Characterization of beryl (aquamarine variety) from pegmatites of Minas Gerais,Brazil

Eight samples of the beryl variety aquamarine were selected from four pegmatites in the Governador Valadares and Araçuaí regions in northeastern Minas Gerais State, Brazil. These samples were fully characterized by chemical analysis, infrared and UV-visible spectroscopy, thermal analyses, and high-temperature X-ray diffraction (from room temperature up to 800 °C). Several physical and chemical properties of beryl were found to depend on the amount of water and ions residing in the structural channels. The thermal expansion coefficients from room temperature to about 800 °C are temperature-independent, with αa ? ?3.2 × 10^?6 ° C^?1 and αc ? ?8.7 × 10^?6 ° C^?1. The contraction of both a and c unit-cell parameters with increasing temperature and the shift of the infrared band centered at about 1200 cm^?1 were tentatively ascribed to interactions between channel water and the silicate rings.The color of beryl seems to be dictated by the relative proportions of Fe³⁺ in the octahedralsites and of fe²⁺ in the channels. Thus, deep-blue samples have little Fe³⁺, whereas greener samples have more Fe³⁺ or less channel Fe²⁺.     

Monitoring Large-Scale Tests for Nuclear Waste Disposal

Two large-scale “in situ” demonstration experiments and their instrumentation are described. The first test (FEBEX Experiment) involves the hydration of a compacted bentonite barrier under the combined effect of an inner source of heat and an outer water flow from the confining saturated granite rock. In the second case, the progressive de-saturation of Opalinus clay induced by maintained ventilation of an unlined tunnel is analyzed. The paper shows the performance of different sensors (capacitive cells, psychrometers, TDR’s) and a comparison of fill behaviour with modelling results. The long term performance of some instruments could also be evaluated specially in the case of FEBEX test. Capacitive sensors provide relative humidity data during long transient periods characterised by very large variations of suction within the bentonite.     

Assessment of three temperature reconstruction methods in the virtual reality of a climate simulation

The performance of statistical climate reconstruction methods in the pre-instrumental period is uncertain, as they are calibrated in a short instrumental period but applied to much longer reconstructions time spans. Here, the virtual reality created by a climate simulation of the past millennium with the model ECHO-G is used as a test bed of three methods to reconstruct the annual Northern Hemisphere temperature. The methods are Composite plus Scaling, the inverse regression method of Mann et al. (Nature 392:779–787, 1998) and a direct principal-components regression method. The testing methodology is based on the construction of pseudo-proxies derived from the climate model output, the application of each of these methods to pseudo-proxy timeseries, and the comparison of their result with the simulated mean temperature. Different structures of the noise have been used to construct pseudo-proxies, ranging from the simulated grid-point precipitation. Also, one sparse and one denser pseudo-proxy network, co-located with two real networks, have been considered. All three methods underestimate the simulated variations of the Northern Hemisphere temperature, but the Composite plus Scaling method clearly displays a better performance and is robust against the different noise models and network size. The most relevant factor determining the skill of the reconstruction appears to be the network size, whereas the different noise models tend to yield similar results.     

Contrast in life histories of exploited fishes and ecosystem structures in coastal waters off west Canada and east Korea

By reviewing the history of fishery exploitation in the coastal waters of west Canada and east Korea, related with contrasting life history strategies of the dominant species, the fishery management challenges that each country would face in the upcoming decades were outlined. In the ecosystem of the Canadian western coastal waters, the dominant oceanographic feature is the coastal upwelling domain off the west coast of Vancouver Island, the northernmost extent of the California Current System in the eastern North Pacific. In the marine ecosystem of the eastern coasts of Korea (the Japan/East Sea), a major oceanographic feature is the Tsushima Warm Current, a branch of the Kuroshio Current in the western North Pacific. Fishes in the Canadian ecosystem are dominated by demersal, long-lived species such as flatfish, rockfish, sablefish, and halibut. During summer, migratory pelagic species such as Pacific hake, Pacific salmon, and recently Pacific sardine, move into this area to feed. In the late 1970s, Canada declared jurisdiction for 200 miles from their coastline, and major fisheries species in Canadian waters have been managed with a quota system. The overall fishing intensity off the west coast of Vancouver Island has been relatively moderate compared to Korean waters. Fishes in the ecosystem of the eastern Korean waters are dominated by short-lived pelagic and demersal fish. Historically, Korea has shared marine resources in this area with neighbouring countries, but stock assessments and quotas have only recently (since the late-1990s) been implemented for some major species. In the Korean ecosystem, fisheries can be described as intensive, and many stocks have been rated as overfished. The two ecosystems responded differently to climate impacts such as regime shifts under different exploitation histories. In the future, both countries will face the challenge of global warming and subsequent impacts on ecosystems, necessitating developing adaptive fisheries management plans. The challenges will be contrasting for the two countries: Canada will need to conserve fish populations, while Korea will need to focus on rebuilding depleted fish populations.     

Middle Miocene aquatic and wetland vegetation of the paleosinkhole at Tarnów Opolski,SW Poland

I analyzed spores, pollen and organic-walled algal remains in Middle Miocene deposits that filled a paleosinkhole at Tarnów Opolski, in the Upper Silesian Upland, Poland. Middle Triassic limestone bedrock in the study area underwent intense karstification under relatively warm and humid climate, resulting in development of numerous sinkholes. As the corrosion reached non-karstified marls, flowing water in the vadose zone was plugged and meteoric waters thus accumulated, leading to pond development. This palaeobotanical study was undertaken to “reconstruct” the fossil freshwater algae community and vegetation in and around the water body. Chlorophyta such as Botryococcus, filamentous algae from the family Zygnemataceae, mainly Mougeotia, Spirogyra and Zygnema, and desmids were important components of the algal assemblage. Most of the identified algae prefer mesotrophic to eutrophic conditions, and are characteristic of stagnant or slow-flowing shallow water. Among the free-floating and rooted plants were Salviniaceae/Azollaceae (probably Salvinia), Nuphar, Potamogeton, and carnivorous taxa such as Utricularia and probably Aldrovanda. The water body was surrounded by swamp vegetation composed of herbs such as Typha, Sparganium, Alismataceae and others, and riparian forests. The upper portion of the sediment section contains abundant pollen of swamp forest taxa such as Taxodium/Glyptostrobus, Nyssa and Alnus. The paleobotanical remains from the sinkhole at Tarnów Opolski suggest it was a shallow water body that was probably prone to rapid warming. Presence of resting cells, e.g. zygospores of Zygnemataceae and desmids, suggests that the pond may have dried periodically. Presence of Nuphar, Utricularia and Aldrovanda pollen, however, indicates long periods with standing water.     

Segmentation algorithm for long time series analysis

Time series analysis is an important issue in the earth science-related engineering applications such as hydrology, meteorology and environmetrics. Inconsistency and nonhomogeneity that might arise in a time series yield segments with different statistical characteristics. In this study, an algorithm based on the first order statistical moment (average) of a time series is developed and applied on five time series with length ranging from 84 items to nearly 1,300. Comparison to the existing segmentation algorithms proves the applicability and usefulness of the proposed algorithm in long hydrometeorological and geophysical time series analysis.     

A geologic study of the Juan del Grijalva landslide,the most important mass movement during the last century in Mexico

On November 4th 2007, along the Grijalva River in the state of Chiapas, Mexico, has occurred one of the largest landslides ever known. This landslide, known as Juan del Grijalva, destroyed the town of the same name, killing 20 people, and moved 55 million cubic meters of rock and debris down slope to completely block the Grijalva River. In order to understand the characteristics and factors that triggered the Juan del Grijalva landslide, geologic studies were conducted at the site. The results indicate that the landslide was composed of a lithologic sequence of thin-bedded shales and thin to medium-thick-bedded sandstones. This was faulted into several blocks dipping in the same sense as the mass movement. The main triggering factor was the increment of the pore pressure into the lithologic unit due to water saturation after 5 days of heavy rain before the incident. According to records from the last century, the Juan del Grijalva mass movement represents one of the largest mass movements recorded all over the world. The risk conditions of the area after the landslide lead to the rapid construction of an artificial channel to drain the accumulating mass of water upstream and therefore prevent a future catastrophic inundation down stream.     

Colloidal Stability and Toxicity of Gold Nanoparticles and Gold Chloride on <Emphasis Type="Italic">Chlamydomonas reinhardtii</Emphasis>

Here we have examined interactions of gold nanoparticles differing in primary particle size and coating with the green algae Chlamydomonas reinhardtii as function of the colloidal stability of the particles in the experimental media used for toxicity studies. Interactions of dissolved Au³⁺ ions with algae were also examined. Included endpoints were photosynthetic yield and algal growth. Morphological and structural effects were examined microscopically and by flow cytometry. The results indicate no significant toxicity of gold nanoparticles to C. reinhardtii. Analysis of published data suggests toxicity of gold nanoparticles on algal growth to relate rather to particular coatings than to the gold core.     

A semi-continuous measurement of gaseous ammonia and particulate ammonium concentrations in PM<Subscript>2.5</Subscript> in the ambient atmosphere

Ammonia has a short residence time in the atmosphere and rapidly neutralizes acid gases that occur near its source, requiring a rapid measurement system for ammonia and particulate ammonium concentrations to better understand their sources, temporal variation of ammonia emissions, and the formation of secondary ammonium aerosols. A semi-continuous measurement system, consisting of a diffusion scrubber, a particle growth chamber, an air-liquid separator, and a fluorescent detector, was developed to determine both gaseous ammonia (NH₃) and particulate ammonium (NH ₄ ⁺ ) in PM_2.5 in the ambient atmosphere of Gwangju, South Korea, during the months of March, April, July, and September of 2007. During the sampling periods, the average concentrations of ammonia and ammonium were found to be 2.33?±?1.29 μg/m³ and 1.89?±?0.99 μg/m³, respectively. Although the average gaseous ammonia concentration was highest in March, the particulate ammonium concentration was higher during the warmer season, reaching 2.08?±?1.07 μg/m³ and 2.32?±?0.94 μg/m³ in April and July, respectively, while only 1.68?±?0.61 μg/m³ in March and 1.24?±?0.99 μg/m³ in September. It is proposed that the higher availability of acid species during the warmer months produced a significant amount of particulate ammonium sulfate. Diurnal fluctuation of ammonia and ammonium during the warmer months showed that their peak time occurred at approximately 10:00 am. Both ammonia and ammonium concentrations were better correlated during the warmer months than during the cooler months. Further, the data suggest that the ammonia and ammonium were measured under well dispersed conditions, and multiple sources contributed to the ammonia at the sampling site.     

Hydrochemical and Multivariate Statistical Evaluation of Heavy Metals in Shallow Alluvial Aquifers of North Brahmaputra Plain,India

The aim of this study was to display distribution and relationships of heavy elements in the unconfined, shallow alluvial aquifers of the lower Jia Bharali catchment and adjoining areas in central part of North Brahmaputra Plain (NBP), India using hydrochemical as well as multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis. The original matrix was made up of 10 trace elements (As, Cd, Cu, Co, Cr, Fe, Mn, Pb, Ni and Zn) estimated from 50 shallow alluvial dug wells in both the wet and the dry season for a duration of 3 hydrological years (2008–2011). Except As, Cu and Zn all the other toxic metals in the shallow aquifers were found exceeding the WHO maximum permissible limits for drinking water. PCA extracted five varimax factors as geogenic, agricultural and anthropogenic explaining about 71.2% of the total variance in the wet season and 69.3% total variance in the dry season. Hierarchical cluster analysis classified the dug wells into two groups in the wet season and three groups in the dry season with respect to the heavy elements. The results emphasized the need for routine monitoring and management in order to avoid contamination of groundwater sources in the NBP with respect to the dissolved trace elements.