Inferring salinity from temperature or depth for dynamic height computations in the north pacific

Abstract

A computational method is developed where salinities inferred from mean salinity profiles (computed from all available data) are used to calculate 0/500 db dynamic height from temperature profiles. Using data from Ocean Weather Station P (50°N, 145°W), the method yielded a much smaller uncertainty in inferred 0/500 db dynamic height (～3 dyn cm) than that found using a mean temperature‐salinity relationship (～10 dyn cm). Applied to historical hydrographic data averaged over 5° squares in the North Pacific (north of 30°N), the method led to inferred dynamic‐height uncertainties typically less than 4 dyn cm in the region north of the Subarctic Front (～40°N). In this same region, dynamic heights inferred from mean temperature‐salinity curves had large uncertainties. South of the Subarctic Front, the dynamic‐height uncertainties associated with the temperature‐salinity curves were smaller than those computed with the mean salinity profiles. A combination of these two methods was used to compute inferred dynamic height from a climatology of temperature structure in the region from 30–50°N, 130°W‐150°E.     

Industrial decentralisation in South Africa: tool of Apartheid or spontaneous restructuring?

Industrial decentralisation (ID) has been a central component of South Africa's regional strategy for over twenty years. Until recently, though, the programme has evinced little interest amongst industrialists. The fact that ID policy has been premised upon political rather than economic considerations has been thought to lie at the root of this failure. Following recent developments, however, this view is being reassessed. The reorganisation of ID policy in 1982 and the dramatic acceleration in the rate of industrial relocations that this reorganisation appears to have induced, has led theorists to revise their thinking on both the economic and political imperatives underpinning the programme. The purpose of this paper is to review the debates that are now developing concerning ID in South Africa, and to suggest where further research and analysis might be most profitably directed.     

Assessment of textural variational pattern and electrical conduction of economic and accessible Quaternary hydrolithofacies via geoelectric and laboratory methods in SE Nigeria: A case study of select locations in Akwa Ibom State

Textural variational pattern of economic and accessible Quaternary aquifer repositories and its conductivity in the south-eastern Nigeria have been assessed through the integration of vertical electrical sounding and laboratory measurements. The results have shown the lithological attributes, pore-water and amount of residual clay minerals in the assumed clean sand; mechanism of charge fixation at the fluid - surface interface; intricate geometry of pores and pore channels; formation’s ability to transmit pore-water and cation exchange capacity.The connections of electrical and hydraulic properties and their distributions have been established. The average interface conductivity contributed by residual clay minerals in assumed clean sands of the aquifer repositories in the study area have been estimated as 30µS/m. Intrinsic average porosity and formation factor have been respectively deduced as 12% and 14.75. Comparing the simulated aquifer formation factor obtained from the observed porosity data with the observed aquifer formation factor, indicates the that study area has 0.5 ≤ a ≤ 0.8 pore geometry factor and 1.5 ≤ m ≤ 2.0 cementation factor as the best fitting values. The interrelations between aquifer parameters have been established through different plots and the aquifer have been empirically proved to be associated with residual clay minerals as the interface conductivity C_q is not equal to zero. The wide ranges of parameters estimated are an indication of variations in grain size. The estimated intrinsic average porosity, formation factor and the average BQ_v are viable in characterizing the aquifer flow dynamics and contaminant modelling in the associated aquifer sands For low pore geometry factors a (0.2) and low cementation factor m (0.5) the formation factor remains fairly constant. However, marked variability is noticed at higher a (1.0) and m (2.5). Despite the observed variability in formation factors at the indicated porosities, the spatial or geometrical spread of the formation factor remains unchanged in the aquifer units. The Tables for geoelectric and petrophysical parameters and the associated mathematical models generated in this study can be used for groundwater contaminant modelling and simulation of pore space parameters with reasonable accuracy.     

Groundwater flux as a determinant of coastal-zone upland loss: a case study from the Pennsylvania coast of Lake Erie,USA

Climate change in the Great Lakes Basin of North America over the next several decades is projected to lead to significant changes to coastal environments. Groundwater-driven coastal bluff recession should increase in areas where groundwater forcing is important and lead to increased loss of coastal uplands. The latter is an issue in NW Pennsylvania because of coastal development pressures, and because the state ranks within the top five US states in grape production, most of which occurs within 5 km of the Lake Erie coastline. In 2007, viticulture contributed almost $2.4 billion to the state economy. An analysis of a 20-km stretch of coast shows that bluff retreat is pervasive and variable under current climatic conditions. Over a 9-year time frame, bluff change rates ranged from ?4.2 to +0.98 m/year. In general, higher retreat rates (?0.2 to ?0.65 m/year) occurred along the sandy central beach–ridge sector which lacks significant surface drainage. Lower retreat rates (?0.10 to ?0.25 m/year) occurred along coastal sectors where surface drainage networks are well developed. Conservative estimates of groundwater discharge at the bluff correlate strongly (r = 0.74, p < 0.001) with bluff retreat rate. Groundwater is inferred to be the principal driving mechanism for both bluff retreat and spatial variability in retreat rates on this coast. Other common factors that may spatially influence bluff retreat elsewhere (bluff height, land use, beach width) do not correlate strongly with retreat rate.     

Seismic motion and response prediction alternatives

Statistical methods are available which predict the maximum response of simple oscillators given the peak acceleration (A_p), peak velocity (V_p) or peak displacement (D_p) of seismic ground motions. An alternative parameter, namely an ordinate (or ordinates) of the Fourier amplitude spectrum of ground motion acceleration, FS(f), may in fact be a preferred predictor of peak response, especially in a frequency range close to f. Other statistical methods (attenuation laws) use distance R and other parameters such as magnitude (M), Modified Mercalli epicentral Intensity (I_o) and Modified Mercalli site Intensity (MMI or I_s) to predict spectral velocity (S_v(f)), etc. In using such approaches, it is most desirable to know the total uncertainty in the predicted peak response of the system given the starting parameter values. An extensive strong motion data set is used to study these questions, The most direct prediction models are found to be preferable (have lower prediction dispersion) but data may not be available in all regions to permit their use.     

A geochemical approach to constraining the formation of glassy fallout debris from nuclear tests

Glassy nuclear fallout debris from near-surface nuclear tests is fundamentally reprocessed earth material. A geochemical approach to analysis of glassy fallout is uniquely suited to determine the means of reprocessing and shed light on the mechanisms of fallout formation. An improved understanding of fallout formation is of interest both for its potential to guide post-detonation nuclear forensic investigations and in the context of possible affinities between glassy debris and other glasses generated by high-energy natural events, such as meteorite impacts and lightning strikes. This study presents a large major-element compositional dataset for glasses within aerodynamic fallout from the Trinity nuclear test (“trinitite”) and a geochemically based analysis of the glass compositional trends. Silica-rich and alkali-rich trinitite glasses show compositions and textures consistent with formation through melting of individual mineral grains—quartz and alkali feldspar, respectively—from the test-site sediment. The volumetrically dominant glass phase—called the CaMgFe glass—shows extreme major-element compositional variability. Compositional trends in the CaMgFe glass are most consistent with formation through volatility-controlled condensation from compositionally heterogeneous plasma. Radioactivity occurs only in CaMgFe glass, indicating that co-condensation of evaporated bulk ground material and trace device material was the main mechanism of radioisotope incorporation into trinitite. CaMgFe trinitite glasses overlap compositionally with basalts, rhyolites, fulgurites, tektites, and microtektites but display greater compositional diversity than all of these naturally formed glasses. Indeed, the most refractory CaMgFe glasses compositionally resemble early solar system condensates—specifically, CAIs.     

Elemental and mineralogical changes in soils due to bioturbation along an earthworm invasion chronosequence in Northern Minnesota

Minnesota forested soils have evolved without the presence of earthworms since the last glacial retreat. When exotic earthworms arrive, enhanced soil bioturbation often results in dramatic morphological and chemical changes in soils with negative implications for the forests’ sustainability. However, the impacts of earthworm invasion on geochemical processes in soils are not well understood. This study attempts to quantify the role of earthworm invasion in mineral chemical weathering and nutrient dynamics along an earthworm invasion chronosequence in a sugar maple forest in Northern Minnesota. Depth and rates of soil mixing can be tracked with atmospherically derived short lived radioisotopes ²¹⁰Pb and ¹³⁷Cs. Their radioactivities increase in the lower A horizon at the expense of the peak activities near the soil surface, which indicate that soil mixing rate and its depth reach have been enhanced by earthworms. Enhanced soil mixing by earthworms is consistent with the ways that the vertical profiles of elemental and mineralogical compositions were affected by earthworm invasion. Biologically cycled Ca and P have peak concentrations near the soil surface prior to earthworm invasion. However, these peak abundances significantly declined in the earthworm invaded soils presumably due to enhanced soil mixing. It is clear that enhanced soil mixing due to earthworms also profoundly altered the vertical distribution of most mineral species within A horizons. Though the mechanisms are not clear yet, earthworm invasion appears to have contributed to net losses of clay mineral species and opal from the A horizons. As much as earthworms vertically relocated minerals and elements, they also intensify the contacts between organic matter and cations as shown in the increased amount of Ca and Fe in organically complexed and in exchangeable pools. With future studies on soil mixing rates and elemental leaching, this study will quantitatively and mechanically address the role of earthworms in geochemical evolution of soils and forests’ nutrient dynamics.     

Field investigation of deformation characteristics and stress mobilisation of a soil slope

Stress mobilisation and deformation of a slope are important for engineers to carry out reliable design of retaining systems. However, most case histories reported mainly on the response of pore water pressure (PWP), whereas knowledge about the stress deformation characteristics of slope is limited. In this study, a saprolitic soil slope was instrumented to monitor not only the responses of PWP but also horizontal stress and horizontal displacement. To assist in the interpretation of field data, a series of laboratory tests was conducted to characterise volume change behaviour of the soil taken from the site, under the effects of both net stress and suction. During a rainstorm event when positive PWP built up, a remarkably large displacement of 20 mm was recorded between 5.5- and 6-m depths, and the top 5 m of the slope exhibited translational downslope movement. This caused an increase in Bishop’s effective horizontal stress by 350 %, which reached a peak value close to 40 % of a Bishop’s effective passive stress. During the subsequent dry season when suction was recovered, an upslope rebound of 10 mm was recorded. Comparison of field and laboratory data reveals that the rebound was attributed to suction-induced soil shrinkage. This rebound led to a decrease in the Bishop’s effective horizontal stress previously built up during the storm event.     

Surficial geophysical deduction of the geomaterial and aquifer distributions at Ngor-Okpala local government area of Imo State, South Eastern Nigeria

Twenty seven vertical electrical sounding (VES) profiles surrounding four known traverses were obtained in Ngor-Okpala local government area of Imo state to examine the subsurface geomaterials and the associated groundwater potential. The VES data, constrained by borehole data, provided useful information about the subsurface hydrogeologic and lithologic conditions. From the validated interpretation, the area assessed has loamy soil, medium grained sands, well-sorted medium-grained/gravelly sands and river sand as the lithologic succession from top to the bottom of the depth penetrated. The aquifers in the area were found in the medium-grained sands and well-sorted medium-coarse-grained sands. The aquifer depth for all-season groundwater that would be devoid of draw-down can be found at a depth range of 42–50 m. The resistivity maps of selected depths exhibit sharp resistivity changes at depth due mainly to undulating subsurface topography. A map of the distribution of the kσ-values shows that good quality groundwater can be found in most parts of the area.     

Ferrihydrite dissolution by pyridine-2,6-bis(monothiocarboxylic acid) and hydrolysis products

Pyridine-2,6-bis(monothiocarboxylate) (pdtc), a metabolic product of microorganisms, including Pseudomonas putida and Pseudomonas stutzeri was investigated for its ability of dissolve Fe(III)(hydr)oxides at pH 7.5. Concentration dependent dissolution of ferrihydrite under anaerobic environment showed saturation of the dissolution rate at the higher concentration of pdtc. The surface controlled ferrihydrite dissolution rate was determined to be 1.2 × 10⁻⁶ mol m⁻² h⁻¹. Anaerobic dissolution of ferrihydrite by pyridine-2,6-dicarboxylic acid or dipicolinic acid (dpa), a hydrolysis product of pdtc, was investigated to study the mechanism(s) involved in the pdtc facilitated ferrihydrite dissolution. These studies suggest that pdtc dissolved ferrihydrite using a reduction step, where dpa chelates the Fe reduced by a second hydrolysis product, H₂S. Dpa facilitated dissolution of ferrihydrite showed very small increase in the Fe dissolution when the concentration of external reductant, ascorbate, was doubled, suggesting the surface dynamics being dominated by the interactions between dpa and ferrihydrite. Greater than stoichiometric amounts of Fe were mobilized during dpa dissolution of ferrihydrite assisted by ascorbate and cysteine. This is attributed to the catalytic dissolution of Fe(III)(hydr)oxides by the in situ generated Fe(II) in the presence of a complex former, dpa.