A high-resolution bragg spectrometer for the observation of the hot interstellar medium X-ray emission

We present a high-resolution Bragg spectrometer designed for the observation of the soft X-ray cosmic diffuse background. The instrument concept is derived from the de Broglie geometry for the study of extended sources. It consists in a mosaïc of spherical TlAP crystals associated with position sensitive detectors located on the focussing surface. The spectral resolution and its variation with the field of view is estimated by Monte-Carlo simulations for different X-ray energies chosen among the most intense lines emitted by an astrophysical plasma in the temperature range 1–4×10⁶K. The estimated sensitivity and the simulations of actual space observations show that the instrument is capable to separate the strongest lines emitted by the most abundant ions (OVII,OVIII, FeXVII, NeIX, etc.) and to map the whole sky during a six month mission.     

Adjustability of exposed elements by updating their capacity for resistance after a damaging event: application to an earthquake–tsunami cascade scenario

Natural Hazards - The 2011 Great East Japan earthquake and tsunami remind us once again that these types of cascade event can occur and cause considerable damage. The scientific community realizes...     

Determination of Radiogenic 87Sr/86Sr and Stable δ88/86SrSRM987 Isotope Values of Thirteen Mineral,Vegetal and Animal Reference Materials by DS‐TIMS

This work presents new ⁸⁷Sr/⁸⁶Sr and δ^88/86Sr_SRM987 isotopic values of thirteen mineral, vegetal and animal reference materials. Except for UB‐N, all our results are consistent with previously published data. Our results highlight intermediate precisions among the best presently published and a non‐significant systematic shift with the calculated δ^88/86Sr_SRM987 mean values for the three most analysed reference materials in the literature (i.e., IAPSO, BCR‐2 and JCp‐1). By comparison with the literature and between two distinct digestions, a significant bias of δ^88/86Sr_SRM987 values was highlighted for two reference materials (UB‐N and GS‐N). It has also been shown that digestion protocols (nitric and multi‐acid) have a moderate impact on the δ^88/86Sr_SRM987 isotopic values for the Jls‐1 reference materials suggesting that a nitric acid digestion of carbonate can be used without significant bias from partial digestion of non‐carbonate impurities. Different δ^88/86Sr_SRM987 values were measured after two independent Sr/matrix separations, according to the same protocol, for a fat‐rich organic reference material (BCR‐380R) and have been related to a potential post‐digestion heterogeneity. Finally, the δ^88/86Sr_SRM987 value differences measured between animal‐vegetal and between coral‐seawater reference materials agree with the previously published results, highlighting an Sr isotopic fractionation along the trophic chain and during carbonate precipitation.     

Case study on the strategy and application of enhancement solutions to improve remediation of soils contaminated with Cu, Pb and Zn by means of electrodialysis

Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.     

Effect of storms during drought on post‐wildfire recovery of channel sediment dynamics and habitat in the southern California chaparral,USA

Current global warming projections suggest a possible increase in wildfire and drought, augmenting the need to understand how drought following wildfire affects the recovery of stream channels in relation to sediment dynamics. We investigated post‐wildfire geomorphic responses caused by storms during a prolonged drought following the 2013 Springs Fire in southern California (USA), using multi‐temporal terrestrial laser scanning and detailed field measurements. After the fire, a dry‐season dry‐ravel sediment pulse contributed sand and small gravel to hillslope‐channel margins in Big Sycamore Creek and its tributaries. A small storm in WY 2014 generated sufficient flow to mobilize a portion of the sediment derived from the dry‐ravel pulse and deposited the fine sediment in the channel, totaling ~0.60 m³/m of volume per unit length of channel. The sediment deposit buried step‐pool habitat structure and reduced roughness by over 90%. These changes altered sediment transport characteristics of the bed material present before and after the storm; the ratio of available to critical shear stress (τ_o/τ_c) increased by five times. Storms during WY 2015 contributed additional fine sediment from tributaries and lower hillslopes and hyperconcentrated flow transported and deposited additional sediment in the channel. Together these sources delivered sediment on the order of six times that in 2014, further increasing τ_o/τ_c. These storms during multi‐year drought following wildfire transformed channel dynamics. The increased sediment transport capacity persisted during the drought period characterized by the longer residence time of relatively fine‐grained post‐fire channel sedimentation. This contrasts with wetter years, when post‐fire sediment is transported from the fluvial system during the same season as the post‐fire sediment pulse. Results of this short‐term study highlight the complex and substantial effects of multi‐year drought on geomorphic responses following wildfire. These responses influence pool habitat that is critical to longer‐term post‐wildfire riparian ecosystem recovery. Copyright © 2017 John Wiley & Sons, Ltd.     

Numerical simulation of the 30–45 ka debris avalanche flow of Montagne Pelée volcano,Martinique: from volcano flank collapse to submarine emplacement

Natural Hazards - In November 2015, China government announced that the national carbon emissions trading market is expected to start in 2017. Carbon emission trading system is a raising concern...     

Dating of marine aragonite by electron spin resonance

Marine aragonite, in the form of corals and/or shells, provides useful markers of geological and archaeological events. It is, therefore, important to have simple and accurate methods of dating these materials. Electron spin resonance (ESR) has previously been shown to be a reliable method for establishing the age of aragonitic coral samples in the time period approximately 100 ka B.P. The primary purpose of the present work is to discuss the problems encountered in extending this method to considerably older samples, up to 600 ka BP in age. In this time period there are questions about the stability of the ESR signal. The samples investigated are aragonitic corals from reef terraces of Barbados, West Indies, all of which have previously been dated by the methods, and by U-series disequilibrium, for samples below the limit of this method. There is generally good agreement for samples up to about 300 ka in age; older samples, even unrecrystallized, appear younger when dated by ESR than by . The source of this discrepancy is not clear. The explanation of thermal fading is not adequate. However, it appears likely that in most cases ESR will be able to be used to date materials up to this age. Further investigation is needed to determine tests that will distinguish datable samples from non-datable ones.