西龙池上水库GPS变形监测系统研究及实现

为了实现对西龙池上水库变形的连续、自动化监测,研制了GPS变形监测软件DDMS,建立了西龙池上水库连续运行监测系统。1a的运行表明,系统具有较高的稳定性,DDMS在观测数据无缺失的情况下,提供有效解的概率高于98%。该软件2h时段解在N、E、U方向的重复性分别为1.2mm、0.9mm、2.2mm,4h时段解算N、E、U方向的重复性为0.8mm、0.7mm、1.5mm。利用本文实现的GPS监测系统可进行高效率的实时、自动化、高精度大坝变形监测。     

Spectroscopic studies of synthetic and natural ringwoodite, γ-(Mg,Fe)<Subscript>2</Subscript>SiO<Subscript>4</Subscript>

Synthetic ringwoodite γ-(Mg_1?x Fe _x )₂SiO₄ of 0.4 ≤ x ≤ 1.0 compositions and variously colored micro-grains of natural ringwoodite in shock metamorphism veins of thin sections of two S6-type chondrites were studied by means of microprobe analysis, TEM and optical absorption spectroscopy. Three synthetic samples were studied in addition with Mössbauer spectroscopy. The Mössbauer spectra consist of two doublets caused by ^VIFe²⁺ and ^VIFe³⁺, with IS and QS parameters close to those established elsewhere (e.g., O’Neill et al. in Am Mineral 78:456–460, 1993). The Fe³⁺/Fe_total ratio evaluated by curve resolution of the spectra, ranges from 0.04 to 0.1. Optical absorption spectra of all synthetic samples studied are qualitatively very similar as they are directly related to the iron content. They differ mostly in the intensity of the observed absorption features. The spectra consist of a very strong high-energy absorption edge and a series of absorption bands of different width and intensity. The three strongest and broadest absorptions of them are attributed to splitting of electronic spin-allowed ⁵ T _2g → ⁵ E _g transitions of ^VIFe²⁺ and intervalence charge-transfer (IVCT) transition between ferrous and ferric ions in adjacent octahedral sites of the ringwoodite structure. The spin-allowed bands at ca. 8,000 and 11,500 cm^?1 weakly depend on temperature, whilst the Fe²⁺/Fe³⁺ IVCT band at ~16,400 cm^?1 displays very strong temperature dependence: i.e., with increasing temperature it decreases and practically disappears at about 497 K, a behavior typical for bands of this type. With increasing pressure the absorption edge shifts to lower energies while the spin-allowed bands shift to higher energy and strongly decreases in intensity. The IVCT band also strongly weakens and vanishes at about 9 GPa. We assigned this effect to pressure-induced reduction of Fe³⁺ in ringwoodite. By analogy with synthetic samples three broad bands in spectra of natural (meteoritic) blue ringwoodite are assigned to electronic spin-allowed transitions of ^VIFe²⁺ (the bands at ~8,600 and ~12,700 cm^?1) and Fe²⁺/Fe³⁺ IVCT transition (~18,100 cm^?1), respectively. Spectra of colorless ringwoodite of the same composition consist of a single broad band at ca. 12,000 cm^?1. It is assumed that such ringwoodite grains are inverse (Fe, Mg)₂SiO₄-spinels and that the single band is caused by the split spin-allowed ⁵ E → ⁵ T ₂ transition of ^IVFe²⁺. Ringwoodite of intermediate color variations between dark-blue and colorless are assumed to be partly inversed ringwoodite. No glassy material between the grain boundaries in the natural colored ringwoodite aggregates was found in our samples and disprove the cause of the coloration to be due to light scattering effect (Lingemann and Stöffler in Lunar Planet Sci 29(1308), 1998).     

北斗短基线三频实测数据单历元模糊度固定

基于北斗实测三频数据,通过分析比较选取了三组线性独立的超宽巷组合,采用无几何模式(geometry-free)和几何模式(geometry-based)相结合的方法对其进行单历元模糊度固定,然后恢复各频率上的原始模糊度,最后进行定位解算。实验结果表明,对于短基线,组合系数的合理选取是模糊度成功固定的关键;在选用合适(长波长、弱电离层、低噪声)的组合时,对于静态和动态短基线,其原始载波模糊度单历元固定成功率分别为99.75%和95.08%,从而可以避开传统解算中周跳探测等复杂的数据预处理过程,单历元取得cm级定位精度。     

Initial assessment of the COMPASS/BeiDou-3: new-generation navigation signals

The successful launch of five new-generation experimental satellites of the China’s BeiDou Navigation Satellite System, namely BeiDou I1-S, I2-S, M1-S, M2-S, and M3-S, marks a significant step in expanding BeiDou into a navigation system with global coverage. In addition to B1I (1561.098 MHz) and B3I (1269.520 MHz) signals, the new-generation BeiDou-3 experimental satellites are also capable of transmitting several new navigation signals in space, namely B1C at 1575.42 MHz, B2a at 1176.45 MHz, and B2b at 1207.14 MHz. For the first time, we present an initial characterization and performance assessment for these new-generation BeiDou-3 satellites and their signals. The L1/L2/L5 signals from GPS Block IIF satellites, E1/E5a/E5b signals from Galileo satellites, and B1I/B2I/B3I signals from BeiDou-2 satellites are also evaluated for comparison. The characteristics of the B1C, B1I, B2a, B2b, and B3I signals are evaluated in terms of observed carrier-to-noise density ratio, pseudorange multipath and noise, triple-frequency carrier-phase ionosphere-free and geometry-free combination, and double-differenced carrier-phase and code residuals. The results demonstrate that the observational quality of the new-generation BeiDou-3 signals is comparable to that of GPS L1/L2/L5 and Galileo E1/E5a/E5b signals. However, the analysis of code multipath shows that the elevation-dependent code biases, which have been previously identified to exist in the code observations of the BeiDou-2 satellites, seem to be not obvious for all the available signals of the new-generation BeiDou-3 satellites. This will significantly benefit precise applications that resolve wide-lane ambiguity based on Hatch–Melbourne–Wübbena linear combinations and other applications such as single-frequency precise point positioning (PPP) based on the ionosphere-free code–carrier combinations. Furthermore, with regard to the triple-frequency carrier-phase ionosphere-free and geometry-free combination, it is found that different from the BeiDou-2 and GPS Block IIF satellites, no apparent bias variations could be observed in all the new-generation BeiDou-3 experimental satellites, which shows a good consistency of the new-generation BeiDou-3 signals. The absence of such triple-frequency biases simplifies the potential processing of multi-frequency PPP using observations from the new-generation BeiDou-3 satellites. Finally, the precise relative positioning results indicate that the additional observations from the new-generation BeiDou-3 satellites can improve ambiguity resolution performance with respect to BeiDou-2 only positioning, which indicates that observations from the new-generation BeiDou-3 satellites can contribute to precise relative positioning.     

附有长度约束的模糊度解算方法比较

整周模糊度解算方法的合理选择是GNSS定向处理中的关键问题,针对此问题,该文对GNSS定向中的LAMBDA_C和CLAMBDA两种附有基线长约束的模糊度固定方法的性能进行了详细的对比分析。结果显示,相对于经典的基于Ratio检验的LAMBDA算法,LAMBDA_C和CLAMBDA均可提高模糊度固定率和正确率,尤其是在单频单系统下提高效果更为显著;CLAMBD的总体固定效果略优于LAMBDA_C,但后者的解算效率更高。     

非完整约束的OD/SINS自适应组合导航方法

在地面车载组合导航GNSS/OD/SINS中,全球导航卫星系统（GNSS）信号容易受到环境的干扰甚至发生中断,将非完整性约束（NHC）应用于里程计（OD）/捷联惯性导航系统（SINS）组合,可以有效抑制GNSS信号中断期间组合导航系统的误差发散。通常NHC的噪声设定基于固定的经验值,然而在实际运动过程中,车辆运行轨迹复杂多变,其运动状态不能完全满足NHC前提假设,经验给定的噪声无法准确反映车辆实际运动情况。为此,本文分析了NHC噪声与车辆运动状态的关系,构建了一种基于车辆运动状态的NHC噪声自适应方法。通过所选场景的实测数据验证表明：采用噪声自适应的NHC/OD/SINS组合导航结果相比于固定噪声的NHC/OD/SINS组合,在GNSS信号中断110 s、车辆连续转弯的情况下,最大水平位置误差减小了68.4%;在GNSS信号中断74 s、车辆直线行驶的情况下,最大水平位置误差减小了87.3%;能较好地抑制GNSS中断期间组合导航系统的误差发散。     

Leaf wax n-alkane δD values of field-grown barley reflect leaf water δD values at the time of leaf formation

Leaf wax n-alkanes from barley (Hordeum vulgare) from a field in Switzerland exhibited changes in δD values on the order of 20‰ over a growing season, while source water (soil water) and leaf water varied by 40‰. Additionally the seasonal variability in δD values of leaf wax n-alkanes of different barley leaves can only be found across different leaf generations (i.e. leaves that were produced at different times during the growing season) while n-alkane δD values did not vary significantly within a leaf generation. Interestingly, δD values of n-alkanes correlated best with the δD values of leaf water at midday of the sampling day but showed no significant correlation with soil water (e.g. precipitation) δD values. These results provide empirical evidence that leaf wax δD values record leaf water enrichment, and therefore integrate the isotopic effects of precipitation and evapotranspiration. Our results show that leaf wax n-alkane δD values from grasses are ‘locked in’ early during leaf development and hence record the environmental drivers of leaf water enrichment, such as vapor pressure deficit (VPD). Our data have important implications for the interpretation of paleorecords of leaf wax δD. We suggest that leaf wax n-alkane δD values from sedimentary records could be used to estimate changes in the degree of leaf water enrichment and hence VPD.     

用星载单频GPS数据实时定轨的电离层延迟改正

对"电离层比例因子法"进行改进,并利用CHAMP低轨卫星在不同太阳活动情况和不同轨道高度条件下的观测数据进行验算,计算结果表明改正后的"电离层比例因子法"具有很好的通用性和有效性.     

Significant seasonal variation in the hydrogen isotopic composition of leaf-wax lipids for two deciduous tree ecosystems (Fagus sylvativa and Acerpseudoplatanus)

Compound specific hydrogen isotope ratios (δD) of long chain sedimentary n-alkanes, which mostly originate from the leaf waxes of higher terrestrial plants, are increasingly employed as paleoclimate proxies. While soil water is the ultimate hydrogen source for these lipids and the isotopic fractionation during biosynthesis of lipids is thought to remain constant, environmental parameters and plant physiological processes can alter the apparent hydrogen isotopic fractionation between leaf-wax lipids and a plant’s source water. However, the magnitude and timing of these effects and their influence on the isotopic composition of lipids from higher terrestrial plants are still not well understood. Therefore we investigated the seasonal variability of leaf-wax n-alkane δD values for two different temperate deciduous forest ecosystems that are dominated by two different tree species, Beech (Fagus sylvatica) and Maple (Acerpseudoplatanus).We found significant seasonal variations for both tree species in n-alkane δD values of up to 40‰ on timescales as short as one week. Also, the isotopic difference between different n-alkanes from the same plant species did vary significantly and reached up to 50‰ at the same time when overall n-alkane concentrations were lowest.Since δD values of soil water at 5 and 10 cm depth, which we assume represent the δD value of the major water source for the investigated beech trees, were enriched in autumn compared to the spring by 30‰, whereas n-alkane δD values increased only by 10‰, we observed variations in the apparent fractionation between beech leaf derived n-alkanes and soil water of up to 20‰ on a seasonal scale. This observed change in the apparent fractionation was likely caused by differences in leaf water isotopic enrichment. Based on mechanistic leaf water models we conclude that changes in the isotopic difference between water vapor and soil water were the most likely reason for the observed changes in the apparent fractionation between n-alkanes and soil water.The large variability of n-alkane concentrations and δD values over time implies a continuous de novo synthesis of these compounds over the growing season with turnover times possibly as short as weeks. The signal to reach the soil therefore represents an integrated record of the last weeks before leaf senescence. This holds true also for the sedimentary record of small catchment lakes in humid, temperate climates, where wind transport of leaf-wax lipids is negligible compared to transfer through soil and the massive input of leaves directly into the lake in autumn.     

Die gaschromatographische Bestimmung von Diethylentriaminpentaessigsäure in Oberflächenwasser

Gaschromatographic Determination of Diethylenetriaminepentaacetic Acid in Surface Water. A method for the determination of diethylenetriaminepentaacetic acid (DTPA) is reported. The determination is based on the preconcentration on a strong base anion exchange resin, esterification with n-propanol and following gaschromatographic separation using a N-selective detector. The sensitivity of the method, including enrichment, is 1 μg/L in river water. The identity of DTPA in river water was proved by mass spectrography. The method can be used also for the quantitative determination of nitrilotriacetic acid (NTA), ethylenediaminetetraacetic acid (EDTA), cyclohexanediaminetetraacetic acid (CDTA) and ethyleneglycolbis-(2-aminoethylether)-N,N,N′,N′-tetraacetic acid (EGTA). The method was used to examine river water. An investigation along the river Rhine, taking grab samples from January and february 1992 showed that DTPA was present in some sampling places in similiar concentrations as NTA and EDTA.