A first deep seismic survey in the Sea of Marmara: Deep basins and whole crust architecture and evolution

Increased source strength, streamer length and dense spatial coverage of seismic reflection profiles of the SEISMARMARA Leg 1 allow to image the deep structure of the marine North Marmara Trough (NMT) on the strike-slip North Anatolian Fault (NAF) west of the destructive Izmit 1999 earthquake. A reflective lower crust and the Moho boundary are detected. They appear upwarped on an E-W profile from the southern Central Basin eastwards, towards more internal parts of the deformed region. Thinning of the upper crust could use a detachment suggested from an imaged dipping intracrustal reflector that would allow upper crustal material to be dragged from beneath it and above the lower crust, accounting for the extensional component but also southwest motion of the southern margin of the NMT. Sections across the eastern half of the NMT, crossing the Cinarcik and Imrali basins, reveal several faults that are active reaching into the basement and have varying strike and proportions of normal and strike-slip displacement. They might be viewed as petals of a large scale negative flower-structure that spreads over a width of 30 km at surface and is rooted deeper in the lithosphere. Under the Central Basin a very thick sediment infill is revealed and its extensional bounding faults are active and imaged as much as 8 km apart down to 6 km depth. We interpret them as two deep-rooted faults encompassing a foundering basement block, rather than being merely pulled-apart from a jog in a strike-slip above a décollement. The deep-basin lengthening would account for only a modest part of the proposed 60 km finite motion since 4 Myr along the same direction oblique to the NMT that sidesteps the shear motion from its two ends. Thus differential motion occurred much beyond the deep basins, like subsidence involving the NMT bounding faults and the intracrustal detachments. The complex partitioned motion localized on active faults with diverse natures and orientations is suggested to represent the overburden deformation induced from horizontal plane simple shear occurring in depth at lithospheric scale, and in front of the North Anatolian Fault when it propagated through the region.     

Multixenobiotic resistance, acetyl-choline esterase activity and total oxyradical scavenging capacity of the Arctic spider crab, Hyasaraneus, following exposure to bisphenol A, tetra bromo diphenyl ether and diallyl phthalate

The Arctic has become a sink for persistent organic pollutants (POPs) originating from lower latitudes, and relatively high levels have been found in different biota. Recent studies have identified detrimental effects on wildlife including endocrine disruption, impairment of enzyme activity, and reduced immune function. The Arctic spider crab, Hyas araneus, shown interesting potential for its use as sentinel organism in polar ecosystems. This study investigated the effect of 2,2',4,4'-tetra bromo diphenyl ether (BPDE), bisphenol A (BPA), and diallyl phthalte (DPA) on H. araneus in a three weeks exposure study. Expression of multixenibiotic resistance (MXR) proteins has been studied using the C219 monoclonal antibody which allows identifying an immunoreactive protein of 40 kDa in the digestive gland while no such protein could be observed in the gills. Expression of this protein was increased by exposure to DPA (+75%; p<0.05, n=10). All compounds significantly affected muscle acetylcholine esterase (AChE) activity (p<0.05, n=10) with 50 microg/L DPA having the strongest effect by lowering the value to 37% of control. The total oxyradical scavenging capacity measured in the digestive gland toward peroxyl, hydroxyl and peroxynitrite was also significantly reduced indicating a decreased resistance to oxidative stress generated by DPA (p<0.05, n=5). These results thus suggest the potential detrimental effects of DPA even at concentration as low as 50 microg/L on H. araneus.     

Spatial analysis of instream nitrogen loads and factors controlling nitrogen delivery to streams in the southeastern United States using spatially referenced regression on watershed attributes (SPARROW) and regional classification frameworks

Understanding how nitrogen transport across the landscape varies with landscape characteristics is important for developing sound nitrogen management policies. We used a spatially referenced regression analysis (SPARROW) to examine landscape characteristics influencing delivery of nitrogen from sources in a watershed to stream channels. Modelled landscape delivery ratio varies widely (by a factor of 4) among watersheds in the southeastern United States—higher in the western part (Tennessee, Alabama, and Mississippi) than in the eastern part, and the average value for the region is lower compared to other parts of the nation. When we model landscape delivery ratio as a continuous function of local‐scale landscape characteristics, we estimate a spatial pattern that varies as a function of soil and climate characteristics but exhibits spatial structure in residuals (observed load minus predicted load). The spatial pattern of modelled landscape delivery ratio and the spatial pattern of residuals coincide spatially with Level III ecoregions and also with hydrologic landscape regions. Subsequent incorporation into the model of these frameworks as regional scale variables improves estimation of landscape delivery ratio, evidenced by reduced spatial bias in residuals, and suggests that cross‐scale processes affect nitrogen attenuation on the landscape. The model‐fitted coefficient values are logically consistent with the hypothesis that broad‐scale classifications of hydrologic response help to explain differential rates of nitrogen attenuation, controlling for local‐scale landscape characteristics. Negative model coefficients for hydrologic landscape regions where the primary flow path is shallow ground water suggest that a lower fraction of nitrogen mass will be delivered to streams; this relation is reversed for regions where the primary flow path is overland flow. Published in 2009 by John Wiley & Sons, Ltd.     

The snowball Earth aftermath: Exploring the limits of continental weathering processes

Carbonates capping Neoproterozoic glacial deposits contain peculiar sedimentological features and geochemical anomalies ascribed to extraordinary environmental conditions in the snowball Earth aftermath. It is commonly assumed that post-snowball climate dominated by CO₂ partial pressures several hundred times greater than modern levels, would be characterized by extreme temperatures, a vigorous hydrological cycle, and associated high continental weathering rates. However, the climate in the aftermath of a global glaciation has never been rigorously modelled. Here, we use a hierarchy of numerical models, from an atmospheric general circulation model to a mechanistic model describing continental weathering processes, to explore characteristics of the Earth system during the supergreenhouse climate following a snowball glaciation. These models suggest that the hydrological cycle intensifies only moderately in response to the elevated greenhouse. Indeed, constraints imposed by the surface energy budget sharply limit global mean evaporation once the temperature has warmed sufficiently that the evaporation approaches the total absorbed solar radiation. Even at 400 times the present day pressure of atmospheric CO₂, continental runoff is only 1.2 times the modern runoff. Under these conditions and accounting for the grinding of the continental surface by the ice sheet during the snowball event, the simulated maximum discharge of dissolved elements from continental weathering into the ocean is approximately 10 times greater than the modern flux. Consequently, it takes millions of years for the silicate weathering cycle to reduce post-snowball CO₂ levels to background Neoproterozoic levels. Regarding the origin of the cap dolostones, we show that continental weathering alone does not supply enough cations during the snowball melting phase to account for their observed volume.     

Gravity variations along the Southeast Bohol Ophiolite Complex (SEBOC), Central Philippines: Implications on Ophiolite Emplacement

Abstract The basement complex of Bohol Island consists of the Southeast Bohol Ophiolite Complex (SEBOC), Cansiwang Melange and Alicia Schist. The SEBOC is a complete, but dismembered ophiolite with outcrops generally trending northeast– southwest and dipping north-west. The harzburgite units of the SEBOC are almost always observed to be thrusted onto the Cansiwang Melange, which in turn is thrusted onto the Alicia Schist. Bouguer gravity values on Bohol range from about +60 mGal in the west to +120 mGal in the east, in the region to the north-east of the SEBOC outcrops. Based on the present distribution of the SEBOC units and their thrust fault relationship with the Cansiwang Melange and Alicia Schist, it is proposed that the SEBOC was emplaced by onramping towards the south-eastward direction. However, the orientation of the Bouguer highs suggests that the thrusting direction of the ophiolite units is towards the south-west and not towards the south-east.     

Modeling Permeability Changes Caused by Hydrothermal Circulation

A new model for simulating porosity and permeability changes caused by sedimentary reservoirsdiagenesis is presented. Permeability is computed from changes in the mineral volume fractionsresulting from precipitation and dissolution of the rock-forming mineral as fluid flows throughvariable salinity and temperature fields. Its evolution is controlled by a power—law relationship,in which a weighting coefficient is assigned to clay minerals. This approach allows theincorporation of the widely observed influence of clay content on the porosity—permeabilityrelationship. A synthetic example is set up to analyze the sensitivity of the results to a set offour controlling parameters: the effect of the clay-weighting coefficient compared to the effectof the salinity gradient, temperature gradient, and exponent coefficient of the permeabilityevolution law. Using a large range of values for these parameters, the results show that theirinfluence is of equivalent magnitude in terms of permeability evolution rate. It also seemsthat the value of the clay-weighting coefficient affects the evolution trend: permeability mayincrease when the porosity decreases (and vice versa). The model is compared to the classicalapproach for which permeability is a function of porosity change only. Results display thestrong influence of even low values of the clay-weighting coefficient on the permeabilitychange. Consequently, the specific influence of mineral transfers on pore structure changes isa key parameter for modeling permeability changes and cannot be bypassed by the use ofsimple porosity—permeability evolution law.     

Adjustment of a drainage network to capture induced base-level change: an example from the Sorbas Basin, SE Spain

Quaternary catchments in the south of the Sorbas Basin, SE Spain have been affected by two regionally significant river captures. The river captures were triggered by changes in regional gradients associated with sustained Quaternary uplift in the region of 160 m Ma⁻¹. The first capture occurred in the early Pleistocene and re-routed 15% of the original Sorbas Basin drainage into the Carboneras Basin to the south. The second occurred in the late Pleistocene and re-routed 73% of the original Sorbas Basin drainage to the east. This latter capture had dramatic consequences for base-level in the Sorbas Basin master drainage. Local base-level was lowered by 90 m at the capture site, 50 m at 7 km upstream and 25 m at 13 km upstream of the site. The base-level change instigated a complex re-organisation of the drainage networks in systems tributary to the master drainage over the ensuing period (some 100 ka). After the capture, drainage systems closer to the capture site experienced a tenfold increase in incision rates over most of their network. Those located some 13 km upstream of the capture site experienced a fivefold increase in incision, although in this instance, the changes do not appear to have propagated to the headwater regions of the drainage nets. The sensitivity of individual catchments was largely governed by geological controls (structure and lithology). The detailed network evolution in the most sensitive areas can be traced by reconstructing former drainage pathways using abandoned drainage cols and the alignment and degree of incision of the drainage networks. Three main stages of evolution can be identified which record the progressive spread of base-level changes from the master drainage. These are Stage 1 (pre-capture): original south-to-north consequent drainage; Stage 2 (early stage, post capture): aggressive subsequent southwest-to-northeast and east–west drainage developed along structural lineaments first in the east of the area (Stage 2a), and later in the west of the area (Stage 2b); and Stage 3 (late stage, post capture): obsequent drainage developing on the topography of the Stage 2 drainage. All stages of the network evolution are associated with drainage re-routing as a function of river capture at a variety of scales. The results highlight the complex response of the fluvial system, and the very different geomorphological histories of adjacent catchments, emphasising the need for regional approaches for examining long-term changes in fluvial systems.     

Phytolith assemblages as a promising tool for reconstructing Mediterranean Holocene vegetation

The reliability of phytolith assemblage analysis for characterizing Mediterranean vegetation is investigated in this study. Phytolith assemblages are extracted from modern and buried Holocene soils from the middle Rhône valley (France). The relation between modern phytolith assemblages and the surrounding vegetation, as well as between fossil assemblages and contemporaneous vegetation, already reconstructed through other proxies, is discussed. We demonstrate that the main northwestern Mediterranean biomes are well distinguished by soil phytolith assemblage analysis. In particular, the density of pine and nonconiferous trees (densities expressed relatively to the grass cover) and the overall degree of opening of the vegetation appear well recorded by three phytolith indexes. North Mediterranean vegetation changes during the Holocene period, mainly tree line shifts, pine wood development and deforestation are poorly documented, due to the scarcity of proxy-preserving sites. Phytolith assemblage analysis of soils, buried soils, and sediments appears to be a promising technique to fill this gap.     

New Reference Materials and Assessment of Matrix Effects for SIMS Measurements of Oxygen Isotopes in Garnet

Accurate ion microprobe analysis of oxygen isotope ratios in garnet requires appropriate reference materials to correct for instrumental mass fractionation that partly depends on the garnet chemistry (matrix effect). The matrix effect correlated with grossular, spessartine and andradite components was characterised for the Cameca IMS 1280HR at the SwissSIMS laboratory based on sixteen reference garnet samples. The correlations fit a second‐degree polynomial with maximum bias of ca. 4‰, 2‰ and 8‰, respectively. While the grossular composition range 0–25% is adequately covered by available reference materials, there is a paucity of them for intermediate compositions. We characterise three new garnet reference materials GRS2, GRS‐JH2 and CAP02 with a grossular content of 88.3 ± 1.2% (2s), 83.3 ± 0.8% and 32.5 ± 3.0%, respectively. Their micro scale homogeneity in oxygen isotope composition was evaluated by multiple SIMS sessions. The reference δ¹⁸O value was determined by CO₂ laser fluorination (δ¹⁸O_LF). GRS2 has δ¹⁸O_LF = 8.01 ± 0.10‰ (2s) and repeatability within each SIMS session of 0.30–0.60‰ (2s), GRS‐JH2 has δ¹⁸O_LF = 18.70 ± 0.08‰ and repeatability of 0.24–0.42‰ and CAP02 has δ¹⁸O_LF = 4.64 ± 0.16‰ and repeatability of 0.40–0.46‰.