An occurrence of cadmiferous phosphorite soil concretions in Jamaica

Bauxite exploration drilling revealed the presence of phosphate minerals through the chemical and XRD analysis of recovered drill hole samples at Spitzbergen, in Manchester Parish, Jamaica. A subsequent pit led to the discovery of phosphorite concretions composed of hard competent masses of finely crystalline fluorapatite, with some minor crandallite. The phosphorite contains anomalously high levels of Zn (>5000 mg kg⁻¹), Cd (>1.1%), Ag (>20 mg kg⁻¹), Be (>80 mg kg⁻¹) and, to a lesser extent, U. Textural and geochemical evidence indicates that the phosphorite concretions were most likely formed by the replacement of limestone by secondary deposition proximal to fossil guano deposits, postulated to be Late Miocene or Pliocene sea-bird colonies. Mechanical dispersion of the phosphorite concretions through karst weathering processes has led to their wider spatial distribution than the original guano deposits. Subsequent weathering of the concretions and the admixture of their decomposition products into the bauxitic and Terra Rossa soils is postulated to be the cause of the widespread anomalous levels of Zn, Cd and Be in these soils in central Jamaica, and the elevated levels of P in the bauxite.     

Formation of the Vysoká–Zlatno Cu–Au skarn–porphyry deposit, Slovakia

The central zone of the Miocene Štiavnica stratovolcano hosts several occurrences of Cu–Au skarn–porphyry mineralisation, related to granodiorite/quartz–diorite porphyry dyke clusters and stocks. Vysoká–Zlatno is the largest deposit (13.4 Mt at 0.52% Cu), with mineralised Mg–Ca exo- and endoskarns, developed at the prevolcanic basement level. The alteration pattern includes an internal K- and Na–Ca silicate zone, surrounded by phyllic and argillic zones, laterally grading into a propylitic zone. Fluid inclusions in quartz veinlets in the internal zone contain mostly saline brines with 31–70 wt.% NaCl eq. and temperatures of liquid–vapour homogenization (Th) of 186–575°C, indicating fluid heterogenisation. Garnet contains inclusions of variable salinity with 1–31 wt.% NaCl eq. and Th of 320–360°C. Quartz–chalcopyrite veinlets host mostly low-salinity fluid inclusions with 0–3 wt.% NaCl eq. and Th of 323–364°C. Data from sphalerite from the margin of the system indicate mixing with dilute and cooler fluids. The isotopic composition of fluids in equilibrium with K-alteration and most skarn minerals (both prograde and retrograde) indicates predominantly a magmatic origin (δ¹⁸O_fluid 2.5–12.3‰) with a minor meteoric component. Corresponding low δD_fluid values are probably related to isotopic fractionation during exsolution of the fluid from crystallising magma in an open system. The data suggest the general pattern of a distant source of magmatic fluids that ascended above a zone of hydraulic fracturing below the temperature of ductile–brittle transition. The magma chamber at ∼5–6 km depth exsolved single-phase fluids, whose properties were controlled by changing PT conditions along their fluid paths. During early stages, ascending fluids display liquid–vapour immiscibility, followed by physical separation of both phases. Low-salinity liquid associated with ore veinlets probably represents a single-phase magmatic fluid/magmatic vapour which contracted into liquid upon its ascent.     

Groundwater contributions of flow and nitrogen in a headwater agricultural watershed

Nonpoint sources of nitrogen (N) and other nutrients are a major source of water pollution within the Chesapeake Bay watershed and other basins around the world. Human activities associated with agricultural practices can account for a large percentage of N loadings delivered to streams and rivers. This work aims to improve understanding of N transport from groundwater to surface waters, quantifying the principal hydrological processes driving water and N fluxes into and out of a headwater agricultural stream reach. The study site is a 175-m stream reach in a heavily cultivated 40-ha watershed in east-central Pennsylvania. This subwatershed is underlain by fractured shale bedrock, and receives most of its baseflow from groundwater, either by diffuse matrix discharge through the streambed or by localized discharge through riparian seeps. Samples of stream, seep, and shallow groundwater were collected approximately monthly under steady hydrologic conditions in 2017. Calculated matrix flow from hydraulic head and conductivity measurements paired with differential stream gauging was used to solve for the riparian seep flux using a mass balance approach. Riparian seep fluxes ranged from 45 to 217 m³/d, transporting 0.6–4.2 kg N d⁻¹ of nitrate-N from the fractured bedrock aquifer to the stream. Hydrochemical data suggest that the stream is mainly disconnected from the underlying aquifer and that seeps supply essentially all water and N to the system. Seeps are likely sourced with N in nearby agricultural fields and accelerated through the system with shorter residence times than shallow groundwater. Water isotope data reinforced this notion. This study underscores the importance of agriculture as a source of N to ground and surface waters. Identifying source areas that are causing groundwater enrichment of N and seep areas where N discharges to streams is beneficial for developing N pollution mitigation strategies and implementing management practices that aim to reduce nutrient loads to the Chesapeake Bay.     

Genotyping of Rhodopirellula baltica organisms using multispacer sequence typing

Rhodopirellula baltica is a ubiquitous Planctomycetes organism isolated from marine environments worldwide. Multilocus sequence analysis (MLSA) has been the only method used to assess the diversity of R. baltica organisms. Here, we developed multispacer sequence typing (MST) genotyping and applied it to four R. baltica isolates from the French Mediterranean Sea and R. baltica DSM10527^T type strain. While MLSA yielded interpretable sequences for two of nine genes in three R. baltica isolates, MST based on sequencing two intergenic spacers yielded an unambiguous, strain‐specific profile for each one of the four R. baltica isolates under investigation. We propose that MST could be used as an alternative R. baltica genotyping method to assess the diversity of these Planctomycetes organisms.     

Use of Federal Sand for Beach Nourishment and Shore Protection Projects

Coastal shoreline protection and beach nourishment are significant issues for coastal states along the Atlantic and Gulf coasts. In some areas, there is a critical need to identify suitable sources of sand for possible use in public works projects for coastal protection. The continental shelf contains large resources of sand and gravel that could be used to support such projects. The U.S. Department of the Interior's (DOI) Minerals Management Service (MMS) provides policy direction and guidance for development of the resources located on the federal portion of the continental shelf. This article highlights the MMS's Sand Program, focusing on its cooperative resource and environmental studies with several coastal states, significant milestones and accomplishments, and anticipated activities in 1998 and beyond. Management of sand resources on the federal portion of the continental shelf has been made easier by a federal state partnership concept. Using this cooperative concept, joint projects are being conducted to investigate offshore sand resources, potential sites, extraction methods, and related environmental conditions. The MMS has procedures for negotiating sand agreements under the Outer Continental Shelf Lands Act (OCSLA) and ensuring that the resources are developed in an environ mentally sound manner. The authority to negotiate with project sponsors, an important recent change in the OCSLA, also resides with the MMS. This 1992 change in OCSLA facilitates the use of Outer Continental Shelf (OCS)resources for public projects. Further, the MMS is authorized to assess a fee based on the value of the resource and the public interest served. The MMS has worked with local sponsors and authorized the use of OCS sand for two projects. However, additional resource and environmental projects, as well as negotiated agreements, are anticipated within the near future with states and local governments along the Atlantic and Gulf coasts.     

Petrogenesis of basaltic shergottite Northwest Africa 5298: Closed‐system crystallization of an oxidized mafic melt

Abstract– Northwest Africa (NWA) 5298 is an evolved basaltic shergottite that has bulk characteristics and mineral compositions consistent with derivation from an oxidized reservoir in Mars. Chemically zoned clinopyroxene (64.5%, augite and pigeonite), with interstitial lath‐shaped plagioclase (29.4%, An₄₀ to An₅₅), constitutes the bulk of this meteorite. The plagioclase has been converted by shock to both isotropic maskelynite and spherulitic, birefringent feldspar representing a quenched vesicular melt. The remainder of the rock consists of minor amounts of Fe‐Ti oxides (ilmenite and titanomagnetite), phosphates (merrillite and apatite), silica polymorph, fayalite, pyrrhotite, baddeleyite, and minor hot desert weathering products (calcite and barite). Oxygen fugacity derived from Fe‐Ti oxide thermobarometry is close to the quartz‐fayalite‐magnetite (QFM) buffer indicating that the late stage evolution of this magma occurred under more oxidizing condition than those recorded in most other shergottites. Merrillite contains the largest abundances of rare earth elements (REE) of all phases, thereby controlling the REE budget in NWA 5298. The calculated bulk rock REE pattern normalized to CI chondrite is relatively flat. The evolution of the normalized REE patterns of the bulk rock, clinopyroxene, plagioclase, and phosphate in NWA 5298 is consistent with closed‐system chemical behavior with no evidence of crustal contamination or postcrystallization disturbance of the REE contents of these phases.     

Evaluation of the WAMME model surface fluxes using results from the AMMA land-surface model intercomparison project

The West African monsoon (WAM) circulation and intensity have been shown to be influenced by the land surface in numerous numerical studies using regional scale and global scale atmospheric climate models (RCMs and GCMs, respectively) over the last several decades. The atmosphere–land surface interactions are modulated by the magnitude of the north–south gradient of the low level moist static energy, which is highly correlated with the steep latitudinal gradients of the vegetation characteristics and coverage, land use, and soil properties over this zone. The African Multidisciplinary Monsoon Analysis (AMMA) has organised comprehensive activities in data collection and modelling to further investigate the significance land–atmosphere feedbacks. Surface energy fluxes simulated by an ensemble of land surface models from AMMA Land-surface Model Intercomparison Project (ALMIP) have been used as a proxy for the best estimate of the “real world” values in order to evaluate GCM and RCM simulations under the auspices of the West African Monsoon Modelling Experiment (WAMME) project, since such large-scale observations do not exist. The ALMIP models have been forced in off-line mode using forcing based on a mixture of satellite, observational, and numerical weather prediction data. The ALMIP models were found to agree well over the region where land–atmosphere coupling is deemed to be most important (notably the Sahel), with a high signal to noise ratio (generally from 0.7 to 0.9) in the ensemble and a inter-model coefficient of variation between 5 and 15%. Most of the WAMME models simulated spatially averaged net radiation values over West Africa which were consistent with the ALMIP estimates, however, the partitioning of this energy between sensible and latent heat fluxes was significantly different: WAMME models tended to simulate larger (by nearly a factor of two) monthly latent heat fluxes than ALMIP. This results due to a positive precipitation bias in the WAMME models and a northward displacement of the monsoon in most of the GCMs and RCMs. Another key feature not found in the WAMME models is peak seasonal latent heat fluxes during the monsoon retreat (approximately a month after the peak precipitation rates) from soil water stores. This is likely related to the WAMME northward bias of the latent heat flux gradient during the WAM onset.     

Consistency and fidelity of Indonesian-throughflow total volume transport estimated by 14 ocean data assimilation products

Monthly averaged total volume transport of the Indonesian throughflow (ITF) estimated by 14 global ocean data assimilation (ODA) products that are decade to multi-decade long are compared among themselves and with observations from the INSTANT Program (2004–2006). The main goals of the comparisons are to examine the consistency and evaluate the skill of different ODA products in simulating ITF transport. The ensemble averaged, time-mean value of ODA estimates is 13.6 Sv (1 Sv = 10⁶ m³/s) for the common 1993–2001 period and 13.9 Sv for the 2004–2006 INSTANT Program period. These values are close to the 15-Sv estimate derived from INSTANT observations. All but one ODA time-mean estimate fall within the range of uncertainty of the INSTANT estimate. In terms of temporal variability, the scatter among different ODA estimates averaged over time is 1.7 Sv, which is substantially smaller than the magnitude of the temporal variability simulated by the ODA systems. Therefore, the overall “signal-to-noise” ratio for the ensemble estimates is larger than one. The best consistency among the products occurs on seasonal-to-interannual time scales, with generally stronger (weaker) ITF during boreal summer (winter) and during La Nina (El Nino) events. The scatter among different products for seasonal-to-interannual time scales is approximately 1 Sv. Despite the good consistency, systematic difference is found between most ODA products and the INSTANT observations. All but the highest-resolution (18 km) ODA product show a dominant annual cycle while the INSTANT estimate and the 18-km product exhibit a strong semi-annual signal. The coarse resolution is an important factor that limits the level of agreement between ODA and INSTANT estimates. Decadal signals with periods of 10–15 years are seen. The most conspicuous and consistent decadal change is a relatively sharp increase in ITF transport during 1993–2000 associated with the strengthening tropical Pacific trade wind. Most products do not show a weakening ITF after the mid-1970s’ associated with the weakened Pacific trade wind. The scatter of ODA estimates is smaller after than before 1980, reflecting the impact of the enhanced observations after the 1980s. To assess the representativeness of using the average over a three-year period (e.g., the span of the INSTANT Program) to describe longer-term mean, we investigate the temporal variations of the three-year low-pass ODA estimates. The average variation is about 3.6 Sv, which is largely due to the increase of ITF transport from 1993 to 2000. However, the three-year average during the 2004–2006 INSTANT Program period is within 0.5 Sv of the long-term mean for the past few decades.