微波消解法测定磷矿石中的主次量组分

磷元素是植物和动物营养的必需元素，所以全世界绝大多数的磷被作为一个主要成分用于粮食作物的氮-磷-钾肥料中。磷矿石是全球磷元素的最重要来源。     

OH point defects in olivine from Pakistan

The infrared (IR) spectra of gem-quality olivine crystals from Pakistan, formed in serpentinised dunitic rocks, are characterised by strongly pleochroic absorption bands at 3,613, 3,597, 3,580 and 3,566 cm^?1. These bands are assigned to O-H stretching vibrations of OH point defects corresponding to H₂O concentrations of about 35 wt ppm. Unlike other olivine spectra, the dominating bands are strongly polarised parallel to the b-axis. The unusual spectra type, excludes the presence of planar defects. This finding is supported by transmission electron microscopy. The 3,613 cm^?1 band is related to vacant Si sites, the slightly lower energetic bands preferentially to vacant M2 sites. The exclusive presence of these bands is not only a characteristic feature of olivines treated under high P,T conditions equivalent to mantle environment, the presence of these bands in untreated natural olivine also indicates formation conditions equivalent to crustal rocks.     

Experimental and numerical modelling of sedimentation in a rectangular shallow basin

Numerical simulation of flows in shallow reservoirs has to be checked for its consistency in predicting real flow conditions and sedimentation patterns. Typical flow patterns may exhibit flow separation at the inlet, accompanied by several recirculation and stagnation areas all over the reservoir surface. The aim of the present research project is to study the influence of the geometry of a reservoir on sediment transport and deposition numerically and experimentally, focusing on a prototype reservoir depth between 5 and 15 m as well as suspended sediment transport.
A series of numerical simulations is presented and compared with scaled laboratory experiments, with the objective of testing the sensitivity to different flow and sediment parameters and different turbulence closure schemes. Different scenarios are analyzed and a detailed comparison of preliminary laboratory tests and some selected simulations are presented.
The laboratory experiments show that suspended sediment transport and deposition are determined by the initial flow pattern and by the upstream and downstream boundary conditions. In the experiments, deposition in the rectangular basin systematically developed along the left bank, although inflow and outflow were positioned symmetrically along the centre of the basin. Three major horizontal eddies developed influencing the sediment deposition pattern. Although asymmetric flow patterns are privileged, a symmetric pattern can appear from time to time. This particular behaviour could also be reproduced by a two-dimensional depth-averaged flow and sediment transport model （CCHE2D）. The paper presents numerical simulations using different turbulence closure schemes （k-ε and eddy viscosity models）. In spite of the symmetric setup, these generally produced an asymmetric flow pattern that can easily switch sides depending on the assumptions made for the initial and boundary conditions. When using the laboratory experiment as a reference, the most reliable numerical results have been obtai     

Petrogenesis of the Swartruggens and Star Group II kimberlite dyke swarms,South Africa: constraints from whole rock geochemistry

Thirty-seven samples from the Swartruggens and Star Group II kimberlite dyke swarms, emplaced through the Kaapvaal craton, have been analysed for their major and trace element and Sr, Nd and Hf isotope compositions. The samples are all MgO-rich (~12–35 wt%) with high Mg# (0.72–0.90) and Ni (~610–2700 ppm) contents. The kimberlites are strongly enriched in incompatible elements (Zr = 140–668 ppm; La = 124–300 ppm; Nb = 68–227 ppm; Ba = 1500–7000), and have high and variable chondrite normalised La/Yb ratios (Swartruggens = 94 ± 21; Star = 202 ± 36). ⁸⁷Sr/⁸⁶Sr (0.70718–0.71050) ratios are elevated, whereas εNd (−11.95 to −7.84) and ¹⁷⁶Hf/¹⁷⁷Hf ratios (0.282160–0.282564) are low. Inter- and intra-dyke compositional variation is significant, and there are systematic differences between the kimberlites found at the two localities. Intra-locality differences can largely be attributed to a combination of the effects of alteration, crustal contamination, macrocryst entrainment and phenocryst fractionation. There is some evidence for distinct parental magmas formed through variable and low degrees (0.5–2%) of partial melting, as illustrated by crossing rare earth element patterns. The Star kimberlites have derived from a less radiogenic source, with higher LREE enrichment than the Swartruggens kimberlites. Inferred primary magmas at each locality have high Mg# (~0.83), are Ni-rich (850–1220 ppm) and are strongly enriched in incompatible elements. Calculated mantle source compositions are strongly enriched in incompatible elements (La/Yb_n ~ 10–50), but refractory in terms of Mg# and Ni contents. Incompatible element ratios such as Ba/Nb (>13.5), La/Nb (> 1.1) and Ce/Pb (< 22) are unlike those characteristic of Group I kimberlites or ocean island basalts, but indistinguishable from calc-alkaline magmas. Taken together with extremely low εNd and εHf, these compositional characteristics are used to argue for derivation of these Group II kimberlite magmas from the deep subcontinental lithospheric mantle, metasomatised during the Proterozoic by calc-alkaline fluids/melts.