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11.
High levels of Cd and Zn in Jamaican soils observed in geochemical surveys are related to the presence of phosphorites of possible Late-Miocene or Pliocene age. The trace element and REE geochemistry of the phosphorites, together with SEM studies, indicate a guano origin for the phosphorites. No specific host minerals for Cd could be identified in the fossiliferous phosphorite which is characterized by uniquely high levels of Cd, Zn, Ag, Be, U and Y. However, in the soil Cd is present in lithiophorite and a complex history of pedological development is preserved in the aluminous–goethite present in the soil. The unique guano signature is preserved in the soil despite the fact that guanos themselves have either not been observed or have been destroyed by continuing karst and soil development. The phosphorite geochemical signature can be traced in the data of a 1988 island-wide soil geochemical survey, identifying areas where the Palaeo-environment that supported bird ‘rookeries’ existed in the Late-Miocene or Pliocene. 相似文献
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Experiments were conducted in an oscillatory water tunnel to investigate what effects temporal inertia has on the resistance of a granular medium. The flow law governing stationary porous media flow is reasonably well accepted and understood but the effects of unsteady flow have commonly been neglected. The present research was designed to assess the magnitude of the acceleration effects on media of uniformly packed spheres of equal diameter and on one sample of randomly placed stone.Oscillatory flow tests were made in a large oscillatory flume tunnel with periods varying from 3 to 12 seconds. The influence of properties of the medium (grain size and porosity) were tested by using spheres with two different diameters and packing each size sphere in different geometric arrangements. Tests made on a stone sample provided a qualitative assessment of the effects of more random material properties.For the experiments described in this paper, the Forchheimer unsteady-stationary flow law described the oscillatory measurements well when velocities and energy losses were maximum. Empirical coefficients determined from steady-stationary flow were generally found to apply to the unsteady flow, however some evidence of dependency on the period of oscillation was noted. 相似文献
14.
P. Cobo C. Ranz A. Fernández M. Cuesta D.K. Anthony M. Siguero 《Marine Geophysical Researches》2005,26(2-4):87-95
Vertical resolution is of fundamental importance in sonar exploration and is directly related to the duration of the acoustic
pulse generated by the transducer. The shorter the radiated pulse, the higher the vertical resolution. Many sub-bottom profiling
sonar systems use piezoelectric transducers because they are reversible and well understood. Piezoelectric projectors are
normally resonant transducers, which are intrinsically narrowband. A piezoelectric transducer is usually driven by a tone-burst.
However, it is possible to use Fourier techniques to find a pre-compensated electrical driving function so that the transducer
radiates a prescribed wider band acoustic waveform. This technique can be applied to synthesize zero-phase cosine-magnitude,
Gaussian, and bionic pulses, with a conventional sandwich transducer. Zero-phase cosine-magnitude waveforms provide minimum
length pulses (and therefore maximum resolution) within a prescribed frequency band.The aim of this paper is to illustrate
the synthesis of wideband acoustic pulses using an underwater piezoelectric projector. The conventional acoustic waveform
radiated when a Tonpiltz transducer is transiently excited using a “click” and allows its frequency response function to be
measured. This function is used to design the electrical signal which then drives the transducer so that it radiates the shortest
pulse compatible with its mechanical response. The significant resolution enhancement of the waveform shaping process is illustrated
by its application to a sediment wedge model. 相似文献
15.
The concentrations of total carbonate (Ct), sulphate, sulphide, thiols and oxygen, the ratio between the stable sulphur isotopes 34S and 32S in sulphate and sulphide, and the density (used to calculate salinity) were determined on samples from the water column of Framvaren, a superanoxic fjord in southern Norway. From a depth of 18m (the oxic-anoxic boundary) the initial sulphate concentration, ([SO4]init), as calculated from salinity, is significantly higher than the sum of the measured sulphur species. This is attributed to a loss of sulphur from the water column. The amount of total carbonate produced, corrected for the initial concentration (Ct - 2.4 Sal/35) is found to be proportional to the amount of sulphate consumed, ([SO4]init - [SO4]), according to the following relation Ct- 2.4 Sal/35 = 1.84 ([SO4]init - [SO4]). Isotopic fractionation caused by bacterial sulphate reduction in the anoxic part of the water column produces sulphide with a δ34S 40‰ lower than the δ34S for sulphate at corresponding depths. The isotopic fractionation also results in δ34S value for the remaining sulphate at depths below 80 m being considerably higher than the mean value for ocean water, which is close to + 20‰. The δ34S values for sulphate at depths between 10 and 50 m were lower than + 20‰ which indicates oxidation of sulphide, which follows upon diffusion of sulphide from deeper parts of the water column and inflow of oxygenated seawater over the sill into the anoxic water of the fjord. A conclusive scenario of the Framvaren sulphur chemistry is presented. 相似文献
16.
格陵兰东南部和相邻大洋表层气温时序中记录了一个急剧的事件。这一事件大约出现在3100a(模拟年) ,持续约40a ,以温度降低3°C为特征。由于其峰值比平均值高6个标准偏差(σ)以上 ,可以认为降温是急剧的。如果该区域年平均表层气温时序正常排布 ,那么这种异常可能每数亿年出现一次,如此大幅度降温持续那么久的概率极小。如果将不足40a的变化从时序中去掉 ,那么事件高峰期表层气温低于平均值10~11σ。大气层较低层位的这种急剧降温源于海面温度急剧下降。大约3086a开始 ,格陵兰东海岸中部滨外发育了约0.5°C… 相似文献
17.
A code of practice for ocean mining has been developed by the International Marine Minerals Society. The code provides general guiding Principles for development of marine mineral resources and delineates Operating Guidelines for application, as appropriate, at specific mining sites. In total 11 operating guidelines are provided to serve as benchmarks for industry and targets for regulatory agencies and other stakeholders. They include the following commitments: •To sustainable development, •To environmentally responsible corporate ethics, •To the development of effective community partnership, •To implementation of environmental risk management, •To the integration of environmental management into all phases of development, •To the establishment of corporate environmental performance targets, •To timely environmental improvements and upgrading, •To responsible rehabilitation of operations sites and decommissioning of facilities, and •To accurate and timely, reporting and documentation, archiving, and performance review. 相似文献
18.
Valeria Mattiangeli Anthony W. Ryan Paul Galvin Jarle Mork & Thomas F. Cross 《Marine Ecology》2003,24(4):247-258
Abstract. Nine allozyme and two minisatellite loci were used to investigate potential genetic differentiation among three samples of Mediterranean poor cod, Trisopterus minutus capelanus, from the Gulf of Lion, the Tuscan Archipelago and the Aegean Sea. Both types of markers showed consistent results, with FST values of 0.0262 and 0.0296 (P < 0.0015, after Bonferroni correction for multiple tests) for allozymes and minisatellites, respectively. Allele frequency heterogeneity tests between pairs of samples showed a clear separation between the two western Mediterranean samples (Gulf of Lion, Tuscan Archipelago) and the eastern one (Aegean Sea). The results indicate that at least two reproductively isolated populations of poor cod occur in the Mediterranean. 相似文献
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20.
C. Rabouille H. Stahl F. Bassinot A. Tengberg J. Brunnegard P. Hall K. Kiriakoulakis J. -L. Reyss L. Dezileau P. Crassous P. Roos R. S. Lampitt 《Progress in Oceanography》2001,50(1-4)
Fluxes contributing to the particulate carbonate system in deep-sea sediments were investigated at the BENGAL site in the Porcupine Abyssal Plain (Northeast Atlantic). Deposition fluxes were estimated using sediment traps at a nominal depth of 3000 m and amounted to 0.37±0.1 mmol C m−2 d−1. Dissolution of carbonate was determined using flux of total alkalinity from in situ benthic chambers, is 0.4±0.1 mmol C m−2 d−1. Burial of carbonate was calculated from data on the carbonate content of the sediment and sedimentation rates from a model age based on 14C dating on foraminifera (0.66±0.1 mmol C m−2 d−1). Burial plus dissolution was three times larger than particle deposition flux which indicates that steady-state is not achieved in these sediments. Mass balances for other components (BSi, 210Pb), and calculations of the focusing factor using 230Th, show that lateral inputs play only a minor role in this imbalance. Decadal variations of annual particle fluxes are also within the uncertainty of our average. Long-term change in dissolution may contribute to the imbalance, but can not be the main reason because burial alone is greater than the input flux. The observed imbalance is thus the consequence of a large change of carbonate input flux which has occured in the recent past. A box model is used to check the response time of the solid carbonate system in these sediments and the time to reach a new steady-state is in the order of 3 kyr. Thus it is likely that the system has been perturbed recently and that large dissolution and burial rates reflect the previously larger particulate carbonate deposition rates. We estimate that particulate carbonate fluxes have certainly decreased by a factor of at least 3 and that this change has occurred during the last few centuries. 相似文献