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991.
Mikael?PedersenEmail author Jesper?K.?Nielsen Adrian?J.?Boyce Anthony?E.?Fallick 《Mineralium Deposita》2003,38(1):108-123
Bituminous mud shales of the Upper Permian Ravnefjeld Formation (Zechstein 1 equivalent) are mineralised with zinc, lead and copper within a ca. 50 km2 area on Wegener Halvø in central East Greenland. The occurrence of base-metal sulphides in shale nodules cemented prior to compaction indicates an early commencement of base-metal mineralisation. In other cases, post-compactional sulphide textures are observed. Homogeneous lead isotope signatures of galena and sphalerite from the shales (206Pb/204Pb: 18.440–18.466; 207Pb/204Pb: 16.554–16.586; 208Pb/204Pb: 38.240–38.326) suggest that all base metals were introduced during a single hydrothermal event. Therefore, post-compactional textures are believed to result from recrystallisation of early diagenetic sulphides during deep burial in the Upper Cretaceous to Tertiary. Lead isotope signatures of galena hosted in Upper Permian carbonate build-ups are relatively heterogeneous compared to those of the shale-hosted sulphides. The observed relations indicate a shared lead source for the two types of mineralisation, but different degrees of homogenisation during mineralisation. This suggests that lead was introduced to the carbonate rocks and black shales during two separate events. δ34S of base-metal sulphides in the Ravnefjeld Formation lie between –12 and –4‰, whereas synsedimentary and early diagenetic pyrite in unmineralised shales in general have δ34S between –47 and –16.5‰. Early diagenetic pyrite in the Wegener Halvø area in general has δ34S 15 to 20‰ higher than the same pyrite morphotype in Triaselv in the western part of the basin. This relatively high δ34S can be explained by extensive microbial sulphate reduction within persistent euxinic (super-anoxic) bottom waters under which supply of isotopically light seawater sulphate (and disproportionation of intermediate sulphur compounds) was restricted. The sulphur in the base-metal sulphides is believed to represent sulphide-dominated pore water, enriched in 34S due to preferential removal of 32S by sulphate-reducing bacteria and precipitation of diagenetic pyrite in the near-seafloor environment. We suggest that the sulphide-dominated pore water was trapped in the shale formation prior to introduction of base-metal-bearing fluids through fractures in the underlying carbonates, and that sulphide precipitation took place when the two fluids met. δ34S values of carbonate-hosted base-metal sulphides fall within the same range as the shale-hosted ones. The relationship between barite and sulphides and evidence for pre-mineralisation entrapment of liquid hydrocarbons in the carbonates suggest that the sulphide in this case is derived by in-situ thermochemical sulphate reduction (TSR). Measured fractionation between sulphide and sulphate ranges from 18.5 to 24.4‰, suggesting temperatures of TSR around 70 to 100 °C. Vitrinite reflectance measurements in mineralised shale samples are all between 1.7 and 2.0%, except for samples taken close to a Tertiary dyke giving ca. 3.0%. Vitrinite reflectance data are comparable to previously published data from unmineralised shale samples in the area and could not be proven to correlate with the degree of mineralisation. This indicates that any early hydrothermal effect has been overprinted later, probably during deep burial in the Late Cretaceous to Early Tertiary as previously proposed. 相似文献
992.
Anthony M. Filippi 《The Professional geographer》2007,59(2):236-255
Bathymetry is an important variable in scientific and operational applications. The research objectives in this study were to estimate bathymetry based on derivative reflectance spectra used as input to a multilayer perceptron artificial neural network (ANN) and to evaluate the efficacy of field and simulated training/testing data. ANNs were used to invert reflectance field data acquired in optically shallow coastal waters. Results indicate that for the simulation‐based models, nonderivative spectra yielded more accurate bathymetry retrievals than the derivative spectra used as ANN input. However, for the empirical field‐based models, derivative spectra were superior to nonderivative spectra as ANN input. This study identifies circumstances under which derivative spectra are useful in bathymetry estimation, and thus increases the likelihood of obtaining accurate inversions. 相似文献
993.
A procedure for numerical approximation to two-dimensional, hydraulically-driven fracture propagation in a poroelastic material is described. The method uses a partitioned solution procedurè to solve a finite element approximation to problems described by the theory of poroelasticity, in conjunction with a finite difference approximation for modelling fluid flow along the fracture. An equilibrium fracture model based on a generalized, Dugdale–Barenblatt concept is used to determine the fracture dimensions. An important feature is that the fracture length is a natural product of the solution algorithm. Two example problems verify the accuracy of the numerical procedure and a third example illustrates a fully-coupled simulation of fracture propagation. Photographs taken from a high-performance engineering workstation provide insight into the nature of the coupling among the physical phenomena. 相似文献
994.
Artificial neural networks (ANNs) were developed for accurately predicting potentiometric surface elevations (monitoring well water level elevations) in a semiconfined glacial sand and gravel aquifer under variable state, pumping extraction, and climate conditions. ANNs "learn" the system behavior of interest by processing representative data patterns through a mathematical structure analogous to the human brain. In this study, the ANNs used the initial water level measurements, production well extractions, and climate conditions to predict the final water level elevations 30 d into the future at two monitoring wells. A sensitivity analysis was conducted with the ANNs that quantified the importance of the various input predictor variables on final water level elevations. Unlike traditional physical-based models, ANNs do not require explicit characterization of the physical system and related physical data. Accordingly, ANN predictions were made on the basis of more easily quantifiable, measured variables, rather than physical model input parameters and conditions. This study demonstrates that ANNs can provide both excellent prediction capability and valuable sensitivity analyses, which can result in more appropriate ground water management strategies. 相似文献
995.
Peter Koděra Jaroslav Lexa Andrew Hugh Rankin Anthony Edward Fallick 《Mineralium Deposita》2005,39(8):921-943
The central zone of the large Miocene tiavnica stratovolcano in the Western Carpathians hosts epithermal Au mineralization of intermediate-sulfidation type, located at deep levels of the historic Rozália base-metal mine at Banská Hodrua. The Au mineralization occurs as subhorizontal veins at the base of pre-caldera andesites, close to the roof of a subvolcanic granodiorite intrusion. The veins are dismembered by a set of quartz–diorite porphyry sills and displaced by the younger, steeply dipping, Rozália base-metal vein, and parallel structures. The base-metal vein structures are related to resurgent horst uplift in the caldera center. The Au mineralization formed during two stages. Based on fluid inclusion evidence, both stages formed from fluids of low salinity (0–3 wt% NaCl eq.), which underwent extensive boiling at moderate temperatures (280–330°C). Variable pressure conditions (39–95 bars, neglecting the effect of CO2) indicate continual opening of the system and a transition from suprahydrostatic towards hydrodynamic conditions at shallow depths (~550 m). The fluid inclusions of the Rozália base-metal vein show homogenization temperature peaks at ~285 and 187°C and salinities between 1 and 4 wt% NaCl eq. Precipitation of Au is considered to be the result of prolonged boiling of fluids and associated decrease in Au solubility. Oxygen and hydrogen isotope data for quartz and carbonate from the Au veins show a relatively homogeneous fluid composition (–2.7 to 1.118O, –78 to –62D). The combined 18Ofluid and Dfluid values suggest a mixed character of fluids, falling between the fields of typical magmatic and meteoric water influenced by 18Ofluid shift due to fluid–rock isotopic exchange. End stages of open-system boiling and fractionation could have been reached, at least locally. Significantly lower isotopic composition of meteoric fluids associated with Au mineralization compared to those associated with the intrusion-related mineralizations could have resulted from changing paleoclimate and/or analytical problems of extraction of water from fluid inclusions. The proposed genetic model for the Au deposit at Rozália mine highlights the importance of hydrothermal activity during the early stage of caldera collapse. Caldera subsidence established new, convective, fluid-flow paths along marginal caldera faults, which acted as infiltration zones. Major metal precipitation occurred within subhorizontal structures that formed as the result of a collapse-related stress field. A shallow, differentiated magma chamber at the base of the volcano was the likely source of heat and magmatic components for the mineralizing fluids.Editorial handling: S. Nicolescu 相似文献
996.
Orpin AR Ridd PV Thomas S Anthony KR Marshall P Oliver J 《Marine pollution bulletin》2004,49(7-8):602-612
Coastal development activities can cause local increases in turbidity and sedimentation. This study characterises the spatial and temporal variability of turbidity near an inshore fringing coral reef in the central Great Barrier Reef, under a wide range of natural conditions. Based on the observed natural variability, we outline a risk management scheme to minimise the impact of construction-related turbidity increases. Comparison of control and impact sites proved unusable for real-time management of turbidity risks. Instead, we suggest using one standard deviation from ambient conditions as a possible conservative upper limit of an acceptable projected increase in turbidity. In addition, the use of regional weather forecast as a proxy for natural turbidity is assessed. This approach is simple and cheap but also has limitations in very rough conditions, when an anthropogenic turbidity increase could prove fatal to corals that are already stressed under natural conditions. 相似文献
997.
Anthony Finizola Jean-Franois Lnat Orlando Macedo Domingo Ramos Jean-Claude Thouret Francesco Sortino 《Journal of Volcanology and Geothermal Research》2004,135(4):216
One of the seven potentially active andesite stratovolcanoes in southern Peru, Misti (5822 m), located 17 km northeast and 3.5 km above Arequipa, represents a major threat to the population (900,000 inhabitants). Our recent geophysical and geochemical research comprises an extensive self-potential (SP) data set, an audio–magnetotelluric (AMT) profile across the volcano and CO2 concentrations in the soil along a radial profile. The SP survey is the first of its kind in providing a complete mapping of a large andesitic stratovolcano 20 km in diameter. The SP mapping enables us to analyze the SP signature associated with a subduction-related active volcano.The general SP pattern of Misti is similar to that of most volcanoes with a hydrogeologic zone in the lower flanks and a hydrothermal zone in the upper central area. A quasi-systematic relationship exists between SP and elevation. Zones with constant SP/altitude gradients (Ce) are observed in both hydrogeologic (negative Ce) and hydrothermal (positive Ce) zones. Transition zones between the different Ce zones, which form a concentric pattern around the summit, have been interpreted in terms of lateral heterogeneities in the lithology. The highest amplitudes of SP anomalies seem to coincide with highly resistive zones. The hydrothermal system 6 km in diameter, which extends over an area much larger than the summit caldera, may be constrained by an older, concealed collapse caldera. A sealed zone has apparently developed through alteration in the hydrothermal system, blocking the migration of CO2 upward. Significant CO2 emanations are thus observed on the lower flanks but are absent above the hydrothermal zone. 相似文献
998.
Hennebelle Patrick Belloche Arnaud Whitworth Anthony André Philippe 《Astrophysics and Space Science》2004,292(1-4):355-360
We present numerical simulations of the evolution of low-mass, isothermal, molecular cores which are subjected to an increase in external pressure. If the external pressure increases very slowly, the core approaches instability quite quasi-statically. However, for faster compressions, a compression wave is driven into the core (Hennebelle, P., Whitworth, A., Gladwin, P. and André, P.: 2003a MNRAS 340, 870). Quantitative comparisons with observational velocity and density profiles are presented. The consequences of this compression for the fragmentation of the cloud is investigated and discussed. 相似文献
999.
1000.
The network of interrelationships among a set of 22 geographic journals is investigated, using data on the frequency with which articles published in one journal cite papers published In another. The analysis considers journals published in 1970–1972 and 1980–1982. Journals with a focus on regional science weaken their connection to others in the set. The Annals retains its position at the core of the journal space that is identified using multidimensional scaling; Environment and Planning A invades the niche vacated by the regional science journals. 相似文献