微波消解法测定磷矿石中的主次量组分

磷元素是植物和动物营养的必需元素,所以全世界绝大多数的磷被作为一个主要成分用于粮食作物的氮-磷-钾肥料中。磷矿石是全球磷元素的最重要来源。     

Validation of Geant4 10.3 simulation of proton interaction for space radiation effects

Monte Carlo simulation of space radiation effects induced by protons is important for design of space missions. Geant4 is a well established toolkit for Monte Carlo simulation focused on high energy physics applications. In this work, a set of new validation results versus data for Geant4 electromagnetic and hadronic interaction of protons is presented and discussed. Optimal configuration of Geant4 physics for space applications is proposed.     

Design sea state assessment using genetic algorithm approach

Two major statistical issues can be distinguished in the procedure of wave extreme prediction. The first issue is that predicted extreme values must be based on data collected in a relatively short time. The second issue is extrapolation of the observed data into its extreme region, typically lying well beyond from even the most extreme available observation. The process of extrapolation plays a fundamental role in this area of analysis and therefore it is essential to fit empirically a convenient probability distribution that describes the available data as closely as possible. Determination of extreme values probability distribution parameters by genetic algorithm is applied to improve the methodology of extreme sea state prediction.Illustrative applications of the method are given for a North Atlantic sea environment. The results are presented as crest height maximum values occurring with a given probability or in a design storm that has a specified return period.     

Applied focused ion beam techniques for sample preparation of astromaterials for integrated nanoanalysis

Abstract— Sample preparation is always a critical step in the study of micrometer‐sized astromaterials available for study in the laboratory, whether their subsequent analysis is by electron microscopy or secondary ion mass spectrometry. A focused beam of gallium ions has been used to prepare electron transparent sections from an interplanetary dust particle (IDP), as part of an integrated analysis protocol to maximize the mineralogical, elemental, isotopic, and spectroscopic information extracted from one individual particle. In addition, focused ion beam (FIB) techniques have been employed to extract cometary residue preserved on the rims and walls of microcraters in 1100 series aluminum foils that were wrapped around the sample tray assembly on the Stardust cometary sample collector. Non‐ideal surface geometries and inconveniently located regions of interest required creative solutions. These include support pillar construction and relocation of a significant portion of sample to access a region of interest. Serial sectioning, in a manner similar to ultramicrotomy, is a significant development and further demonstrates the unique capabilities of focused ion beam microscopy for sample preparation of astromaterials.     

The role of carbonate-fluoride melt immiscibility in shallow REE deposit evolution

The Lugiin Gol nepheline syenite intrusion, Mongolia, hosts a range of carbonatite dikes mineralized in rare-earth elements(REE). Both carbonatites and nepheline syenite-fluorite-calcite veinlets are host to a previously unreported macroscale texture involving pseudo-graphic intergrowths of fluorite and calcite. The inclusions within calcite occur as either pure fluorite, with associated REE minerals within the surrounding calcite, or as mixed calcite-fluorite inclusions, with associated zirconosilicate minerals. Consideration of the nature of the texture, and the proportions of fluorite and calcite present(～29 and 71 mol%,respectively), indicates that these textures most likely formed either through the immiscible separation of carbonate and fluoride melts, or from cotectic crystallization of a carbonatefluoride melt. Laser ablation ICP-MS analyses show the pure fluorite inclusions to be depleted in REE relative to the calcite. A model is proposed, in which a carbonate-fluoride melt phase enriched in Zr and the REE, separated from a phonolitic melt, and then either unmixed or underwent cotectic crystallization to generate an REE-rich carbonate melt and an REE-poor fluoride phase. The separation of the fluoride phase(either solid or melt) may have contributed to the enrichment of the carbonate melt in REE, and ultimately its saturation with REE minerals. Previous data have suggested that carbonate melts separated from silicate melts are relatively depleted in the REE, and thus melt immiscibility cannot result in the formation of REE-enriched carbonatites. The observations presented here provide a mechanism by which this could occur, as under either model the textures imply initial separation of a mixed carbonate-fluoride melt from a silicate magma. The separation of an REEenriched carbonate-fluoride melt from phonolitic magma is a hitherto unrecognized mechanism for REE-enrichment in carbonatites, and may play an important role in the formation of shallow magmatic REE deposits.