Palaeoproterozoic evaporites in Fennoscandia: implications for seawater sulphate, the rise of atmospheric oxygen and local amplification of the δ13C excursion

This paper addresses global oxygenation and establishment of a marine sulphate reservoir in the Palaeoproterozoic. We report syn-depositional, marine, anhydrite-containing pseudomorphs after Ca-sulphates as widespread throughout the Tulomozero Formation in the SE Fennoscandian Shield, implying that surface waters were oxidized and a large SO marine reservoir was developed as early as 2100 Ma. The Ca-sulphates and associated magnesite and halite precipitated syn-depositionally from oxidized, evolved and modified seawater in coastal playa, sabkha and intertidal flat settings. ⁸⁷Sr/⁸⁶Sr and δ¹³C of associated ¹³C-rich stromatolitic dolostones were environmentally controlled with the highest ratios occurring in playa and sabkha carbonates. The results imply that the Palaeoproterozoic δ¹³C_carb excursion was amplified by 8‰ by local environmental factors and calls into question many observations of putative δ¹³C global signals reported previously from similar Palaeoproterozoic, evaporitic, dolostones. The local environmental amplification can explain a large regional and intercontinental δ¹³C discrepancy observed in synchronous carbonates.     

Physics of solar prominences

Summary Conclusion This colloquium on solar prominences - the first ever held - has shown that a major part of activity in prominence research in recent years concentrated on both observation and computation of the magnetic conditions which were found to play a crucial role for the development and the maintainance of prominences. Remarkable progress was made in fine-scale measurements of photospheric magnetic fields around filaments and in internal field measurements in prominences. In addition, important information on the structure of the magnetic fields in the chromosphere adjacent to the filaments may be derived from high resolution photographs of the H fine structure around filaments which have become available recently; unfortunately, an unambiguous determination of the vector field in the chromosphere is not yet possible.It is quite clear, now, that stable filaments extend along neutral lines which divide regions of opposite longitudinal magnetic fields. Different types of neutral lines are possible, depending on the history and relationship of the opposite field regions. There is convincing evidence that the magnetic field in the neighbouring chromosphere may run nearly parallel to the filament axis and that there are two field components in stable prominences: an axial field dominant in the lower parts and a transverse field dominant in the higher parts.Methods for the computation of possible prominence field configurations from measured longitudinal photospheric fields were developed in recent years. In a number of cases (e.g. for loop prominences) the observed configuration could be perfectly represented by a force-free or even a potential field; poor agreement was found between computed and measured field strengths in quiescent prominences. In order to reconcile both of them it is necessary to assume electric currents. Unambiguous solutions will not be found until measurements of the vector field in the photosphere and in the prominences are available.The two-dimensional Kippenhahn-Schlüter model is still considered a useful tool for the study of prominence support and stability. However, a more refined model taking into account both field components and considering also thermal stability conditions is available now. It was proposed that quiescent prominences may form in magnetically neutral sheets in the corona where fields of opposite directions meet.As for the problem of the origin of the dense prominence material there are still two opposite processes under discussion. The injection of material from below, which was mainly applied to loop prominences, has recently been considered also a possible mechanism for the formation of quiescent prominences. On the other hand, the main objections against the condensation mechanism could be removed: it was shown that (1) sufficient material is available in the surrounding corona, and that (2) coronal matter can be condensed to prominence densities and cooled to prominence temperatures in a sufficiently short time.The energy balance in prominences is largely dependent on their fine structure. It seems that a much better radiative loss function for optically thin matter is now available. The problem of the heat conduction can only be treated properly if the field configuration is known. Very little is known on the heating of the corona and the prominence in a complicated field configuration. For the optically thick prominences the energy balance becomes a complicated radiative transfer problem.Still little is known on the first days of prominence development and on the mechanism of first formation which, both, are crucial for the unterstanding of the prominence phenomenon. As a first important step, it was shown in high resolution H photographs that the chromospheric fine structure becomes aligned along the direction of the neutral line already before first filament appearance. More H studies and magnetic field measurements are badly needed.Recent studies have shown that even in stable prominences strong small-scale internal rotational or helical motions exist; they are not yet understood. On the other hand, no generally agreed interpretation of large-scale motions of prominences seems to exist. A first attempt to explain the ascendance of prominences, the Disparitions Brusques, as the result of a kink instability was made recently.New opportunities in prominence research are offered by the study of invisible radiations: X-rays and meterwaves provide important information, not available otherwise, on physical conditions in the coronal surroundings of prominences; EUV observations will provide data on the thin transition layer between the cool prominence and the hot coronal plasma.Mitt. aus dem Fraunhofer Institut No. 111.     

Kokchetavite: a new potassium-feldspar polymorph from the Kokchetav ultrahigh-pressure terrane

Kokchetavite, a new polymorph of K-feldspar (KAlSi₃O₈), has been identified as micrometer-size inclusions in clinopyroxene and garnet in a garnet-pyroxene rock from the Kokchetav ultrahigh-pressure terrane, Kazakhstan. Kokchetavite has a hexagonal structure with a =5.27(1) Å, c=7.82(1) Å, V=188.09 ų, Z=1, and is found to be associated with phengite + /-cristobalite (or quartz) + siliceous glass ± phlogopite/titanite/calcite/zircon, occurring as multi-phase inclusions in clinopyroxene and garnet. It is concluded that kokchetavite could not be an exsolution phase in host minerals. Instead, it might be metastably precipitated from an infiltrated K-rich melt during rock exhumation. Alternatively, although less likely, kokchetavite might be derived from dehydration of K-cymrite, which, in turn, was formed at high pressures. In either case, kokchetavite is a metastable polymorph of K-feldspar.     

Capture effects in carbonaceous material: A Stardust analogue study

Abstract— It is reasonable to expect that cometary samples returned to Earth by the Stardust space probe have been altered to some degree during capture in aerogel at 6.1 km/s. In order to help interpret the measured structure of these particles with respect to their original cometary nature, a series of coal samples of known structure and chemical composition was fired into aerogel at Stardust capture velocity. This portion of the study analyzed the surfaces of aerogel‐embedded particles using Raman spectroscopy. Results show that particle surfaces are largely homogenized during capture regardless of metamorphic grade or chemical composition, apparently to include a devolatilization step during capture processing. This provides a possible mechanism for alteration of some aliphatic compound‐rich phases through devolatilization of cometary carbonaceous material followed by re‐condensation within the particle. Results also show that the possibility of alteration must be considered for any particular Stardust grain, as examples of both graphitization and amorphization are found in the coal samples. It is evident that Raman G band (～1580 cm^?1) parameters provide a means of characterizing Stardust carbonaceous material to include identifying those grains which have been subjected to significant capture alteration.     

Decoupling between the middle and upper crust during transpression-related lateral flow: Variscan evolution of the Aston gneiss dome (Pyrenees, France)

We present a structural, AMS, microstructural and kinematic study of the Aston gneiss dome (French Pyrenees), which consists of a core made up of orthogneiss and paragneiss intruded by numerous sills of Carboniferous peraluminous granite. The orthogneiss corresponds to a former Ordovician granitic laccolith. Four Variscan events have been evidenced in this gneiss dome: (i) D1 deformation observed only as relics in the orthogneisses and their country-rocks located above the sillimanite isograd, and characterized by a NS to NE–SW non coaxial stretch associated to top to the south motions (NS convergence); (ii) D2-a deformation observed in the orthogneisses and their country-rocks, mainly migmatitic paragneisses, located below the sillimanite isograd and in the peraluminous granites whatever their structural level, and characterized by an EW to N120°E stretch associated to a top to the east flat shearing (lateral flow in the hot middle crust in a transpressive regime); (iii) D2-b deformation characterized by EW-trending megafolds corresponding to the domes in the middle crust and by EW-trending tight folds with subvertical axial planes in the metasedimentary upper crust; (iv) subvertical medium-temperature mylonitic bands developed by the end of the transpression.The Aston massif is a good example of decoupling between a cold upper crust and a hotter middle crust overheated by a thermal event originated in the upper mantle. This decoupling allowed the lateral flow of the migmatitic middle crust along a direction at high angle with respect to the more or less NS-trending direction of convergence. We suggest that the HT-LP metamorphism developed before the formation of the domes during D2-a, coevally with the emplacement of numerous sills of peraluminous granite, whereas the emplacement of the large calc-alkaline plutons in the upper crust occurred by the end of D2-b. Our data invalidate the previous geodynamical models based on either early or late extensional regime to explain the development of the HT-LP metamorphism. This new interpretation of the dynamics of the Variscan crust of the Pyrenees is consistent with recent studies conducted in Archaean and Palaeoproterozoic hot continental crusts having undergone oblique convergence, and characterized by a competition between vertical thickening and lateral flow induced by the important rheological contrast between two thermally different levels.     

Stardust impact analogs: Resolving pre‐ and postimpact mineralogy in Stardust Al foils

Abstract– The grains returned by NASA’s Stardust mission from comet 81P/Wild 2 represent a valuable sample set that is significantly advancing our understanding of small solar system bodies. However, the grains were captured via impact at ～6.1 km s^?1 and have experienced pressures and temperatures that caused alteration. To ensure correct interpretations of comet 81P/Wild 2 mineralogy, and therefore preaccretional or parent body processes, an understanding of the effects of capture is required. Using a two‐stage light‐gas gun, we recreated Stardust encounter conditions and generated a series of impact analogs for a range of minerals of cometary relevance into flight spare Al foils. Through analyses of both preimpact projectiles and postimpact analogs by transmission electron microscopy, we explore the impact processes occurring during capture and distinguish between those materials inherent to the impactor and those that are the product of capture. We review existing and present additional data on olivine, diopside, pyrrhotite, and pentlandite. We find that surviving crystalline material is observed in most single grain impactor residues. However, none is found in that of a relatively monodisperse aggregate. A variety of impact‐generated components are observed in all samples. Al incorporation into melt‐derived phases allows differentiation between melt and shock‐induced phases. In single grain impactor residues, impact‐generated phases largely retain original (nonvolatile) major element ratios. We conclude that both surviving and impact‐generated phases in residues of single grain impactors provide valuable information regarding the mineralogy of the impacting grain whilst further studies are required to fully understand aggregate impacts and the role of subgrain interactions during impact.     

Subarctic catchment water storage and carbon cycling – Leading the way for future studies using integrated datasets at Pallas,Finland

Subarctic ecohydrological processes are changing rapidly, but detailed and integrated ecohydrological investigations are not as widespread as necessary. We introduce an integrated research catchment site (Pallas) for atmosphere, ecosystems, and ecohydrology studies in subarctic conditions in Finland that can be used for a new set of comparative catchment investigations. The Pallas site provides unique observational data and high-intensity field measurement datasets over long periods. The infrastructure for atmosphere- to landscape-scale research in ecosystem processes in a subarctic landscape has recently been complemented with detailed ecohydrological measurements. We identify three dominant processes in subarctic ecohydrology: (a) strong seasonality drives ecohydrological regimes, (b) limited dynamic storage causes rapid stream response to water inputs (snowmelt and intensive storms), and (c) hydrological state of the system regulates catchment-scale dissolved carbon dynamics and greenhouse (GHG) fluxes. Surface water and groundwater interactions play an important role in regulating catchment-scale carbon balances and ecosystem respiration within subarctic peatlands, particularly their spatial variability in the landscape. Based on our observations from Pallas, we highlight key research gaps in subarctic ecohydrology and propose several ways forward. We also demonstrate that the Pallas catchment meets the need for sustaining and pushing the boundaries of critical long-term integrated ecohydrological research in high-latitude environments.     

Spatially distributed modelling of soil erosion and sediment yield at regional scales in Spain

Initiated by the need to quantify erosion rates and the impacts of global changes on erosion, several attempts have been made to apply erosion models at regional scales. However, these models have often been directed towards on-site soil erosion estimates, emphasising sheet and rill erosion processes, and disregarding gully erosion, channel erosion and sediment transport. These models are therefore of limited use for the assessment of sediment yield, off-site impacts of erosion, and for the development of environmental management to control these impacts at regional scale. This study analyses and compares three spatially distributed models for the prediction of soil erosion and/or sediment yield at regional scales: the WATEM-SEDEM model that is based on the empirical Revised Universal Soil Loss Equation (RUSLE) in combination with a sediment transport equation, the physics-based Pan European Soil Erosion Risk Assessment model (PESERA), and a newly developed Spatially Distributed Scoring model (SPADS). The three models were applied to 61 Spanish drainage basins and model predictions were evaluated against data on measured reservoir sedimentation rates. Global data sets on land use, climate, elevation and soil characteristics were used as model input for WATEM-SEDEM and SPADS, whereas published soil erosion estimates of PESERA at 1 km² resolution were used directly. SPADS and WATEM-SEDEM provided best results after separate calibration for basins with a Sediment Delivery Ratio (SDR) higher than 5% and those with an SDR lower than 5%. In this way, SPADS explained 67% of variation in sediment yield, while WATEM-SEDEM explained 48% of the variation. PESERA represents a promising alternative to the use of empirical models at the regional scale as it can be applied to very diverse environments with little calibration. However, PESERA provides soil erosion rates and not sediment yield estimates. For most basins PESERA soil erosion rates vary between fifty and close to zero percent of total sediment yield. Two major factors may explain this discrepancy between modelled soil erosion rates and measured sediment yield. First, it may be that PESERA underestimates soil erosion under Mediterranean conditions, although PESERA soil erosion rates are of the same order of magnitude as erosion rates measured in erosion plot studies. Second, gully-, river channel erosion and sediment transport processes may be much more important than sheet- and rill erosion for regional scale sediment yield in these environments. These issues therefore require further attention in future model development. Although spatially lumped models provide better predictions of sediment yield at the basin scale, and while validation of the predicted spatial patterns of sources and sinks of sediment requires further research, spatially distributed models are expected to be of value to support management decisions regarding the assessment of on-site and off-site impacts of erosion at the regional scale.