Two similar missions with two launch windows, in 2021 and 2022 and for both sample return in 2029 (with mission duration of 7 and 8?years), have been defined. Earlier or later launches, in 2020 or 2024, also offer good opportunities. All manoeuvres are carried out by a chemical propulsion system. MarcoPolo-R takes advantage of three industrial studies completed as part of the previous Marco Polo mission (see ESA/SRE (2009)3, Marco Polo Yellow Book) and of the expertise of the consortium led by Dr. A.F. Cheng (PI of the NASA NEAR Shoemaker mission) of the JHU-APL, including JPL, NASA ARC, NASA LaRC, and MIT.     

The Chandrayaan-1 X-ray Spectrometer: First results

We present X-ray fluorescence observations of the lunar surface, made by the Chandrayaan-1 X-ray Spectrometer during two solar flare events early in the mission (12th December 2008 and 10th January 2009). Modelling of the X-ray spectra with an abundance algorithm allows quantitative estimates of the MgO/SiO₂ and Al₂O₃/SiO₂ ratios to be made for the two regions, which are in mainly basaltic areas of the lunar nearside. One of these ground tracks includes the Apollo 14 landing site on the Fra Mauro Formation. Within the 1σ errors provided, the results are inside the range of basaltic samples from the Apollo and Luna collections. The Apollo 14 soil composition is in agreement with the results from the January flare at the 1σ uncertainty level. Discrepancies are observed between our results and compositions derived for the same areas by the Lunar Prospector gamma-ray spectrometer; some possible reasons for this are discussed.     

Colonisers of the dark: biostalactite‐associated metazoans from “lu Lampiùne” submarine cave (Apulia,Mediterranean Sea)

Metazoan/microbial bioconstructions, or biostalactites (BSTs), discovered in submarine caves of Apulia c. 20 years ago—and later found in several shallow‐water Mediterranean caves—are receiving increasing attention in the last years. Examination of a single BST from the “lu Lampiùne” cave (Apulia), at the limit between the Adriatic and the Ionian seas, has been addressed for the first time in this paper. The BST started growing at c. 6,000 years ago with a rapid accretion of large‐sized serpulids (Protula), slowing down since about 3,000–4,000 years ago with a shift in main bioconstructors, probably caused by environmental changes. The present‐day community on the outer BST surface is dominated by skeletonised epibionts, mostly small‐sized serpulids, bryozoans and foraminifers, which contribute carbonate to the BST growth, by encrusting sponges, and by a few endobionts, including boring bivalves and insinuating sponges. New data remarkably increase biodiversity known for the “lu Lampiùne” cave and the cave habitat in the region. Thirty‐five taxa (16 bryozoans, 10 serpulids, 3 brachiopods, 2 foraminifers, 2 sponges, 1 bivalve and 1 cirriped) are recorded for the first time from Apulian marine caves, highlighting the need for further research in the area. In addition, the BST‐associated community seems to differ from those of individual BSTs from other Mediterranean caves, revealing the individuality of these communities.     

First observation of energetic neutral atoms in the Venus environment

The ASPERA-4 instrument on board the Venus Express spacecraft offers for the first time the possibility to directly measure the emission of energetic neutral atoms (ENAs) in the vicinity of Venus. When the spacecraft is inside the Venus shadow a distinct signal of hydrogen ENAs usually is detected. It is observed as a narrow tailward stream, coming from the dayside exosphere around the Sun direction. The intensity of the signal reaches several , which is consistent with present theories of the plasma and neutral particle distributions around Venus.     

Natural and Anthropic Middle-term Variations in the Delta System at the Mouth of the Goro River (Po Delta, Italy)

Abstract. The modern delta system of the Po River is the result of an evolution strictly controlled by anthropic factors and mainly developed during a period of climatic deterioration (Little Ice Age 1550/1850).
At the beginning of the 17^th century the main branch of the Po River, Fornaci Po, was modified with the "Cut of Viro" in order to avoid landfill of the Venetian Lagoon. Simultaneously, the southernmost branch of Ariano, or Goro, was forced to flow southwards. Subsequent sedimentary variations, caused by changes in the climatic conditions, contributed to make the area supplied by the Goro Po River increasingly lagoonary. In the second half of the 19^th century (end of the Little Ice Age – L.I.A. –), the first coastal spits started to take shape and developed in different systems throughout the entire following century. Coastal spits turned out to produce in the original bay, a progressive closure towards the sea. The strong decrease in solid loads, characterising the second half of the 20^th century and mainly due to anthropic factors, marks the beginning of a new phase extending to the overall Po Delta system, in which the mouth layout is controlled by wave energy.