Mineralogical and geochemical constraints on the origin of ferromanganese crusts from the Rivera Plate (western margin of Mexico)

Marine hydrogenetically precipitated ferromanganese crusts are widespread in the Pacific Ocean. They occur as pavements coating volcanic or sedimentary hard-rock substrates, mainly on the slopes of seamounts, plateaus and hills in ocean basins and continental margins. We studied three ferromanganese crusts from one dredge haul from the Rivera Plate (western margin of Mexico), which are up to 15 mm thick and grow directly on a substrate of pillow basalt fragments. They consist of laminated, botryoidal, porous aggregates mostly of Fe and Mn oxyhydroxides and up to 10% silicates. XRD analysis showed the predominance of poorly crystallized mineral phases in the crusts that include Mn-feroxyhyte and vernadite, and an authigenic smectite-like clay. Detrital minerals probably derive from granodiorites of the eastern wall of the neighboring Middle America Trench. Scattered barite grains occur on the crust surface and suggest plume fall-out derived from hydrothermal vents, although a possible pelagic source cannot be dismissed. Ratios between major (Fe, Mn, Si) and trace (Co, Ni, Cu) elements reveal that such crusts are predominantly hydrogenetic in origin, although they show a hydrothermal influence that increases in the outer layers. Iron contents range from 16.2 to 25.2 wt.%, and manganese from 3.4 to 14.5 wt.%. The Fe/Mn ratio ranges from 1.6 to 7.0. The SiO₂/Al₂O₃ ratio ranges from 4.3 to 6.6, indicating the presence of biogenic silica (radiolarians). The concentrations of copper (up to 383 ppm) and cobalt (up to 534 ppm) are significantly below those of the typical hydrogenetic crusts, whereas Ni (up to 1320 ppm) is about the same or slightly lower. REE normalized profiles and ΣREE values (486 to 732 ppm) match those reported for hydrogenetic crusts, but suggest a hydrothermal contribution for the later crust layers. The inferred crust growth rates using the Co-chronometer (44 and 229 mm/Myr) are higher than those reported for pure hydrogenetic crusts (mostly 1 to 6 mm/Myr), thus indicating an increasing hydrothermal influence. The highest growth rate (229 mm/Myr, corresponding to the outer crust layers) suggests a regional hydrothermal input of iron and manganese to seawater. The intensification of regional submarine hydrothermal activity began about 13,000 yr ago, and may be related to the tectonic activity in the complex junction of the Rivera, Cocos, Pacific and North America plates.     

Toothed whales in the northwestern Mediterranean: insight into their feeding ecology using chemical tracers

Risso’s dolphins, pilot whales and sperm whales rarely strand in the northwestern Mediterranean. Thus, their feeding ecology, through the analysis of stomach contents, is poorly known. The aim of this study was to gain further insight into the segregation/superposition of the diet and habitat of Risso’s dolphins, pilot whales and sperm whales using chemical tracers, namely, stable isotopes (δ¹³C, δ¹⁵N) and organochlorines. Significantly different δ¹⁵N values were obtained in Risso’s dolphins (11.7 ± 0.7‰), sperm whales (10.8 ± 0.3‰) and pilot whales (9.8 ± 0.3‰), revealing different trophic levels. These differences are presumably due to various proportions of Histioteuthidae cephalopods in each toothed whale’s diet. Similar δ¹³C contents between species indicated long-term habitat superposition or corroborated important seasonal migrations. Lower congener 180 concentrations (8.20 vs. 21.73 μg.g⁻¹ lw) and higher tDDT/tPCB ratios (0.93 vs. 0.42) were observed in sperm whales compared with Risso’s dolphins and may indicate wider migrations for the former. Therefore, competition between these species seems to depend on different trophic levels and migration patterns.     

RESPONSE OF THE CANADIAN PERMAFROST ENVIRONMENT TO CLIMATIC CHANGE

Human-induced climatic warming will have major impacts on permafrost, which presently underlies half of Canada's land mass. The adaptation of the northern environment and its physical processes to the altered climate may be contemporaneous or may lag behind climatic change. The extent of permafrost will diminish, accompanied by modifications of the land surface through thermokarst or mass wasting. Streamflow regimes, sediment transport, coastal flooding and erosion will be affected. The magnitude of most components of the water balance will be altered. More research is needed to understand how the permafrost environment behaves during the transient phase, and the problem of permafrost adaptation should be addressed holistically. [Key words: climatic change, frozen ground, ground ice, hydrology, permafrost, periglacial geomorphology, water balance.]     

Fluid inclusion evidence for deep burial of the Tertiary accretionary wedge of the Carpathians

Hydrothermal quartz from mineralized joints of the Carpathian accretionary wedge contains immiscible aqueous, oil‐condensate, methane and carbon dioxide‐rich fluid inclusions. Distribution patterns of the inclusion trapping PT parameters point to a crack‐seal mechanism during upward and lateral migration of hot methane‐rich fluids from overpressured sediments at the base of the accretionary wedge. A simple equation is proposed to calculate depths from densities and trapping pressures of the buoyant inclusion fluids. In the Carpathian accretionary wedge, the paleofluid pressures of 52–306 MPa correspond to a 5‐ to 11‐km‐thick overburden. Prior to exhumation, thickness of the wedge must have attained 10–25 km, of which only c. 50% was preserved until recently. Anomalously high methane densities (up to 0.43 g cm^?3) recorded in the lowermost nappe sheets are provisionally interpreted as a result of supralithostatic overpressure due to thermal cracking of oil and kerogen to methane and pyrobitumen at temperatures above 200 °C.     

Source spectral phases of surface waves recovered from observed spectral amplitudes by using Hilbert transforms

Spectral phases of surface waves radiated at the seismic source are recovered by means of the Hilbert transform of spectral amplitudes. Through numerical simulations as well as the study of an earthquake with well known focal mechanism, it is shown that the recovered phases satisfy a criterion of coherency, so that they can be used in an inversion process for the retrieval of the seismic moment tensor.     

Generation of earth stratified models compatible with both ellipticity and phase velocity observations of Rayleigh waves

In the eigenvalue eigenvector decomposition used in inversion techniques, we can sometimes obtain eigenvalues close to zero. Related to these eigenvalues close to zero, a set of stratified earth models is generated. These are compatible with the theoretical observations according to a given model. The method is applied to ellipticities and phase velocities of Rayleigh waves, and supply proof of the advantage of working with both sets of data together.     

Mineral assemblages of the Francisco I. Madero Zn–Cu–Pb–(Ag) deposit, Zacatecas, Mexico: Implications for ore deposit genesis

The Francisco I. Madero deposit, central Mexico, occurs in the Mesozoic Guerrero Terrane, which hosts many ore deposits, both Cretaceous (volcanogenic massive sulfides) and Tertiary (epithermal and skarn deposits). It is hosted by a 600 m-thick calcareous-pelitic unit, of Lower Cretaceous age, crosscut by porphyritic dikes that strike NW–SE. A thick felsic volcanic Tertiary sequence, consisting of andesites and rhyolitic ignimbrites, unconformably overlies the Cretaceous series. At the base, the mineralization consists of several mantos developed within calcareous beds. They are dominantly composed of sphalerite, pyrrhotite and pyrite with minor chalcopyrite, arsenopyrite and galena. At the top of the orebody, there are calcic skarns formed through prograde and retrograde stages. The resulting mineral assemblages are rich in manganoan hedenbergite (Hd_75–28Di_40–4Jh_40–20), andraditic garnets (Adr_100–62Grs_38–0), epidote (Ep_95–36Czo_60–5Pie_8–0), chamosite, calcite and quartz. The temperature of ore deposition, estimated by chlorite and arsenopyrite geothermometry, ranges from 243° to 277 °C and from 300° to 340 °C, respectively. The pressure estimated from sphalerite geobarometry averages 2.1 kbar. This value corresponds to a moderately deep skarn and agrees with the high Cu content of the deposit. Paragenesis, P–T conditions and geological characteristics are compatible with a distal, dike-related, Zn skarn deposit. Its style of mineralization is similar to that of many high-temperature carbonate replacement skarn deposits in the Southern Cordillera.