1980–1990: Ten years of geochemical investigation at Phlegrean Fields (Italy)

A systematic geochemical investigation on the thermal manifestations of the volcanic area of Phlegrean Fields started in 1980, with the aim of obtaining useful information about the changes possibly occurring at the same time of vertical ground movements, termed as “bradyseismic”, which frequently interested this area.The attention was initially given to the fumaroles and the boiling pools of Solfatara and Pisciarelli, then subsequently extended to thermal springs, dug wells, and crater lakes.Analytical data pertaining to a period preceding the last crisis of 1982–1984 were then available, as well as other data collected during the previous crisis of 1970; a comprehensive picture of the variations observed before, during and after the acceleration of vertical movement has been drawn.According to the results obtained, the intrusion of a magmatic body as the trigger of the observed ground deformation is considered unrealistic. The whole area appears now in a quiet stage, and no further perturbation is expected without previous significant tectonic activity; chemical precursors appear suitable for an early detection of changes occurring at depth, to forecast possible consequences to be expected in the surface environment.     

A low magnitude seismic sequence near Isernia (Molise,Central Italy) in January 1986

Following the increase in seismic activity which occurred near Isernia (Molise, Central Italy) in January 1986, a digital seismic network of four stations with three-component, short-period seismometers, was installed in the area by the Osservatorio Vesuviano. The temporary network had an average station spacing of about 8–10 km and, in combination with permanent local seismic stations, allowed the accurate determination of earthquake locations during an operating period of about one month. Among the 1517 detected earthquakes, 170 events were selected with standard errors on epicentre and depth not greater than respectively 0.5 and 1.5 km. The most frequent focal depths ranged between 4 and 8 km, while the epicentres distribution covered a small area NE of Isernia of about 10 km². A main rupture zone could not be clearly identified from the spatial distribution of the earthquakes, suggesting a rupture mechanism involving heterogeneous materials. The activity was characterized by low energy levels, the largest earthquake, on January 18, 1986, havingM _D =4.0. The time sequence of events and pattern of seismic energy release revealed a strong temporal clustering of events, similar to the behaviour commonly associated with seismic swarms.     

Innovative monitoring tools for the complex spatial dynamics of river chemistry: case study for the Alpine region

Chemical reactions in aqueous geochemical systems are driven by nonequilibrium conditions, and their dynamics can be deduced through the distributional analysis (identification of probability laws) of complex compositional indices. In this perspective, compositional data analysis offers the possibility to investigate the behavior of the composition as a whole instead of isolated chemical species, with the awareness that multispecies systems are characterized by the simultaneous interactions among all their parts. We addressed this problem using D???1 isometric log-ratio coordinates describing the D compositional dataset of the river chemistry of the Alpine region (D number of variables), thus working in the \({{\mathbb{R}}^{D - 1}}\) statistical sample space. The D???1 coordinates were chosen using the decreasing variance criterion so that each one could provide information about different space–time properties for the investigated geochemical system. Coordinates dominated by heterogeneity appear to be able to capture regime shifts only on a long-time period and monitor processes on a very wide scale. On the other hand, coordinates characterized by lower variability present multimodality, thus capturing the presence of alternative states in the analyzed spatial domain also for the current time. Further developments are needed to determine the ranges of conditions for which variability and other statistics can be useful indicators of regime shifts on different time–space scales in geochemical systems.     

Oligotrophication from wetland epuration alters the riverine trophic network and carrying capacity for fish

Submerged aquatic vegetation (SAV) constitutes a major component of fish habitat, providing support for epiphytes and invertebrates as well as shelter from predators. The effects of wetland epuration from a mesotrophic to a nearly oligotrophic state were examined over a 15?km long reach of the St. Lawrence River under the direct influence of major farmland tributaries. We hypothesized that the nutrient-enriched zone would support a higher biomass of SAV, epiphytes, macroinvertebrates and fish than the nitrogen-deficient epurated zone located downstream of the wetland. Predictions included that the enriched habitat would support a richer fish assemblage, with higher biomass and growth of juvenile yellow perch than found in the epurated zone. Results supported these hypotheses, demonstrating the chain of effects of nutrient reduction on the biomass of SAV (fourfold drop), invertebrate prey (ninefold), small (threefold) and large (1.5-fold) fish between the two zones. In addition to the reduction in SAV biomass, the replacement of filamentous chlorophytes by benthic mats of filamentous cyanobacteria in the epurated zone resulted in a less complex 3-D habitat structure and a low invertebrate availability for fish. Oligotrophication by wetland epuration exerted negative effects on fish habitat quality, food quantity and availability, with an impairment of juvenile perch growth and recruitment. A generalized model of the changes in habitat carrying capacity occurring with epuration (oligotrophication) or eutrophication is presented, with examples of other aquatic systems in which strong linkages between trophic status, SAV, invertebrates and fish productivity were also demonstrated.     

Geochemical heterogeneities and dynamics of magmas within the plumbing system of a persistently active volcano: evidence from Stromboli

We report here the most complete dataset for major and trace elements, as well as Sr isotopic compositions, of magmas erupted by Stromboli since the onset of present-day activity 1,800 years ago. Our data relate to both porphyritic scoria and lava originating in the uppermost parts of the feeding system, plus crystal-poor pumice produced by paroxysmal explosive eruption of deep-seated, fast ascending, magma. The geochemical variations recorded by Stromboli’s products allow us to identify changes in magma dynamics affecting the entire plumbing system. Deep-seated magmas vary in composition between two end-members having different key ratios in strongly incompatible trace elements and Sr isotopes. These features may be ascribed to mantle source processes (fluid/melt enrichment, variable degrees of melting) and occasional contamination by deep, mafic, cumulates. Temporal trends reveal three phases during which magmas with distinct geochemical signatures were erupted. The first phase occurred between the third and fourteenth centuries AD and was characterised by the eruption of evolved magmas sharing geochemical and Sr isotopic compositions similar to those of earlier periods of activity (<12 ka—Neostromboli and San Bartolo). The second phase, which began in the sixteenth century and lasted until the first half of the twentieth century, produced more primitive, less radiogenic, magmas with the lowest Ba/La and Rb/Th ratios of our dataset. The last phase is ongoing and is marked by a magma having the lowest Sr isotopic composition and highest Rb/Th ratio of the dataset. While this new magma can be clearly identified in the pumice erupted during the last two paroxysmal eruptions of 2003 and 2007, shallow degassed magma extruded during this time span records significant geochemical and isotopic heterogeneities. We thus suggest that the shallow reservoir has been only partially homogenised by this new magma influx. We conclude that compositional variations within the shallow magma system of a persistently active volcano provide only a biassed signal of ongoing geochemical changes induced by deep magma refilling. We argue that source changes can only be identified by interpreting the geochemistry of pumice, because it reliably represents magma transferred directly from deep portions of the plumbing system to the surface.     

Magma convection and mixing dynamics as a source of Ultra-Long-Period oscillations

Many volcanic eruptions are shortly preceded by injection of new magma into a pre-existing, shallow (<10 km) magma chamber, causing convection and mixing between the incoming and resident magmas. These processes may trigger dyke propagation and further magma rise, inducing long-term (days to months) volcano deformation, seismic swarms, gravity anomalies, and changes in the composition of volcanic plumes and fumaroles, eventually culminating in an eruption. Although new magma injection into shallow magma chambers can lead to hazardous event, such injection is still not systematically detected and recognized. Here, we present the results of numerical simulations of magma convection and mixing in geometrically complex magmatic systems, and describe the multiparametric dynamics associated with buoyant magma injection. Our results reveal unexpected pressure trends and pressure oscillations in the Ultra-Long-Period (ULP) range of minutes, related to the generation of discrete plumes of rising magma. Very long pressure oscillation wavelengths translate into comparably ULP ground displacements with amplitudes of order 10⁻⁴–10⁻² m. Thus, new magma injection into magma chambers beneath volcanoes can be revealed by ULP ground displacement measured at the surface.     

Autochthonous and allochthonous plant contributions to coastal benthic detritus deposits: a dual-stable isotope study in a volcanic lake

The high numbers of primary producers represent multiple sources of organic matter accumulating onto lake bottoms. The difficulty of distinguishing the relative contribution to the mixture presents considerable challenges to the analysis of these organic deposits. In this study, dual-stable isotope analysis and IsoSource model were used to identify allochthonous and autochthonous components of detritus deposits (Particulate Organic Matter: POM) at two different bottom slope sites of a volcanic lake (lake Bracciano). Experiments were carried out to calibrate IsoSource on constructed plant mixtures and assess changes in isotope ratios during plant decomposition. IsoSource satisfactorily discriminated the constructed mixture sources with a few exceptions. Changes in isotopic enrichment during decomposition were low, and thus did not represent a confounding variable in the isotopic analysis. By contrast, chemical and geological differences of the study sites were associated with differences in plant δ¹³C and δ¹⁵N values (more than 2‰ within single plant species). At both sites, the isotopic signals of POM fell between polygons delineated by source end members with an evident shift of δ¹³C toward allochthonous sources. POM amount and diversity were greater at the flatter bottom site, where allochthonous contributions were larger than at the other site. In particular, IsoSource ranked species contributions as follows: A. glutinosa > P. australis > A. donax > S. alba > P. nigra > the benthic macroalga Chara sp. at the first site, and A. glutinosa > P. nigra > the aquatic macrophyte C. demersum at the latter. The composition of littoral POM was determined by allochthonous sources in proportion to their relative abundances (as percent land cover) with differences between sites due to bottom slope.     

Monitoring toxic microalgae Ostreopsis (dinoflagellate) species in coastal waters of the Mediterranean Sea using molecular PCR-based assay combined with light microscopy

A molecular PCR-based assay was developed and applied to macrophyte and seawater samples containing mixed microphytobenthic and phytoplanktonic assemblages, respectively, in order to detect toxic Ostreopsis species in Mediterranean Sea. The specificity and sensitivity of the molecular PCR assay were assessed with both plasmidic and genomic DNA of the target genus or species using taxon-specific primers in the presence of background macrophyte DNA. The PCR molecular technique allowed rapid detection of the Ostreopsis cells, even at abundances undetectable within the resolution limit of the microscopy technique. Species-specific identification of Ostreopsis was determined only by PCR-based assay, due to the inherent difficulty of morphological identification in field samples. In the monitoring of the toxic Ostreopsis blooms PCR-based methods proved to be effective tools complementary to microscopy for rapid and specific detection of Ostreopsis and other toxic dinoflagellates in marine coastal environments.     

Shaking table tests on a masonry building monitored using smart bricks: Damage detection and localization

The seismic behavior of unreinforced masonry buildings is typically characterized by premature brittle collapse mechanisms that can cause serious consequences for the protection of human lives and for the preservation of historical and cultural heritage. Structural health monitoring can be a powerful tool enabling a quick post-earthquake assessment of the structure's performance, but its applications are still scarce as a consequence of the severe limitations affecting off-the-shelf sensing technologies, in terms of local nature of the measurements, costs, as well as long-term behavior, installation, and maintenance. To overcome some of these limitations, the authors have recently proposed a new sensing technology, called “smart brick,” that is a durable clay brick doped with stainless steel microfibers, working as a smart strain sensor for masonry buildings. This paper presents the first full-scale application of smart bricks, used for detecting and localizing progressive earthquake-induced damage in an unreinforced masonry building subjected to shaking table tests. Smart bricks are employed to detect changes in load paths on masonry walls, comparing strain measurements acquired after each step of the seismic sequence with those referring to the undamaged structure. Experimental results are interpreted using a 3D finite element model built to reproduce the shaking table tests. Overall, the results demonstrate that the smart bricks can effectively reveal local permanent changes in structural conditions following a progressive damage, therefore being apt for earthquake-induced damage detection and localization.