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51.
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High-pressure crystal structures and compressibilities have been determined by x-ray methods for MgAl2O4 spinel and its isomorph magnetite, Fe3O4. The measured bulk moduli, K, of spinel and magnetite (assuming K′=4) are 1.94±0.06 and 1.86±0.05 Mbar, respectively, in accord with previous ultrasonic determinations. The oxygen u parameter, the only variable atomic position coordinate in the spinel structure (Fd3m, Z=8), decreases with pressure in MgAl2O4, thus indicating that the magnesium tetrahedron is more compressible than the aluminum octahedron. In magnetite the u parameter is unchanged, and both tetrahedron and octahedron display the 1.9 Mbar bulk modulus characteristic of the entire crystal. This behavior contrasts with that of nickel silicate spinel (γ-Ni2SiO4), in which the u parameter increases with pressure because the silicon tetrahedron is relatively incompressible compared to the nickel octahedron.  相似文献   
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This work proposes a complete method for automatic inversion of data from hydraulic interference pumping tests based on both homogeneous and fractal dual-medium approaches. The aim is to seek a new alternative concept able to interpret field data, identify macroscopic hydraulic parameters and therefore enhance the understanding of flow in porous fractured reservoirs. Because of its much contrasted sensitivities to parameters, the dual-medium approach yields an ill-posed inverse problem that requires a specific optimization procedure including the calculation of analytical sensitivities and their possible re-scaling. Once these constraints are fulfilled, the inversion proves accurate, provides unambiguous and reliable results. In the fractal context inverting several drawdown curves from different locations at the same time reveals more accurate. Finally, hydraulic parameters drawn from inversion should be taken into account to improve in various situations the conditioning of up-scaled flow in fractured rocks.  相似文献   
55.
Ingrid Anne Munz   《Lithos》2001,55(1-4):195-212
Fluid dynamics in sedimentary basins is of tremendous interest, both from a scientific and an economic point of view. Integration between fluid inclusion and present-day fluid data provides the time aspect necessary for reconstruction of fluid flow paths, and can be used for mapping fluid dynamics both on a regional basin scale or on the more local scale of petroleum reservoirs. This paper presents a review of analytical and modelling methods for petroleum in fluid inclusions. Essentially, four types of data for petroleum inclusions can be established through analysis and modelling: (1) textures (which give indirect information of the time aspect), (2) fluid composition, (3) fluid properties and (4) pressure–temperature of trapping. During the last decade, development of analytical methods for determination of inclusion fluid compositions has taken place. Traditional correlation studies for characterisation of maturity and source facies may now therefore include fluid inclusion data. The development has also been directed towards an improved understanding of the physical properties of petroleum inclusions. Although these methods are in their early stages concerning precision and accuracy, data necessary for fluid flow modelling, such as fluid densities, viscosities, pressure and temperature, can be estimated.  相似文献   
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Multispectral thermal infrared radiance measurements of the Kupaianaha flow field were acquired with the NASA airborne Thermal Infrared Multispectral Scanner (TIMS) on the morning of 1 October 1988. The TIMS data were used to map both the temperature and emissivity of the surface of the flow field. The temperature map depicted the underground storage and transport of lava. The presence of molten lava in a tube or tumulus resulted in surface temperatures that were at least 10° C above ambient. The temperature map also clearly defined the boundaries of hydrothermal plumes which resulted from the entry of lava into the ocean. The emissivity map revealed the boundaries between individual flow units within the Kupaianaha field. In general, the emissivity of the flows varied systematically with age but the relationship between age and emissivity was not unique. Distinct spectral anomalies, indicative of silica-rich surface materials, were mapped near fumaroles and ocean entry sites. This apparent enrichment in silica may have resulted from an acid-induced leaching of cations from the surfaces of glassy flows. Such incipient alteration may have been the cause for virtually all of the emissivity variations observed on the flow field, the spectral anomalies representing areas where the acid attack was most intense.  相似文献   
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We argue that the temperature of the stellar phase is likely a monotically decreasing function of radius in the central regions of elliptical galaxies with cusps. We show that it requires the presence of a central mass concentration. An estimate of its minimum mass based on few parameters is given. This lower bound is consistent with current mass values of the central objects in galaxies derived from detailed models. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   
60.
To determine the estrogenicity of effluents from sewage treatment plants (STPs) to larval fish, 2-day-old sunshine bass were exposed to effluents from three STPs serving New York City (NYC), varying in size and treatment level. Estrogenic response was evaluated by measuring vitellogenin (VTG) and estrogen receptor (ER) expression in cytosolic fractions of whole body homogenates. Concentrations of the presumptive endocrine disruptors in the effluents were also measured. VTG and ER levels in sewage-exposed fish were 3-5 times that observed in controls. Combined concentrations of estradiol and estrone ranged from 5 to 13 ng/l and nonylphenol-ethoxylate metabolites (NPEOs: 4-nonylphenol, and 1-, 2-, and 3-nonylphenol-ethoxylates) ranged from 180 to 470 microg/l in chlorinated effluent. Results indicate that both ER and VTG can be used as biomarkers for endocrine disruption in larval fish, and that 4-day exposure to sewage effluent is sufficient to elicit significant expression of these markers in sunshine bass larvae. The extremely higher concentrations of NPEOs found in effluent relative to hormones (approximately 40,000-fold) indicates that surfactant metabolites may be contributing significantly to the estrogenic effects observed.  相似文献   
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