Assimilationszahlen submerser Phanerogamen und ihre Beziehung zur Kohlensäureversorgung

Ohne Zusammenfassung     

The production of granitic melts during ultrametamorphism

Data concerning the occurrence and mineralogy of granitic rocks and migmatites indicate that granitic liquids are not generally water saturated and do not form on minimum melting curves. Experiments on the partial fusion of crustal materials containing water only in hydrated phases demonstrate that water undersaturated melts with compositional affinities to the granite family are produced at temperatures and pressures in accord with observations on the metamorphio state of migmatite terrains.     

The crystal structure of Ca5(PO4)2SiO4 (Silico-Carnotite)

Summary The crystal structure of Ca₅(PO₄)₂SiO₄ (silico-carnotite) has been determined from 3358 x-ray diffraction data collected by a counter method and has been refined toR _w =0.038,R=0.045, in space group Pnma. The unit cell parameters area=6.737 (1) Å,b=15.508 (2) Å andc=10.132 (1) Å at 24°C;Z=4. The observed density is 3.06 and the calculated density is 3.03 g · cm^–3. The crystal contains about 2.5% V₂O₅ as an impurity. The bond lengths within the tetrahedral anions suggest that substitution or disorder of PO₄ ^3–, SiO₄ ^4– and possibly VO₄ ^3– occurs among the anion sites. The structure has some relationship to that of Ca₅(PO₄)₃OH, the predominant inorganic phase in the human body, but suggests that the Ca₅(PO₄)₃OH type structure may not be stable without some of the OH positions being filled. Ca₅(PO₄)₂SiO₄ is more closely related to K₃Na(SO₄)₂ (glaserite) if it is considered that there are systematic cation vacancies in Ca₅(PO₄)₂SiO₄.This type of structure is consistent with the view that cation vacancies in the glaserite-type structure account for solid solutions between Ca₂SiO₄ and Ca₃(PO₄)₂ and between Ca₃(PO₄)₂ and CaNaPO₄.

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Die Kristallstruktur vonCa ₅(PO ₄)₂ SiO ₄ (Silicocarnotit)

Zusammenfassung Die Kristallstruktur von Ca₅(PO₄)₂SiO₄ (Silicocarnotit) wurde aus 3358 Röntgendiffraktometer-Daten bestimmt und in Raumgruppe Pnma aufR _w =0,038,R=0,045 verfeinert. Die Gitterkonstanten (bei 24° C) sind:a=6,737 (1) Å,b=15,508 (2) Å undc=10,132 (1) Å,Z=4; D_obs.=3,06 g · cm^–3, D_exp.=3,03 g · cm^–3. Der Kristall enthält etwa 2,5% V₂O₅ als Verunreinigung. Die Bindungslängen in den tetraedrischen Anionen legen nahe, daß unter den Anionenplätzen gegenseitige Vertretung oder Unordnung von PO₄ ^3–, SiO₄ ^4– und möglicherweise VO₄ ^3– auftritt. Die Struktur zeigt einige Verwandtschaft zu der von Ca₅(PO₄)₃OH, der wichtigsten anorganischen Substanz im menschlichen Körper, weist aber darauf hin, daß eine Struktur vom Ca₅(PO₄)₃OH-Typ ohne Besetzung eines Teiles der OH-Position nicht stabil ist. Ca₅(PO₄)₂SiO₄ zeigt engere Beziehungen zu K₃Na(SO₄)₂ (Glaserit), wenn man berücksichtigt, daß in Ca₅(PO₄)₃SiO₄ systematische Kationen-Leerstellen sind. Dieser Strukturtyp ist mit derAuffassung in Übereinstimmung, daß Kationenleerstellen für die festen Lösungen zwischen Ca₂SiO₄ und Ca₃(PO₄)₂ und zwischen Ca₃(PO₄)₂ und CaNaPO₄ verantwortlich sind.

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With 9 Figures     

Strike and dip of crustal boundaries — A method and its application

Summary If for a point on the earth's surface, the apparent (moveout) seismic velocities have been determined for a number of profiles in different directions, a possibility is offered to calculate true strike and dip of crustal boundaries. In the present paper the theory is developed, partly for a sloping Mohorovii discontinuity only, partly for sloping Conrad and Mohorovii discontinuities with parallel strikes. The theory for the sloping Mohorovii discontinuity is applied to field measurements at a place about 30 km west of Uppsala performed in June 1969. With a crustalP-wave velocity of 6.3 km/sec, a good fit to the observations is obtained for aPn-velocity of 8.55 km/sec and a downdip of Moho of 7.2° in the direction S 3.8° E. These numerical values are not the most important output of this paper. On the other hand, the testing of the method appears far more important, and also that improvements can be suggested in the experimental procedure in future applications of this method.     

Geophysical applications of heat and mass transfer in turbulent pipe flow

The theory of heat and mass transfer in turbulent pipe flow is applied to a semi-infinite moist-walled cylindrical pipe to determine the longitudinal distributions of both temperature and moisture content as functions of external conditions, pipe radius and wall temperature, and flow velocity. Since many cave and mine passages approximate this model, the results are directly applicable to cave microclimate studies and mine ventilation problems. The results are found to agree well with previously published microclimate observations. The theory is also applicable to water flow in free-flow karst aquifers; specifically to the study of temperature variations and of solution kinetics under turbulent flow conditions.     

Fatigue failure characteristics of some models of jointed rock

The time-dependent failure of rock subjected to repeated loading can be explained in terms of the residual strength locus: catastrophic failure occurs when the accumulation of deformation is such that the residual strength locus is intercepted. In a preliminary experimental study of the fatigue characteristics of rock masses, highly idealized models of jointed rock were subjected to a series of cyclic uniaxial compression tests. The results of these experiments show that intact and failed models of jointed rock are extremely susceptible to cyclic fatigue failure, and that in these cases the residual strength locus interpretation of time-dependent failure is correct.     

Detecting patterns of climate change in long-term forecasts of marine environmental parameters

ABSTRACT

Forecasting environmental parameters in the distant future requires complex modelling and large computational resources. Due to the sensitivity and complexity of forecast models, long-term parameter forecasts (e.g. up to 2100) are uncommon and only produced by a few organisations, in heterogeneous formats and based on different assumptions of greenhouse gases emissions. However, data mining techniques can be used to coerce the data to a uniform time and spatial representation, which facilitates their use in many applications. In this paper, streams of big data coming from AquaMaps and NASA collections of 126 long-term forecasts of nine types of environmental parameters are processed through a cloud computing platform in order to (i) standardise and harmonise the data representations, (ii) produce intermediate scenarios and new informative parameters, and (iii) align all sets on a common time and spatial resolution. Time series cross-correlation applied to these aligned datasets reveals patterns of climate change and similarities between parameter trends in 10 marine areas. Our results highlight that (i) the Mediterranean Sea may have a standalone ‘response’ to climate change with respect to other areas, (ii) the Poles are most representative of global forecasted change, and (iii) the trends are generally alarming for most oceans.     

The use of solar faculae in studies of the sunspot cycle

Comparison of the long-term variation of photospheric faculae areas with that of sunspots shows that studies of faculae provide both complementary and supplementary information on the behaviour of the solar cycle. Detailed studies of the development of sunspots with respect to faculae show that there is a high degree of order over much of a given cycle, but marked differences from cycle to cycle. Within a cycle the relationship between spot and faculae areas appears to be similar for the N and S solar hemispheres, and over the early stages of a cycle it is directly related to the magnitude of the maximum sunspot number subsequently attained in that cycle.This result may well have predictive applications, and formulae are given relating the peak sunspot number to simple parameters derived from this early developmental stage. Full application to the current cycle 21 is denied due to the cessation of the Greenwich daily photoheliographic measurements, but use of the cruder weekly data suggests a maximum smoothed sunspot number of 150 ± 22.The effects of the incompatibility of the spot and faculae data, in that faculae are unobservable over a large fraction of the solar disc and also do not always develop associated spots, have been examined in a detailed study of two cycles and shown not to vitiate the results.Now at NOAA, Environmental Data Service, NGSTDC, Boulder, Colo. 80302, U.S.A.     

Saturn's satellites: Nuar-infrared spectrophotometry (0.6–2.5 μm) of the leading and trailing sides and compositional implications

Near-infrared spectra, 0.65–2.5 μm, are presented for Tethys, Dione, Rhea, Iapetus, and Hyperion. Water ice absorptions at 2.0, 1.5, and 1.25 μm are seen in the spectra of all five objects (except the 1.25-μm band was not detected in spectra of Hyperion) and the weak 1.04-μm ice absorption is detected on the leading and trailing sides of Rhea, and the trailing side of Dione. Upper limits to the 1.04-μm ice band depth are <0.3% for the leading side of Dione; <0.7% for the leading side of Iapetus, and the trailing side of Tethys; <1% on the trailing side of Iapetus; and <5% on the leading side of Tethys. The leading-trailing side ice band depth differences on Saturn's satellites are similar to those for the Galilean satellites, indicating possible surface modification by magnetospheric charged particle bombardment. Limits are determined for the amount of particulates, trapped gases, and amonium hydroxide on the surface. The surfaces of Saturn's satellites (except the dark side of Iapetus) are nearly pure water ice, with probably less than about 1 wt% particulate minerals. The ice could be clathrates with as much as a few weight percent trapped gases. The upper limit of amonium hydroxide depends on the spectral data precision and varies from ～ 1 wt% NH₃ for the leading side of Rhea to ～ 10 wt% NH₃ for Dione.