Carbon-Oxidizing and Sulfate-Reducing Bacteria in Mozhaisk Reservoir Soils

The population and distribution of carbon-oxidizing and sulfate-reducing bacteria in the soils of the Mozhaisk Reservoir are studied.     

Bathymetric and geochemical investigation of Kawah Ijen Crater Lake, East Java, Indonesia

A bathymetric survey of Kawah Ijen crater lake was conducted by acoustic sounding in 1996 to compare the lake morphology with those measured in 1922, 1925 and 1938, and to calculate the present lake volume. Even though the lake experienced several hydrothermal eruptions, the maximum depth became shallower (182 m) than before (200 m), resulting in a reduced lake volume (3.0×10⁷ m³).Fifty-two major and minor constituents including rare earth elements and polythionates (PT) of the lake waters at various depths were determined by ICP-AES, ICP-MS and HPLC, respectively. These ions except for several volatile elements are taken up by lake fringe through congruent dissolution of pyroclastics of Kawah Ijen volcano. Most ions are homogeneously distributed throughout the lake, although PT showed a considerable vertical variation. Rare earth elements (REE) in the Kawah Ijen water as well as those from other hyper-acidic crater lakes show distribution patterns likely due to the three rock dissolution (preferential, congruent and residual) types, and their logarithmic concentrations linearly depend upon the pH values of the lake waters.Using the PT degradation kinetics data, production rates of PT, injection rates of SO₂ and H₂S into the lake were estimated to be 114, 86 and 30 tons/day, respectively. Also travel time of the spring water at the Banyupahit Riverhead from Kawah Ijen was estimated to be 600–1000 days through the consideration of decreasing rates of PT. Molten sulfur stocks containing Sn, Cu, Bi sulfides and Pb-barite exposed on the inner crater slope were presumed to be extinct molten sulfur pools at the former lake bottom. This was strongly supported by the barite precipitation temperature estimated through the consideration of the temperature dependence of Pb-chlorocomplex formation.     

Magmatic effects of the lunar late heavy bombardment

Large volumes of mare basalts are present on the surface of the moon, located preferentially in large impact basins. Mechanisms relating impact basins and mare basalt eruptions have previously been suggested: lunar impacts removed low-density material that may have inhibited eruption, and created cracks for fluid flow [Icarus 139 (1999) 246], and lunar basins have long been described as catchments for magma (e.g., [Rev. Geophys. Space Phys. 18 (1980) 107] and references therein). We present a new model for melt creation under near side lunar basins that is triggered by the impacts themselves. Magma can be produced in two stages. First, crater excavation depressurizes underlying material such that it may melt in-situ. Second, the cratered lithosphere rises isostatically, warping isotherms at the lithosphere-asthenosphere boundary which may initiate convection, in which adiabatic melting can occur. The first stage produces by far the largest volume of melt, but convective melting can continue for up to 350 Ma. We propose that giant impacts account for a large portion of the volume and longevity of mare basalt volcanism, as well as for several compositional groups, including high alumina, high titanium, KREEP-rich, and picritic magmas.     

Iron oxidation state in lower mantle mineral assemblages: II. Inclusions in diamonds from Kankan, Guinea

Inclusions of ferropericlase and former (Mg,Fe)(Si,Al)O₃ perovskite in diamonds from Kankan, Guinea believed to originate in the lower mantle were studied using Mössbauer spectroscopy to determine Fe³⁺/ΣFe. Fe³⁺ concentration in the (Mg,Fe)(Si,Al)O₃ inclusion is consistent with empirical relations relating Fe³⁺/ΣFe to Al concentration, supporting the inference that it crystallised in the perovskite structure at lower mantle conditions. In ferropericlase there is a nearly linear variation of trivalent cation abundance with monovalent cation abundance, suggesting a substitution of the form Na_0.5M_0.5³⁺O (M=Fe³⁺, Cr³⁺, Al³⁺). Excess positive charge is likely balanced by cation vacancies, where their abundance is observed to increase with increasing iron concentration, consistent with high-pressure experiments. The abundance of cation vacancies is related to oxygen fugacity, where ferropericlase inclusions from Kankan and São Luiz (Brazil) are inferred to have formed at conditions more oxidising than Fe-(Mg,Fe)O equilibrium, but more reducing than Re-ReO₂ equilibrium. Fe²⁺/Mg partition coefficients between (Mg,Fe)(Si,Al)O₃ and ferropericlase were calculated for inclusions co-existing in the same diamond using Mössbauer data and empirical relations based on high-pressure experimental work. Most values are consistent with high-pressure experiments, suggesting that these inclusions equilibrated at lower mantle conditions. The measured ferropericlase Fe³⁺ concentrations are consistent with diamond formation in a region of redox gradients, possibly arising from the subduction of oxidised material into reduced lower mantle. Reduction of carbonate to form ferropericlase and diamond is consistent with a slight shift of Kankan δ¹³C values to isotopically heavy compositions compared to the worldwide dataset, and could supply the oxygen necessary to satisfy the high Fe³⁺ concentration in (Mg,Fe)(Si,Al)O₃ perovskite, as well as account for the high proportion of ferropericlase in the lower mantle paragenesis. The heterogeneity of lower mantle diamond sources indicates that the composition of lower mantle diamonds do not necessarily reflect those of the bulk mantle.     

Seismic response of a cable‐stayed bridge deck under multi‐component non‐stationary random ground motion

A Markov method of analysis is presented for obtaining the seismic response of cable‐stayed bridges to non‐stationary random ground motion. A uniformly modulated non‐stationary model of the random ground motion is assumed which is specified by the evolutionary r.m.s. ground acceleration. Both vertical and horizontal components of the motion are considered to act simultaneously at the bridge supports. The analysis duly takes into account the angle of incidence of the earthquake, the spatial correlation of ground motion and the quasi‐static excitation. A cable‐stayed bridge is analysed under a set of parametric variations in order to study the non‐stationary response of the bridge. The results of the numerical study indicate that (i) frequency domain spectral analysis with peak r.m.s. acceleration as input could provide more r.m.s. response than the peak r.m.s. response obtained by the non‐stationary analysis; (ii) the longitudinal component of the ground motion significantly influences the vertical vibration of the bridge; and (iii) the angle of incidence of the earthquake has considerable influence on the deck response. Copyright © 2003 John Wiley & Sons, Ltd.     

土壤的冷生构造及其对阿拉斯加土地利用的意义

Cryogenic structure (patterns made by ice inclusions) in seasonally frozen and permafrost-af-fected soils result from ice formation during freezing. Analysis of cryogenic structures in soils is essential to our understanding of the cryogenic processes in soils and to formulating land use management interpretations. When soils freeze, the freezing front moves downward and attracts water moving upward resulting in mainly horizontal lenticular ice formation. Platy and lenticular soil structures form between ice lenses in upper active layer. The reticular soil structure usually forms above the permafrost table caused by freeze-back of the permafrost. The upward freeze-back resulted in platy soil structure and the volume changes following the annual freeze-thaw cycle resulted in vertical cracks. The combined result is an ice-net formation with mineral soils embedded in the ice net. The upper permafrost layer that used to be a part of the active layer has an ice content exceeding 50% due to repeated freeze-thaw cycles over time. The mineral soils appear in blocks embedded in an ice matrix. The permafrost layer that never experienced the freeze-thaw cycle often consists of alternate layers of thin ice lens and frozen soils with extreme hard consistence and has relatively lower ice content than the ice-rich layer of the upper permafrost. Ice contents and thaw settling potentials associated with each cryogenic structure should be considered in engineering and land use interpretations.     

Case study of soil moisture effect on land surface temperature retrieval

Land surface temperature (LST) is an important element of the climate system. Remote sensing methods for estimating LST have been developed in the past and several of them have been implemented at large-scales. Geostationary satellites are of particular interest because they depict the diurnal cycle. Soil moisture has a strong effect on the magnitude of surface temperature via its influence on emissivity; yet, information on soil moisture at large scales is meager. It is of interest to estimate what effect soil moisture has on the retrieval accuracy of surface temperature by methods of remote sensing. In this study, newly developed algorithms to estimate land surface temperature (LST) from geostationary satellites will be applied to GOES-8 observations during the Southern Great Plains 1997 Hydrology Experiment (SGP-97) when surface observations of both soil moisture and surface temperature were made. The ground observations were used to first demonstrate the influence of soil moisture on the diurnal cycle of the surface temperature, its amplitude and the lag in LST maxima. Subsequently, it was established that errors in LST as derived from GOES-8 measurements have a negative correlation with soil moisture, namely, increasing with the decrease of soil moisture.     

Urban change detection related to earthquakes using an adaptive nonlinear mapping of high-resolution images

We propose a nonlinear mapping method for detecting geographical changes. In our system, two images photographed at different points of time are checked based on an iterative nonlinear mapping. The system automatically extracts feature changes of aerial imageries by computing distribution of the image matching score. We evaluate the change detection ability by using the receiver operating characteristic under misregistration cases, including rotational misalignments.