Global tectonics and the geoid

A digitised tectonic model, initially built up for regionalization of Rayleigh waves, is applied to the geoid in order to define the mean geoid heights of the following regions: 3 oceanic regions, namely young oceans (0–30 Ma) middle-aged oceans (30–80 Ma) and old oceans (> 80 Ma); trenches and subduction zones; mountains; and shields. The relative importance of the deep sources is damped or enhanced by progressively removing or adding the lower or higher degrees of the geoid. A statistical approach allows us to quantify the success of the correlation between tectonics and these filtered geoids.Significant variations are observed in these correlations for oceanic regions (including subduction zones) with a cut-off between degree-2 and higher degrees. For degrees ? 3, a well-known trend is observed: high values correspond to young oceans (ridges) and low values to old oceans, high values are also obtained for subduction zones. On the contrary, and unexpectedly, for the degree-2 alone a trend reversal is observed: geoid lows are observed over ridges and geoid highs over old oceans; trenches give the same geoid amplitude than old oceans. Clearly this denotes a degree-2 convection pattern connected to plate tectonics. In addition it is shown that the minimum and maximum inertia axes of the surface distribution of young oceans, and independently of old oceans and trenches, coincide with the Earth's equatorial inertia axes (74°E and 164°E), i.e., with the equatorial extremes of the degree-2 geoid.Plate tectonics is uncorrelated with the polar anomaly of the degree-2 geoid, namely the flattening which is not accounted for by Earth rotation. A north-south axisymmetric convection with a degree-2 pattern is proposed to explain this extra flattening; this model is supported by the latitude dependence of the depth of oceanic ridges.     

The Pb-Sr-Nd isotope geochemistry of some recent circum-Mediterranean granites

Pb, Sr and Nd isotopic compositions have been analyzed in recent granites from Northern Africa, Northern Italy and Greece. Lead isotope compositions of K-feldspars are rather homogeneous, and cluster close to the modern lead of Stacey and Kramers (1975) but with slightly higher²⁰⁷Pb/²⁰⁴Pb and²⁰⁸Pb/²⁰⁴Pb ratios. The Cyclades samples, however, have higher²⁰⁶Pb/²⁰⁴Pb ratios. Addition of mantle-derived lead was probably very limited, which supports a quasi-closed system evolution of this element in the continental crust. The Sr, Nd data fall in the enriched part of the¹⁴³Nd/¹⁴⁴Nd vs.⁸⁷Sr/⁸⁶Sr diagram and define a smooth hyperbolic mixing curve. Over a wide area, straddling different orogens, most granites may be accounted for by a binary mixture between a recycled crustal component and a depleted mantle-like component. No correlation is observed between either Pb and Sr or Nd isotopic ratios, or any isotopic ratio and major element contents. Quantitative modelling suggests that two cases fit the Sr and Nd characteristics of these granites: they both require anatexis of the crust on a scale large enough to average the isotopic properties of heterogeneous terranes. In the first case, the mantle-derived component may be represented by differentiated Island Arc-type magmas, and the granites result from mixing these magmas with anatectic melts. In the second case, mantle-derived igneous rocks, such as obducted ophiolites, are part of the crustal source and their variable involvement in the anatectic process causes isotopic variations.CRPG Contribution n 630.     

Chemical mass balance of calcrete genesis on the Toledo granite (Spain)

The chemical mass balance of calcrete genesis is studied on a typical sequence developed in granite, in the Toledo mountains, Central Spain.

Field evidence and petrographic observations indicate that the texture and the bulk volume of the parent rock are strictly preserved all along the studied calcrete profile.

Microscopic observations indicate that the calcitization process starts within the saprolite, superimposed on the usual mechanisms of granite weathering: the fresh rock is first weathered to secondary clays, mainly smectites, which are then pseudomorphically replaced by calcite. Based on this evidence, chemical mass transfers are calculated, assuming iso-volume transformation from the parent rock to the calcrete.

The mass balance results show the increasing loss of matter due to weathering of the primary phases, from the saprolite towards the calcrete layers higher in the sequence. Zr, Ti or Th, which are classically considered as immobile during weathering, are also depleted along the profile, especially in the calcrete layer. This results from the prevailing highly alkaline conditions, which could account for the simultaneous precipitation of CaCO₃ and silicate dissolution.

The calculated budget suggests that the elements exported from the weathering profile are provided dominantly by the weathering of plagioclase and biotite. We calculate that 8–42% of the original Ca remains in granitic relics, while only 15% of the authigenic Ca released by weathering is reincorporated in the calcite. This suggests that 373 kg/m² of calcium (i.e., three times the original amount) is imported into the calcrete from allochtonous sources, probably due to aeolian transport from distant limestone formations.