Physical and anthropogenic effects on observed long-term nutrient changes in the Irish Sea

The trend in Irish Sea nutrient concentrations over the last four decades has been considered to reflect changes in anthropogenic loading. Comparison of a long-term database for the Menai Strait, North Wales, with an established historic data set for the Cypris station, Isle of Man, indicates that climate also has a significant influence on observations of nutrient concentrations. Data are presented detailing long-term shifts in nitrate, phosphate and silicate measurements since the 1960s at these two fixed sampling sites in the Irish Sea. Broad systematic changes observed in all three nutrients over the decades show a rise from the 1960s through to the 1980s, followed generally by an overall decline in the 1990s. Decadal-scale salinity changes occur in the opposite sense to nutrient changes. Anthropogenic inputs from freshwater cannot fully account for observed nutrient trends, neither is there evidence for shifts in nutrient concentrations in oceanic waters over the past four decades. Climatically forced movement in the geographical position of the freshwater/seawater mixing zone over a decadal time scale could, however, give rise to the observed shifts in nutrient concentration and salinity. This cannot alter nutrient concentration and salinity per se, but causes the measurements taken at fixed sampling sites to fluctuate inversely over this time scale. It is concluded that there is complex interplay between anthropogenic loading and climate affecting the distribution of nutrients in the Irish Sea.     

Comparison of three oxidation methods used for the analysis of the dissolved organic carbon in seawater

Three methods for the determination of dissolved organic carbon in seawater were compared. Samples were analysed using persulphate oxidation, high-temperature combustion, and ultraviolet photo-oxidation. The dissolved organic carbon content of the seawater samples ranged from 0.6 to 1.6 mg C/I. This study shows that results of high-temperature oxidation and photo-oxidation procedures differ by less than 5%, whereas results with persulphate oxidation are about 15% less than those obtained with the high-temperature oxidation. The relative merits of each of the oxidation techniques for the determination of organic matter in seawater are discussed.     

Effect of dispersion on impulsive waves

The generation and propagation of surface waves resulting from suddenly created disturbances over water surfaces is investigated. The initial boundary conditions defining the disturbance are given either by a velocity of the free surface, an initial elevation of the free surface or a pressure impulsively applied on the free surface. It is shown that the corresponding three forms of solutions are related by a simple time derivative. Linear solutions are obtained in the cases where the wave motion is assumed to be nondispersive, mildly dispersive and fully dispersive, as well as in the case where the motion is given by the method of stationary phase. Criteria are established to indicate the limit of validity of each method.     

Laser ablation coupled with ICP-MS applied to U–Pb zircon geochronology: A review of recent advances

Improvements in the technology of laser ablation and ICP-MS instruments make LA-MC-ICPMS a rapid, precise and accurate method for U–Pb zircon geochronology. In this review we describe the main stages of the evolution of this in situ approach from the early 1990s to the present time. Some key points have been progressively improved. The crater size has been reduced to achieve real in situ measurements. The laser wavelength has been reduced as well as the duration of each pulse in order to lower inter-element fractionation. The blank from the gas has to be lowered as far as possible. Double focusing instruments and magnetic field sectors allow flat-topped peaks required for precise isotope ratio measurement to be obtained. The use of a multi-ion counting system significantly improves the sensitivity of the method and the static mode of integration favours the precision of measurement of the transient signal originating from a noisy laser ablated particle beam.Combining the use of a 213 nm UV laser and a MC-ICPMS equipped with a multi-ion counting system operating in static mode, the common precisions achieved for the key ratios ²⁰⁷Pb/²⁰⁶Pb and ²⁰⁶Pb/²³⁸U are better than 1% and 3% (2σ) respectively, including error propagation associated with standard normalization. Until now, the use of a zircon standard has remained necessary to ensure the accuracy of the calculated age. A strategy for common-Pb correction is proposed according to the age of the zircon and according to the Th/U ratio of the grains. After recording sixteen to twenty spot analyses the precision usually achieved on the age is about 1% and even significantly better for Proterozoic samples.In order to show the performance achieved by modern LA-MC-ICPMS geochronology, we tested four zircon samples covering a wide age range from 290 to 2440 Ma. These new age determinations can be compared in term of precision and accuracy since they have already been dated by reference methods (ID-TIMS and SHRIMP). Further developments in the technology of ion counters equipping modern MC-ICPMS and in laser systems will certainly be applied to a large field of geochronology studies in the near future as an alternative to SIMS for in situ age determination.     

Petrogenesis of anomalous K-enriched MORB from the Southwest Indian Ridge: 11°53′E to 14°38′E

Glassy pillow basalts with unusual geochemical characteristics for mid-ocean ridge basalt (MORB) have been dredge sampled from the Southwest Indian Ridge between 12 and 15°E during Leg ANT IV/4 of the F.S. POLARSTERN. Lavas from 4 of 6 dredges are moderately nepheline normative, highly K-enriched (0.5–1.77 wt% K₂O) alkali basalts and hawaiites. Mg-numbers indicate that many of the lavas are fairly primitive (Mg No.=63–67), yet show extreme enrichment in incompatible elements; e.g. Nb (24–60 ppm), Ba (170–470 ppm) and Sr (258–460 ppm). Incompatible-element ratios such as Zr/Nb (3–5) and Y/Nb (0.46–1.1) are extremely low even for E-type (enriched) MORB, whereas (La/Yb)_n ratios are particularly high (3.4–7.8). ⁸⁷Sr/⁸⁶Sr (0.70290–0.70368), ¹⁴³Nd/¹⁴⁴Nd (0.51302–0.51284) and ²⁰⁶Pb/²⁰⁴Pb (18.708–19.564) isotopic ratios further indicate the geochemically enriched nature of these lavas, which range from the compositional field for depleted N-type (normal) MORB towards the composition of Bouvet Island lavas. Mutually correlated incompatible-element and Sr-, Nd- and Pb-isotopic ratios allow a fairly well constrained model to be developed for the petrogenesis of these unusually alkalic mid-ocean ridge lavas. The alkalic nature and degree of enrichment in incompatible elements is ascribed to particularly low degrees of partial melting (3–5 wt%), at greater than usual depth, of a source region that has experienced prior geochemical enrichment (by veining) related to the upwelling Bouvet mantle plume. To account for the observed compositional variations, a model is proposed whereby mixing between partial melts derived from these geochemically enriched silicate veins, and an incipient to low percentage (±2%) melt from the surrounding geochemically depleted suboceanic asthenosphere occurs as a consequence of increasing degree of melting with adiabatic upwelling. Eruption of these alkalic lavas in this spreading ridge environment is attributed to a temporary hiatus in tholeiitic volcanism and associated spreading along this section of the Southwest Indian Ridge, related to readjustment of spreading direction to a more stable plate geometry.     

地震作用下的灰坝液化特征及其动力稳定性分析--以安阳电厂为例

根据安阳电厂灰坝岩土工程性质及其动力学特性,建立了适合灰坝工程的动力分析模型并采用有限元法进行了动力分析.在此基础上,在不同工况条件下对灰坝进行了抗液化安全评价及抗震稳定性分析.研究表明,在不设碎石桩、无排渗体条件下,粉煤灰子坝的抗液化安全系数Ks＜1.25,将发生液化;在设碎石桩、有排渗体条件下,粉煤灰子坝的抗液化安全系数明显提高,Ks≥1.25,不会发生液化.抗震稳定性分析表明,在上述两种工况条件下灰坝是稳定的.     

Magnetic properties of a freshly fallen LL ordinary chondrite: the Bensour meteorite

A comprehensive rock magnetic, magnetic anisotropy and paleomagnetic study has been undertaken in the brecciated LL6 Bensour ordinary chondrite, a few months only after its fall on Earth. Microscopic observations and electronic microprobe analyses indicate the presence of Ni-rich taenite, tetrataenite and rare Co-rich kamacite. Tetrataenite is the main carrier of remanence. Magnetization and anisotropy measurements were performed on mutually oriented 125 mm³ sub-samples. A very strong coherent susceptibility and remanence anisotropy is evidenced and interpreted as due to the large impact responsible for the post-metamorphic compaction of this brecciated material and disruption of the parent body. We show that the acquisition of remanent magnetization postdates metamorphism on the parent body and predates the entering of the meteorite in Earth’s atmosphere. Three components of magnetization could be isolated. A soft coherent component is closely related to the anisotropy of the meteorite and is interpreted as a shock remanent magnetization acquired during the same large impact on the parent body. Two harder components show random directions at a few mm scale. This randomness is attributed either to the formation mechanism of tetrataenite or to post-metamorphic brecciation. All components are likely acquired in very low (≈μT) to null ambient magnetic field, as demonstrated by comparison with demagnetization behavior of isothermal remanent magnetization. Two other LL6 meteorites, Kilabo and St-Mesmin, have also been studied for comparison with Bensour.     

Paleoclimate reconstruction based on the timing of speleothem growth and oxygen and carbon isotope composition in a cave located in the rain shadow in Israel

High-resolution ²³⁰Th/²³⁴U ages and δ¹⁸O and δ¹³C compositions of speleothems in Ma’ale Efrayim Cave located to the east of the central mountain ridge of Israel enable us to examine the nature of the rain shadow aridity during glacial and interglacial intervals. Speleothem growth occurred during marine glacial isotopic periods, with no growth during the two last marine isotope interglacial intervals and during the peak of the Last Glacial Maximum. This contrasts with speleothem growth in caves located on the western flank of the central mountain ridge, in the Eastern Mediterranean semiarid climatic zone, which continued throughout the last 240,000 yr. Thus, during glacial periods water reached both sides of the central mountain ridge. A comparison of the present-day rain and cave water isotopic compositions and amounts at the Ma’ale Efrayim Cave site with those on the western flank shows that evaporation and higher temperatures on the eastern flank are major influences on isotopic composition and the lack of rainfall. The δ¹⁸O and δ¹³C profiles of the speleothems deposited between 67,000 and 25,000 yr B.P. match the general trends of the isotopic profiles of Soreq Cave speleothems, suggesting a similar source (eastern Mediterranean Sea) and similar climatic conditions. Thus, during glacial periods the desert boundary effectively migrated further south or east from its present-day location on the eastern flank, whereas interglacial periods appear to have been similar to the present, with the desert boundary at the same position. The decrease in overall temperature and a consequent reduction in the evaporation to precipitation ratios on the eastern flank are viewed as the major factors controlling the decay of the rain shadow effect during glacial periods.     

Petrogenesis of lavas from the AMAR Valley and Narrowgate region of the FAMOUS Valley, 36°–37°N on the Mid-Atlantic Ridge

Basaltic lavas from the AMAR Valley and the Narrowgate region of the FAMOUS Valley on the Mid-Atlantic Ridge (36° to 37°?N) range in texture from aphyric to highly plagioclase phyric (>25% large plagioclase phenocrysts). Based on ⁸⁷Sr/⁸⁶Sr and ¹⁴³Nd/¹⁴⁴Nd ratios, most of these lavas can be subdivided into two distinct, isotopically homogeneous, groups: Group I has lower ⁸⁷Sr/⁸⁶Sr (0.70288±1) and higher ¹⁴³Nd/¹⁴⁴Nd (0.51312±1) ratios; Group II has higher ⁸⁷Sr/⁸⁶Sr (0.70296±1) and lower ¹⁴³Nd/¹⁴⁴Nd (0.51309±2) ratios. Most Group II lavas are aphyric, whereas Group I lavas are primarily plagioclase phyric. Lavas from both groups show a wide range in incompatible element abundance ratios (e.g., Zr/Nb =6–29; (La/Sm)_n=0.6–1.7). Aphyric lavas have relatively constant Sc (40±1.5?ppm) abundances and CaO/Al₂O₃ ratios (0.80±0.02). Group I lavas are confined primarily to the AMAR rift valley floor whereas Group II lavas are found along the east and west marginal highs. We interpret the isotopic differences between the two groups as reflecting a temporal change in the upwelling mantle beneath this region of the Mid-Atlantic Ridge which is south of the Azore Islands. For each group, a petrogenetic model consistent with the geochemical data is multi-stage decompression melting of an initially enriched, homogeneous, mantle source region. If the early derived, incompatible-element enriched, melt increments are not always pooled with subsequent increments, the erupted magma batches may have the major element characteristics of melts derived by 10 to 20% melting, but with incompatible element abundance ratios reflecting the change from an enriched to depleted source during the incremental melting process. In this process an initially homogeneous source can generate primary magmas with the required range in incompatible element abundance ratios shown by each group. The nearly constant CaO/Al₂O₃ ratios and Sc contents of the aphyric lavas with decreasing Mg?? reflects subsequent polybaric fractionation of clinopyroxene, plagioclase and olivine over the pressure interval 8–6?kbar (24–18?km), followed by rapid transport to the surface and eruption. There is no geochemical evidence for a crustal magma chamber beneath this section of the Mid-Atlantic Ridge.