Organic geochemistry of Walvis Bay diatomaceous ooze—I. Occurrence and significance of the fatty acids

Diatomaceous ooze of the shelf off Walvis Bay (S.W. Africa) was analysed for lipid material. The lipids from the sediment consist of a mixture of hydrocarbons, alcohols, ketones, fatty acids, sterols, carotenoid pigments and chlorophylls. The total fatty acid mixture has been analysed by capillary gas chromatography mass spectrometry and shown to consist of straight chain, iso-, anteiso- and isoprenoid acids. The environmental setting of the S.W. African shelf (Walvis Bay) makes it possible to discuss these fatty acids as markers for the fate of organic matter. The acids in the sediment point to a generation during passage of algal lipids through levels of microbial activity either on or slightly above the burial surface.     

Rare-earth data on monzonoritic rocks related to anorthosites and their bearing on the nature of the parental magma of the anorthositic series

Major and trace elements have been determined in monzonoritic rocks (hypersthene-monzodiorite or jotunite) from two intrusions belonging to the South Rogaland anorthositic complex (Norway). The rare-earth abundance pattern reveals no Eu anomaly, or only a very small one. This fact together with field observations suggest that these rocks represent the parental magma of the anorthositic suite. High Ti and P abundances, low Si content, high Fe/Mg and K₂O/SiO₂ ratios are characteristics of the major element geochemistry. Absolute amounts of some trace elements abundances vary distinctly between the two intrusions. K/Rb ratios as high as 1700 are observed. Partial fusion of upper mantle kaersutite is proposed as a possible mechanism of magma generation. Partition coefficients between plagioclase phenocrysts and liquid are determined.     

Island-arc and underthrust-plate geometry

Geophysical data describing the geometry of underthrust crustal plates at the island arcs are fitted to the relation for strain-free buckling of a thin spherical shell as given by Frank (1968). Agreement of this relation with the data is notable for extensive arcs of large radius. The geometry associated with arcs of smaller radius is less strongly constrained and the dip of descending plates at arcs of small radius is greater than that predicted by the buckling relation. The data have implications concerning the growth of island arcs and the direction in which they may develop.     

The abundance of cadmium and zinc in meteorites

A stable isotope dilution technique using solid source mass spectrometry has been used to accurately determine Cd and Zn in a wide range of materials. The abundance of Cd has been determined in 19 iron, 28 stone and 1 stony-iron meteorites, together with a number of other samples. The abundance of Zn has also been determined for most of these samples. This has enabled the relationship between Cd and Zn to be examined in iron and stone meteorites. The abundance pattern of Zn in iron meteorites supports the existence of chemical groups.     

Eddy flux of sensible heat at different levels in the stratosphere

Summary Covariances of temperature and meridional wind component at 18 stations in the Northern Hemisphere were computed at 2km-intervals from the surface to 28 km. These covariances are proportional to the northward flux of sensible heat resulting from transient eddies. Cross sections of covariance of temperature and meridional wind component during January and July were constructed for 80°W. At this longitude during January a minimum of eddy heat flux occurred near an altitude of 20 km at all latitudes, and in the higher latitudes a sharp increase began somewhere between 18 km and 22 km. Eddy heat fluxes were generally quite small, in the part of the stratosphere below 20 km. A similar pattern was found at the French station of Chateauroux. The layer which separates the regions of small and large eddy heat fluxes appears to coincide with a null layer described byFaust. However, this sharp dividing line between a lower stratosphere with small eddy heat fluxes and an upper stratosphere with large eddy heat fluxes does not appear at all longitudes. Over Alaska one finds maximum eddy heat fluxes between 20 km and 22 km, and values in the lower stratosphere are much larger than those near 80° W.

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Zusammenfassung Die Kovarianz zwischen Temperatur und meridionaler Windkomponente wurde für 18 Stationen der nördlichen Hemisphäre für 2km-Intervalle vom Boden bis 28 km berechnet. Diese Kovarianzen sind dem nach Norden gerichteten mittleren Strom der Wärme proportional, verursacht durch wandernde Wirbel. Für 80°W wurden Querschnitte der Kovarianz zwischen Temperatur und meridionaler Windkomponente konstruiert. In diesem Meridianschnitt tritt ein Minimum des turbulenten Wärmeflusses in nahezu 20 km Höhe in allen Breiten im Januar auf; in höheren Breiten beginnt eine plötzliche Zunahme mit der Höhe zwischen 18 und 22 km. Dieser turbulente Wärmefluß ist im allgemeinen in der unteren Stratosphäre unterhalb 20 km ziemlich klein. Ein ähnliches Verhalten wird bei der französischen Station Chateauroux gefunden. Die Schicht, welche die Regionen des kleinen und des großen turbulenten Wärmeflusses trennt, scheint mit einer vonFaust besprochenen Nullschicht zusammenzufallen. Diese scharfe Trennungslinie zwischen unterer Stratosphäre mit kleinem turbulenten Wärmefluß und der oberen Stratosphäre mit größeren Wirbelköpern der Wärme tritt jedoch nicht an allen Längengraden auf. Über Alaska findet man einen maximalen turbulenten Wärmestrom zwischen 20 und 22 km; auch die Werte in der unteren Stratosphäre sind dort viel größer als diejenigen um 80°W.

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Résumé On a calculé la covariance existant entre la température et la composante méridionale du vent. Ces calculs, ont été effectués pour des intervalles de 2 km du sol à 28 km et cela pour 18 stations, de l'hémisphère nord. Ces nord et provoqués par des tourbillons mobiles. On a construit des sections de la covariance entre température et composante méridionale du vent à 80° de longitude W. Sous cette longitude, on constate en janvier un minimum du flux turbulent de chaleur à environ 20 km d'altitude et cela sous toutes les latitudes. Dans les latitudes élevées, on constate en outre une brusque augmentation de ce flux avec l'altitude et cela entre 18 et 22 km. Ce flux turbulent de chaleur est en général assez faible dans les basses couches de la stratosphère, c'est à dire au-dessous de 20 km. On trouve des conditions similaires, à la station française de Chateauroux. La couche qui sépare les régions présentant des flux turbulents de chaleur faible et important semble coïncider avec la couche nulle deFaust. Cette nette ligne de séparation entre la stratosphère inférieure présentant un faible flux turbulent de chaleur et la stratosphère supérieure comportant des corps tourbillonnaires de chaleur importants ne se rencontre cependant pas sous toutes les longitudes. Au-dessus de l'Alaska, on rencontre un courant turbulent de chaleur maximum entre 20 et 22 km. Les valeurs de la stratosphère inférieure y sont aussi beaucoup plus grandes que celles trouvées à 80° de longitude ouest.

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With 4 Figures     

One dimensional elastic wave propagation in a non-homogeneous conical rod

Summary A one dimensional problem concerning the wave propagation in a non-homogeneous conical rod having its cross-section directly proportional to the square of the distance from a chosen point is considered in this paper. One end of the rod is subjected to a pressure step while the other end is stress free and the pulse shape is examined when the propagation speed of the wave has a particular continuous distribution over the entire rod.     

Forced vibration of a thin non-homogeneous circular plate having a central hole

Summary This paper deals with the forced vibration produced in a thin non-homogeneous circular plate having a central hole when a periodic force is acting on the internal boundary.     

Temperature measurement with a sonic anemometer and its application to heat and moisture fluxes

Boundary-Layer Meteorology - The possibility of measuring heat and moisture fluxes using sonic anemometer data is investigated. Theoretical relations for the temperature variance and heat flux are...     

Crystallization trends of pyroxenes from alkaline subvolcanites of Punta delle Pietre Nere (Gargano,Southern Italy)

Summary The results of microprobe analyses of clinopyroxenes from alkaline melasyenites and layered melagabbros, produced by intra-plate magmatism of Paleocene age at Punta delle Pietre Nere, are here given and discussed.The analysed pyroxenes range from diopsidic to acmite-rich compositions.The first crystallized pyroxenes (diopside) show Al^VI contents suggesting shallow depths of crystallization. In addition pyroxenes from melasyenite and those from melagabbro display different Cr contents, Al/Ti and Mg/(Mg+Fe²⁺+Fe³⁺) ratios confirming their crystallization from melts produced by different parental liquids.Diopsides and salites show an overall trend towards high Al, Ti and Fe³⁺, suggesting that the crystallization occurred under decreasing SiO₂/Al₂O₃ ratios and under relatively highpH₂O–pO₂ conditions.Pyroxenes from the Pietre Nere melasyenite show a progressive variation towards acmite rich compositions at Mg/(Mg+Fe²⁺+Fe³⁺) lower than 0.5; those from the layered melagabbro, instead, show a continuous enrichment in Ca Fe³⁺ AlSiO₆. This different behaviour is due to the co-crystallization, with the latest pyroxenes, of phases with different K/Na and Si/Al ratios.

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Kristallisations-Tendenzen der Pyroxene aus Alkali-Subvulkaniten auf Punta delle Pietre Nere (Gargano, Süditalien)

Zusammenfassung Es werden die Ergebnisse der Mikrosonden-Untersuchungen von Klinopyroxenen aus Alkali-Melasyeniten und schichtigen Alkali-Melagabbros, die durch Intra-plate-Magmatismus paläozenen Alters auf Punta delle Pietre Nere entstanden sind, beschrieben und erörtert.Die untersuchten Pyroxene reichen von diopsidischen bis zu Akmit-reichen Zusammensetzungen.Die zuerst kristallisierten Pyroxene (Diopsid) zeigen Al^VI-Gehalte, die auf geringe Tiefe des Kristallisationsvorganges hinweisen. Dazu zeigen die Pyroxene aus dem Melasyenit und aus dem Melagabbro unterschiedliche Cr-Gehalte; die Al/Ti- und Mg/(Mg+Fe²⁺+Fe³⁺)-Verhältnisse bestätigen deren Kristallisation aus Schmelzen, die aus unterschiedlichen Ursprungsmagmen stammen.Die Diopside und Salite zeigen eine einheitliche Tendenz zu hohem Al-, Ti- und Fe³⁺-Gehalt; dies deutet darauf hin, daß die Kristallisation unter abnehmenden SiO₂/Al₂O₃-Verhältnissen und unter relativ hohenpH₂O–pO₂-Bedingungen stattfand.Die Pyroxene aus dem Punta delle Pietre Nere-Melasyenit zeigen eine zunehmende Änderung zu Akmit-reichen Zusammensetzungen bei weniger als 0,5 Mg/(Mg+Fe²⁺+Fe³⁺); die Pyroxene aus dem schichtig differenzierten Melagabbro zeigen dagegen eine allmähliche Zunahme von CaFe³⁺AlSiO₆. Dieses unterschiedliche Verhalten rührt daher, daß Mineralphasen mit unterschiedlichen K/Na- und Si/Al-Verhältnissen zugleich mit den zuletzt gebildeten Pyroxenen kristallisierten.

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With 6 Figures