Development and Re‐Evaluation of Tourmaline Reference Materials for In Situ Measurement of Boron δ Values by Secondary Ion Mass Spectrometry

Six tourmaline samples were investigated as potential reference materials (RMs) for boron isotope measurement by secondary ion mass spectrometry (SIMS). The tourmaline samples are chemically homogeneous and cover a compositional range of tourmaline supergroup minerals (primarily Fe, Mg and Li end‐members). Additionally, they have homogeneous boron delta values with intermediate precision values during SIMS analyses of less than 0.6‰ (2s). These samples were compared with four established tourmaline RMs, that is, schorl IAEA‐B‐4 and three Harvard tourmalines (schorl HS#112566, dravite HS#108796 and elbaite HS#98144). They were re‐evaluated for their major element and boron delta values using the same measurement procedure as the new tourmaline samples investigated. A discrepancy of about 1.5‰ in δ¹¹B was found between the previously published reference values for established RMs and the values determined in this study. Significant instrumental mass fractionation (IMF) of up to 8‰ in δ¹¹B was observed for schorl–dravite–elbaite solid solutions during SIMS analysis. Using the new reference values determined in this study, the IMF of the ten tourmaline samples can be modelled by a linear combination of the chemical parameters FeO + MnO, SiO₂ and F. The new tourmaline RMs, together with the four established RMs, extend the boron isotope analysis of tourmaline towards the Mg‐ and Al‐rich compositional range. Consequently, the in situ boron isotope ratio of many natural tourmalines can now be determined with an uncertainty of less than 0.8‰ (2s).     

Controls on debris-flow initiation on burned and unburned hillslopes during an exceptional rainstorm in southern New Mexico,USA

AbstractUsing observations from 688 debris flows, we analyse the hydrologic and landscape characteristics that influenced debris-flow initiation mechanisms and locations in a watershed that had been partially burned by the 2012 Whitewater-Baldy Complex Fire in the Gila Mountains, southern New Mexico. Debris flows can initiate due to different processes. Slopes can fail as discrete landslides and then become fluidized and move downstream as debris flows (landslide initiated) or progressive bulking of sediment from a distributed area can become channelized and concentrated as it moves downslope (runoff generated). In this study, we have an unusual opportunity to investigate both types of debris-flow initiation mechanisms in our observations of debris flows, triggered by an exceptional rainstorm in the autumn of 2013. Additionally, we compare our observations with those of a dataset of 1138 debris flows in the Colorado Front Range, triggered during the same weather system. We found that runoff-generated debris flows dominated in burn areas, and runoff required to start these flows could be well characterized by the Shields stress. Landslide-initiated debris flows were dominant in unburned areas. Debris-flow densities were tied to total rainfall and precipitation intensities. Like the observations in the Colorado Front Range, debris-flow initiation locations were found primarily in areas of relatively sparse vegetation on south-facing slopes between 25 and 40°, and with upslope contributing areas less than 1000 m². In terms of preferential locations for debris-flow initiations, 2013 vegetation coverage, approximated by Green–Red Vegetation Index metrics, proved to be more influential than the 2012 burn-severity designation. The uniformity of observations between our study area and those in the Colorado Front Range indicate that the underlying hydrologic and landscape patterns of the debris-flow initiation locations documented in these studies could be applicable to the wider southwest and Rocky Mountain regions. © 2019 John Wiley & Sons, Ltd.     

Deep lithospheric structure beneath the Polish part of the East European Craton as a result of magnetotelluric surveys

Studia Geophysica et Geodaetica - A fundamental tectonic boundary between the Precambrian East European Craton (EEC) and the younger Phanerozoic mountain belts of Europe runs through Poland....     

Multistatic estimation of high-frequency radar surface currents in the region of Toulon

Ocean Dynamics - The high-frequency radar coastal network in Toulon operates in multistatic mode for the monitoring of the ocean circulation in the Northwestern Mediterranean Sea. With 2...     

Biotite Reference Materials for Secondary Ion Mass Spectrometry 18O/16O Measurements

Five new biotite reference materials were calibrated at the SwissSIMS laboratory (University of Lausanne) for oxygen isotope determination by secondary ion mass spectrometry (SIMS) and are available to the scientific community. The oxygen isotope composition of the biotites, UNIL_B1 to B5, was determined by laser‐heating fluorination to be 11.4 ± 0.11‰, 8.6 ± 0.15‰, 6.1 ± 0.04‰, 7.1 ± 0.05‰ and 7.6 ± 0.04‰, respectively. SIMS analyses on spots smaller than 20 μm gave a measurement repeatability of 0.3‰ (2 standard deviation, 2s). The matrix effect due to solid solution in natural biotite could be expressed as a linear function of X_Mg and X_F for biotite. No effect was found for different crystallographic orientations. SIMS analysis allows the oxygen isotope composition of biotite to be measured with a measurement uncertainty of 0.3–0.4‰ (2s) for biotites with similar major element compositions. A measurement uncertainty of 0.5‰ (2s) is realistic when F poor biotites (lower than 0.2% m/m oxides) within the compositional range of X_Mg of 0.3–0.9 were compared from different sessions. The linear correlation with F content offers a reasonable working curve for F‐rich biotites, but additional reference materials are needed to confirm the model.     

Chronology of Quaternary terrace deposits at the locality Hohle Gasse (Pratteln,NW Switzerland)

The Quaternary stratigraphy of the Alpine Foreland consists of distinct terrace levels, which have been assigned to four morphostratigraphic units: Höhere (Higher) Deckenschotter, Tiefere (Lower) Deckenschotter, Hochterrasse (High Terrace) and Niederterrasse (Lower Terrace). Here, we focus on the terrace gravels at Hohle Gasse, SSE of Pratteln near Basel, which are mapped as Tiefere Deckenschotter. Petrographic and morphometric data established from clasts allowed to infer the transport mechanisms and sources of the gravels. Sedimentological analyses indicate that the gravels were transported by a braided river and deposited in a distal glaciofluvial setting. In addition, it can be shown that the majority of the clasts display multiple reworking and only a minority maintained a distinct glaciofluvial shape. Cosmogenic multi-isotope dating using ¹⁰Be and ³⁶Cl allowed direct dating of the sediments at the study site. A depth-profile age of \(2 70_{ - 1 90}^{ + 8 30}\) ka for ¹⁰Be was achieved for the deposits at Hohle Gasse. Unfortunately, no age could be modelled from the ³⁶Cl concentrations as the blank correction was too high. Furthermore, this age proves that the studied terrace level should be assigned to the morphostratigraphic unit Hochterrasse.     

3D simultaneous joint PP‐PS prestack seismic inversion at Schiehallion field,United Kingdom Continental Shelf

A workflow for simultaneous joint PP‐PS prestack inversion of data from the Schiehallion field on the United Kingdom Continental Shelf is presented and discussed. The main challenge, describing reasonable PS to PP data registration before any prestack or joint PP‐PS inversion, was overcome thanks to a two‐stage process addressing the signal envelope, then working directly on the seismic data to estimate appropriate time‐variant time‐shift volumes. We evaluated the benefits of including PS along with PP prestack seismic data in a joint inversion process to improve the estimated elastic property quality and also to enable estimation of density compared with other prestack and post‐stack inversion approaches. While the estimated acoustic impedance exhibited a similar quality independent of the inversion used (PP post‐stack, PP prestack or joint PP‐PS prestack inversion) the shear impedance estimation was noticeably improved by the joint PP‐PS prestack inversion when compared to the PP prestack inversion. Finally, the density estimated from joint PP and PS prestack data demonstrated an overall good quality, even where not well‐controlled. The main outcome of this study was that despite several data‐related limitations, inverting jointly correctly processed PP and PS data sets brought extra value for reservoir delineation as opposed to PP‐only or post‐stack inversion.     

Numerical simulation of the 30–45 ka debris avalanche flow of Montagne Pelée volcano,Martinique: from volcano flank collapse to submarine emplacement

Natural Hazards - In November 2015, China government announced that the national carbon emissions trading market is expected to start in 2017. Carbon emission trading system is a raising concern...