Some characteristics of ozone profiles above Hong Kong

Summary Analysis of ozonesonde data shows that in the lower troposphere above Hong Kong, there is a relative maximum with respect to height in all seasons except winter. In the upper troposphere, there is with respect to height a relative minimum in the seasonally averaged ozone mixing ratio in winter. Ozone mixing ratios in the upper troposphere in winter and spring can be significantly enhanced by stratospheric intrusions associated with the passage of cold fronts and upper cut-off lows.For Hong Kong, the seasonally averaged total ozone has the highest value in spring, and the lowest in winter. The seasonally averaged total tropospheric ozone also has the highest value in spring, but the lowest in summer. In a relative sense, total tropospheric ozone contributes most to the total ozone in spring and the least in summer.The phase of the total ozone anomaly above Hong Kong is influenced by the Quasi-Biennial Oscillation (QBO), with the positive anomaly associated with the easterly phase of QBO, and the negative anomaly the westerly phase.     

QUEST on DASI: a South Pole CMB polarization experiment

QUEST on DASI is a ground-based, high-sensitivity, high-resolution (ℓ_max2500) experiment designed to map CMB polarization at 100 and 150 GHz and to measure the power spectra from E-modes, B-modes from lensing of the CMB, and B-modes from primordial gravitational waves. The experiment comprises a 2.6 m Cassegrain optical system, equipped with an array of 62 polarization-sensitive bolometers (PSBs), located at the South Pole. The instrument is designed to minimize systematic effects; features include differencing of pairs of orthogonal PSBs within a single feed, a rotatable achromatic waveplate, and axisymmetric rotatable optics. In addition the South Pole location allows both repeatable and highly controlled observations. QUEST on DASI will commence operation in early 2005.     

Basaltic and Solution Reference Materials for Iron,Copper and Zinc Isotope Measurements

Iron, Cu and Zn stable isotope systems are applied in constraining a variety of geochemical and environmental processes. Secondary reference materials have been developed by the Institute of Geology, Chinese Academy of Geological Sciences (CAGS), in collaboration with other participating laboratories, comprising three solutions (CAGS‐Fe, CAGS‐Cu and CAGS‐Zn) and one basalt (CAGS‐Basalt). These materials exhibit sufficient homogeneity and stability for application in Fe, Cu and Zn isotopic ratio determinations. Reference values were determined by inter‐laboratory analytical comparisons involving up to eight participating laboratories employing MC‐ICP‐MS techniques, based on the unweighted means of submitted results. Isotopic compositions are reported in per mil notation, based on reference materials IRMM‐014 for Fe, NIST SRM 976 for Cu and IRMM‐3702 for Zn. Respective reference values of CAGS‐Fe, CAGS‐Cu and CAGS‐Zn solutions are as follows: δ⁵⁶Fe = 0.83 ± 0.07 and δ⁵⁷Fe = 1.20 ± 0.13, δ⁶⁵Cu = 0.57 ± 0.06, and δ⁶⁶Zn = ?0.79 ± 0.12 and δ⁶⁸Zn = ?1.65 ± 0.24, respectively. Those of CAGS‐Basalt are δ⁵⁶Fe = 0.15 ± 0.07, δ⁵⁷Fe = 0.22 ± 0.10, δ⁶⁵Cu = 0.12 ± 0.08, δ⁶⁶Zn = 0.17 ± 0.13, and δ⁶⁸Zn = 0.34 ± 0.26 (2s).     

Development of a GIS-based catastrophe theory model (modified DRASTIC model) for groundwater vulnerability assessment

This study developed a new paradigm for groundwater vulnerability assessment by modifying the standard DRASTIC index (DI) model based on catastrophe theory. The developed paradigm was called the catastrophe theory-based DI (CDI) model. The proposed model was applied to assess groundwater vulnerability to pollution index (GVPI) in Perak Province, Malaysia. The area vulnerability index was modeled by considering the DRASTIC multiple vulnerability causative factors (VCFs) obtained from different data sources. The weights and ranking of the VCFs were computed by using the inner fuzzy membership mechanism of the CDI model. The estimated vulnerability index values of the CDI model were processed in a geographic information system (GIS) environment to produce a catastrophe theory–DRASTIC groundwater vulnerability to pollution index (CDGVPI) map, which demarcated the area into five vulnerability zones. The produced CDGVPI map was validated by applying the water quality status–vulnerability zone relationship (WVR) approach and the relative operating characteristic (ROC) curve method. The performance of the developed CDI model was compared with that of the standard DI model. The validation results of the WVR approach exhibits 89.29% prediction accuracy for the CDI model compared with 75% for the DI model. Meanwhile, the ROC validation results for the CDI and DI models are 88.8% and 78%, respectively. The GIS-based CDI model demonstrated better performance than the DI model. The GVPI maps produced in this study can be used for precise decision making process in environmental planning and groundwater management.     

Trends in 1,4-Dioxane Analyses: Implications for Identification and Characterization of Contaminated Groundwater Sites

1,4-Dioxane is a contaminant of emerging concern, and there is significant uncertainty about how its environmental occurrence in groundwater is being assessed given the various analytical methods available. This study compiled public sampling records from 2000 to 2019 that included >106,000 analyses of 1,4-dioxane from 822 different U.S. sites. The 1,4-dioxane detection frequency in the entire dataset (including all methods) was 45%, and the median detected concentration was 10 μg/L, highlighting the dilute nature of 1,4-dioxane in environmental media and the importance of selecting methods with adequate sensitivity. The annual distribution of samples analyzed by each method type confirmed a shift towards methods designed for semi-volatile compounds (Method 8270 and Method 8270 SIM) that exhibited consistently lower reporting limits (median reporting limit for each year typically ≤1 μg/L). In contrast, the method designed for volatile compounds (Method 8260) exhibited less sensitivity for 1,4-dioxane (median reporting limit per year between 40 and 100 μg/L) and its use declined significantly over time with increasing use of the moderately sensitive Method 8260 SIM in later years. This shift contributed to an increase in the 1,4-dioxane detection frequency over time, with a strong correlation between the annual detection frequency and the median reporting limit. Sites where 1,4-dioxane was analyzed but not detected overwhelmingly used less-sensitive methods that may not have been adequate for the expected concentration levels. Given the sub-μg/L groundwater criteria issued for 1,4-dioxane by some regulatory agencies, more sensitive and accurate methods will be increasingly needed to assess compliance.     

The Distribution of Craters Within Craters

Photometric correction is a necessary step in planetary image pre-processing since the images of planetary surfaces are acquired by orbiting spacecraft at various observational geometries. In this study, visible (748 nm) and near-infrared (948 nm) bands of Hyper Spectral Imager (HySI) onboard Chandrayaan-1 have been used to derive a preliminary photometric correction for lunar data. The purpose of the proposed photometric correction for HySI is to convert observations taken at solar incidence (i), sensor emission (e), and the solar phase angles (α) to a fixed geometry by applying i?=?α?=?30° and e?=?0° to each image. The Lommel–Seeliger function was used to model the lunar limb darkening effect, while topography data from the merged Digital Elevation Model of Lunar Reconnaissance Orbiter—Lunar Orbiter Laser Altimeter (LRO-LOLA) and SELENE Terrain Camera (TC) was used to correct local topographic effects. Data from Moon Mineralogy Mapper (M³), SELENE Multiband Imager (MI) and Clementine Ultraviolet and Visible Camera (UV/VIS) were also used to compare radiance, reflectance and phase functions derived from HySI. Our analysis reveals that HySI is darker than M³ primarily due to low surface radiance conditions observed by HySI. The derived phase functions for the two HySI bands indicate a good correlation between the derived reflectance and phase angle as well as with the phase functions derived for the empirically corrected M³ data. This approach led to the derivation of a photometric correction for maria regions. Finally, it is expected that the proposed correction would be applicable to all HySI images covering the lunar mare region.

     

Linear and nonlinear vibration of non-uniform beams on two-parameter foundations using p-elements

A hierarchical finite element is presented for the geometrically nonlinear free and forced vibration of a non-uniform Timoshenko beam resting on a two-parameter foundation. Legendre orthogonal polynomials are used as enriching shape functions to avoid the shear-locking problem. With the enriching degrees of freedom, the accuracy of the computed results and the computational efficiency are greatly improved. The arc-length iterative method is used to solve the nonlinear eigenvalue equation. The computed results of linear and nonlinear vibration analyses show that the convergence of the proposed element is very fast with respect to the number of Legendre orthogonal polynomials used. Since the elastic foundation and the axial load applied at both ends of the beam affect the ratios of linear frequencies associated with the internal resonance, they influence the nonlinear vibration characteristics of the beam. The axial tensile stress of the beam in nonlinear vibration is investigated in this paper, and attention should be paid to the geometrically nonlinear vibration resulting in considerably large axial tensile stress in the beam.