Modelling aspects of structures isolated with the frictional pendulum system

Different modelling aspects of structures isolated using the frictional pendulum system and subjected to earthquake ground motions are studied herein. Although the vertical dynamics of these structures is given special emphasis, other effects such as large isolator deformations and bidirectional input motion are also considered. Different structural models of the FPS are developed and tested for single-storey structures and a real four-storey building frame; among them, an ‘exact’ formulation of the FPS force–deformation constitutive relationship is presented. Results show that global building responses can be computed within 20 per cent error in the mean using a simplified model that ignores the vertical motion of the building; however, structural member deformations and forces need to be computed using a model that considers such motion. This is of particular importance when there exist correlation between the horizontal and vertical components of ground motion. Further, a physical model of the FPS is introduced and used to determine the response of a real four-storey frame, including uplift and downward impact. Results from this analysis show that local column responses may vary substantially depending on the stiffness of the isolation storey and the presence of a mass at the isolation level. Such mass is capable of filtering the large increase in column shear that results from the impact of the structure after uplift. Uplift occurs at several instants of the response of the structure considered, leading to an increase in column base shear as large as 3 times the shear obtained by ignoring the vertical dynamics of the building. © 1998 John Wiley & Sons, Ltd.     

西藏当雄九子拉地区石炭系诺错组中震积岩的发现及意义

西藏当雄九子拉地区石炭系诺错组地层序列中,首次发现了一套非正常沉积的粉砂岩和灰岩的组合.岩系中可识别出非正常的沉积构造,即微同沉积断裂、火焰状构造、同生变形构造及振动液化泄水构造等,这一软沉积变形构造具震积岩的识别标志特征,代表灾变事件震积的地质记录.在剖面结构上大致显示为7个单元的震积序列,自下而上由下伏弱震层(A)—液化脉(B)—震褶岩(C)—震裂岩(D)—阶梯状微断层(E)—火焰状构造(F)—上覆未震层(G)的渐变过程及震积作用逐渐减弱的趋势呈不同形式的组合出现,有ABG、ACDG、AEG、ABCG和ABFG等组合.本研究分析认为晚古生代诺错组早期存在一个强烈的构造活动时期,结合震积岩的分布及区域地质背景研究表明,九子拉北侧一带可能为近东西向同生断裂带,该断裂带的强烈构造活动是本区诺错组震积作用的直接诱发因素.从而佐证了九子拉地区正处于构造转换阶段.本研究对分析晚古生代的构造演化、沉积盆地类型奠定了基础,同时保存完好的震积事件地层记录对推断古断裂、古环境也具有较大意义.     

Optical Spectroscopy and Near-Infrared Observations of Comet C/2000 Wm1 (Linear) in December 2001 from Chile and Brazil

We report on the preliminary analysis of the high-resolution spectrum of CometC/2000 WM1 (LINEAR), obtained on Dec. 1, 2001 with the Fiber fed ExtendedRange Optical Spectrograph (FEROS) installed on the 1.52-m telescope of ESO(Chile). Many emission lines of the molecules C₂, C₃, CN, CH, CH⁺,NH₂, CO, CO⁺, H₂O⁺ and, presumably, C₂ ^- were identifiedin the spectral range 400–900 nm. Also, near-infrared photometry was performed on Dec. 2 and 3, with the infraredcamera (CamIV) attached to the 0.60-m Boller and Chivens telescope of the Picodos Dias Observatory (LNA/MCT), Brazil. We report the preliminary and comparativeanalysis of the I-J and J-H color indices.     

南海尖峰海山多金属结壳地球化学

南海尖峰海山多金属结壳富含30多种元素,其锰铁矿物主要由钡镁锰矿,δ-MnO_2和FeOOH·xH_2O组成。与其它海区的结壳相比,尖峰海山结壳富含Cu、Ni、Ba、Zn、Pb等元素,而Co、Ti、稀土元素(REE)、Sr等元素相对较贫。研究表明,HREE亏损,具明显的Ce正异常,较明显的Tb正异常和Yb负异常。这是氧化弱碱性海洋环境所致。结壳是水成作用的产物,它的形成受南海独特的古海洋环境所控制,海底火山热液作用,可能也是影响因素之一。     

皖南晚中生代花岗闪长岩地球化学:成岩成矿制约

皖南地区是铜、钼、金多金属成矿区,成矿与晚中生代花岗闪长岩类关系密切。近十年来,皖南花岗闪长岩的成因仍然存在分歧。本次报道了皖南花岗闪长岩全岩主、微量元素和锆石原位元素数据。皖南花岗闪长岩(Si O2=64.3%~70.8%)为高钾钙碱性、过铝质岩石,具有相似的埃达克岩特征:高Si O2、Sr/Y(17.1)和(La/Yb)N(14.9)比值,低Yb(1.72×10-6)和Y(18.4×10-6)含量。它们也具有较低Al2O3和Cr(3.40×10-6~10.0×10-6)含量、低Mg#(0.34~0.42)和Nb/Ta(9.6~13.3)值,高K2O和Ba(404×10-6)含量,高K2O/Na2O(0.89~1.55)、Th/La(0.27~0.51)和Th/U(2.79~7.49)比值。锆石原位地球化学特征显示其岩浆源区为低温(锆石Ti-in-zircon温度均值674℃)和高氧逸度(lgfO2集中在-21.4~-9.18,均值-16.4;锆石Ce4+/Ce3+平均值276)的陆壳。这些特征说明皖南花岗闪长岩可能起源于较年轻的加厚下地壳的部分熔融,并经历了斜长石、钾长石和铁镁矿物等结晶分异作用。它们可能形成于与古太平洋板块俯冲密切相关的大陆活动边缘弧至弧后拉张构造转换背景。本区大规模Cu、Mo、Au成矿作用与岩浆的高氧逸度密切相关,而锆石Ce4+/Ce3+可作为矿床勘探一个有效的指标。     

Element partitioning during precipitation of aragonite from seawater: A framework for understanding paleoproxies

This study presents the results from precipitation experiments carried out to investigate the partitioning of the alkaline earth cations Mg²⁺, Ca²⁺, Sr²⁺, and Ba²⁺ between abiogenic aragonite and seawater as a function of temperature. Experiments were carried out at 5 to 75 °C, using the protocol of Kinsman and Holland [Kinsman, D.J.J., Holland, H.D., 1969. The coprecipitation of cations with CaCO₃ IV. The coprecipitation of Sr²⁺ with aragonite between 16 and 96 °C. Geochim. Cosmochim. Acta33, 1-17.] The concentrations of Mg Sr and Ba were determined in the fluid from each experiment by inductively coupled plasma-mass spectrometry, and in individual aragonite grains by secondary ion mass spectrometry. The experimentally produced aragonite grains are enriched in trace components (“impurities”) relative to the concentrations expected from crystal-fluid equilibrium, indicating that kinetic processes are controlling element distribution. Our data are not consistent with fractionations produced kinetically in a boundary layer adjacent to the growing crystal because Sr²⁺, a compatible element, is enriched rather than depleted in the aragonite. Element compatibilities, and the systematic change in partitioning with temperature, can be explained by the process of surface entrapment proposed by Watson and Liang [Watson, E.B., Liang, Y., 1995. A simple model for sector zoning in slowly grown crystals: implications for growth rate and lattice diffusion, with emphasis on accessory minerals in crustal rocks. Am. Mineral.80, 1179-1187] and Watson [Watson, E.B., 1996. Surface enrichment and trace-element uptake during crystal growth. Geochim. Cosmochim. Acta60, 5013-5020; Watson, E.B., 2004. A conceptual model for near-surface kinetic controls on the trace-element and stable isotope composition of abiogenic calcite crystals. Geochim. Cosmochim. Acta68, 1473-1488]. This process is thought to operate in regimes where the competition between crystal growth rate and diffusivity in the near-surface region limits the extent to which the solid can achieve partitioning equilibrium with the fluid. A comparison of the skeletal composition of Diploria labyrinthiformis (brain coral) collected on Bermuda with results from precipitation calculations carried out using our experimentally determined partition coefficients indicate that the fluid from which coral skeleton precipitates has a Sr/Ca ratio comparable to that of seawater, but is depleted in Mg and Ba, and that there are seasonal fluctuations in the mass fraction of aragonite precipitated from the calcifying fluid (“precipitation efficiency”). The combined effects of surface entrapment during aragonite growth and seasonal fluctuations in “precipitation efficiency” likely forms the basis for the temperature information recorded in the aragonite skeletons of Scleractinian corals.     

Evaluation of ferrous and ferric Mössbauer fractions

The Mössbauer fractions f for various ferrous- and/or ferric-containing oxides and oxyhydroxides, silicates and carbonates were evaluated from the experimental temperature dependence of their center shifts, using the Debye approximation for the second-order Doppler shift. It is concluded that ferrous ions exhibit a lower fraction as compared to ferric ions. Using standard mixtures of -Fe₂O₃ with selected Fe²⁺ or Fe³⁺ compounds, it is found that the calculated Fe³⁺ f values are somewhat overestimated with respect to those of Fe²⁺. Possible explanations for this shortcoming are discussed and it is suggested that a different temperature dependence of the intrinsic isomer shift is the most likely reason. This suggestion is corroborated by analyses of hematite and hedenbergite data which are available for temperatures up to 900 K and 800 K respectively.     

Impact of nitrogenous fertilizers on carbonate dissolution in small agricultural catchments: Implications for weathering CO2 uptake at regional and global scales

The goal of this study was to highlight the occurrence of an additional proton-promoted weathering pathway of carbonate rocks in agricultural areas where N-fertilizers are extensively spread, and to estimate its consequences on riverine alkalinity and uptake of CO₂ by weathering. We surveyed 25 small streams in the calcareous molassic Gascogne area located in the Garonne river basin (south-western France) that drain cultivated or forested catchments for their major element compositions during different hydrologic periods. Among these catchments, the Hay and the Montoussé, two experimental catchments, were monitored on a weekly basis. Studies in the literature from other small carbonate catchments in Europe were dissected in the same way. In areas of intensive agriculture, the molar ratio (Ca + Mg)/HCO₃ in surface waters is significantly higher (0.7 on average) than in areas of low anthropogenic pressure (0.5). This corresponds to a decrease in riverine alkalinity, which can reach 80% during storm events. This relative loss of alkalinity correlates well with the content in surface waters. In cultivated areas, the contribution of atmospheric/soil CO₂ to the total riverine alkalinity (CO_{2 ATM-SOIL}/HCO₃) is less than 50% (expected value for carbonate basins), and it decreases when the nitrate concentration increases. This loss of alkalinity can be attributed to the substitution of carbonic acid (natural weathering pathway) by protons produced by nitrification of N-fertilizers (anthropogenic weathering pathway) occurring in soils during carbonate dissolution. As a consequence of these processes, the alkalinity over the last 30 years shows a decreasing trend in the Save river (one of the main Garonne river tributaries, draining an agricultural catchment), while the nitrate and calcium plus magnesium contents are increasing.We estimated that the contribution of atmospheric/soil CO₂ to riverine alkalinity decreased by about 7-17% on average for all the studied catchments. Using these values, the deficit of CO₂ uptake can be estimated as up to 0.22-0.53 and 12-29 Tg¹ yr⁻¹ CO₂ on a country scale (France) and a global scale, respectively. These losses represent up to 5.7-13.4% and only 1.6-3.8% of the total CO₂ flux naturally consumed by carbonate dissolution, for France and on a global scale, respectively. Nevertheless, this loss of alkalinity relative to the Ca + Mg content relates to carbonate weathering by protons from N-fertilizers nitrification, which is a net source of CO₂ for the atmosphere. This anthropogenic CO₂ source is not negligible since it could reach 6-15% of CO₂ uptake by natural silicate weathering and could consequently partly counterbalance this natural CO₂ sink.     

春季一次特殊的暴雨天气过程分析

对2000年春季一次高空槽快速移动影响的暴雨天气过程发生的特殊性进行分析,寻找这次暴雨过程发生的前期特征.