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991.
992.
K. Pecher D. McCubbery E. Kneedler J. Bargar L. Cox B. Tonner 《Geochimica et cosmochimica acta》2003,67(6):1089-1098
We have applied Scanning Transmission Soft X-ray Microscopy (STXM) to investigate the charge state distribution of Mn in two kinds of Mn-biominerals, Mn nodules collected from Lake Michigan sediments and Mn precipitates formed by spores of a marine bacillus SG-1 under transport limited reaction conditions. A data analysis technique was developed, which allows for extraction of spatially resolved 2-d charge state maps of manganese on a submicron level. We find that the charge state of Mn dominates the spectral shape of L-edge spectra of environmentally important single oxidation state Mn minerals and that spectra of mixed oxidation state oxides can be modelled by a combination of appropriate single oxidation state reference spectra. Two-dimensional maps of charge state distributions clearly reveal domains of different oxidation states within single particles of Mn-micronodules. Spots of preferred accumulation of Mn(II) were found, which indicates biogenic precipitation of Mn(II)-species as a first step of nodule formation. The presence of Mn(III) in the studied sediment samples suggests the involvement of one-electron oxidation processes and reaction conditions which inhibit or slow down the disproportionation of Mn(III)-products. Under transport limited conditions, Mn oxidation products formed by spores of the marine bacillus SG-1 can vary from cell to cell. The presence of significant amounts of Mn(III) containing species points to the involvement of one-electron oxidation reactions as in the case of the micro-nodules. Our technique and the results obtained form a new basis for the mechanistic understanding of the formation of Mn biominerals in the environment. 相似文献
993.
Fluxes of Sr into the headwaters of the Ganges 总被引:1,自引:0,他引:1
Mike J Bickle Judith Bunbury Nigel B.W Harris Talat Ahmad 《Geochimica et cosmochimica acta》2003,67(14):2567-2584
Himalayan weathering is recognized as an important agent in modifying sea water chemistry, but there are significant uncertainties in our understanding of Himalayan riverine fluxes. This paper examines causes of the variability, including that of the seasons, by analysis of downstream variations in Sr, 87Sr, and major ions in the mainstream, in relation to the composition of tributary streams from subcatchments with differing geologic substrates.Water samples were collected over four periods spanning the premonsoon, monsoon, and postmonsoon seasons. Uncertainties in the relative fluxes have been estimated, using Monte Carlo techniques, from the short-term variability of mainstream chemistry and the scatter of tributary compositions. The results show marked seasonal variations in the relative inputs related to high monsoon rainfall in the High and Lesser Himalaya, contrasting with the major contribution from glacial melt waters from the Tibetan Sedimentary Series (TSS) at times of low rainfall. Much of the spread in previously published estimates of the sources of Sr in Himalayan rivers may result from these seasonal variations in Sr fluxes.The annual fluxes of Sr into the headwaters of the Ganges are derived from the three main tectonic units in the proportions 35 ± 1% from the TSS, 27 ± 3% from the High Himalayan Crystalline Series (HHCS), and 38 ± 8% from the Lesser Himalaya. The particularly elevated 87Sr/86Sr ratios characteristic of the HHCS and the Lesser Himalaya enhance their influence on seawater Sr-isotope composition. The TSS contributes 13 ± 1%, the HHCS 30 ± 3%, and the Lesser Himalaya 57 ± 11% of the 87Sr flux in excess of the seawater 87Sr/86Sr ratio of 0.709. 相似文献
994.
Field investigations at Dugway Proving Ground in western Utah have produced new data on the chronology and human occupation of late Pleistocene and early Holocene lakes, rivers, and wetlands in the Lake Bonneville basin. We have classified paleo-river channels of these ages as “gravel channels” and “sand channels.” Gravel channels are straight to curved, digitate, and have abrupt bulbous ends. They are composed of fine gravel and coarse sand, and are topographically inverted (i.e., they stand higher than the surrounding mudflats). Sand channels are younger and sand filled, with well-developed meander-scroll morphology that is truncated by deflated mudflat surfaces. Gravel channels were formed by a river that originated as overflow from the Sevier basin along the Old River Bed during the late regressive phases of Lake Bonneville (after 12,500 and prior to 11,000 14C yr B.P.). Dated samples from sand channels and associated fluvial overbank and wetland deposits range in age from 11,000 to 8800 14C yr B.P., and are probably related to continued Sevier-basin overflow and to groundwater discharge. Paleoarchaic foragers occupied numerous sites on gravel-channel landforms and adjacent to sand channels in the extensive early Holocene wetland habitats. Reworking of tools and limited toolstone diversity is consistent with theoretical models suggesting Paleoarchaic foragers in the Old River Bed delta were less mobile than elsewhere in the Great Basin. 相似文献
995.
996.
997.
998.
Geoid determination using adapted reference field, seismic Moho depths and variable density contrast 总被引:4,自引:0,他引:4
The traditional remove-restore technique for geoid computation suffers from two main drawbacks. The first is the assumption
of an isostatic hypothesis to compute the compensation masses. The second is the double consideration of the effect of the
topographic–isostatic masses within the data window through removing the reference field and the terrain reduction process.
To overcome the first disadvantage, the seismic Moho depths, representing, more or less, the actual compensating masses, have
been used with variable density anomalies computed by employing the topographic–isostatic mass balance principle. In order
to avoid the double consideration of the effect of the topographic–isostatic masses within the data window, the effect of
these masses for the used fixed data window, in terms of potential coefficients, has been subtracted from the reference field,
yielding an adapted reference field. This adapted reference field has been used for the remove–restore technique. The necessary
harmonic analysis of the topographic–isostatic potential using seismic Moho depths with variable density anomalies is given.
A wide comparison among geoids computed by the adapted reference field with both the Airy–Heiskanen isostatic model and seismic
Moho depths with variable density anomaly and a geoid computed by the traditional remove–restore technique is made. The results
show that using seismic Moho depths with variable density anomaly along with the adapted reference field gives the best relative
geoid accuracy compared to the GPS/levelling geoid.
Received: 3 October 2001 / Accepted: 20 September 2002
Correspondence to: H.A. Abd-Elmotaal 相似文献
999.
K. Nageswara Rao G. Murali Krishna D. Ramprasad Naik B. Hema Malini 《Journal of the Indian Society of Remote Sensing》2003,31(2):71-80
Interpretation of IRS LISS II and LISS III imagery has revealed the various landforms as well as land use/land cover features in a part of the Godavari delta coastal belt. A comparative analysis of geomorphological vs. land use/land cover maps suggested that the landforms exert a certain degree of control over human land use activities even in this monotonously plain area. Further, an analysis of the sequential imagery pertaining to 1992 and 2001 aimed at detecting the land use/land cover change has indicated that the aquaculture has phenomenally increased by 9,293.5 ha during the 9-year period. At the same time, the cropland which occupied about 29,104 ha in 1992 has been reduced to 19,153.9 ha by 2001 mainly due to the encroachment of aquaculture. Village level data on temporal variation in land use/land cover extracted through GIS analysis revealed that in 14 out of the total 39 villages in the area, the conversion of cropland into aquaculture ponds was more than 30% with the highest conversion rate of 89.8% in Gondi village. These fourteen villages, which are designated as ‘aquaculture hotspots’ are grouped into 4 priority classes based on the intensity of conversion. 相似文献
1000.
High-resolution simulations of global climate, part 2: effects of increased greenhouse cases 总被引:6,自引:0,他引:6
We report results from the highest-resolution simulations of global warming yet performed with an atmospheric general circulation model. We compare the climatic response to increased greenhouse gases of the National Center for Atmospheric Research (NCAR) climate model, CCM3, at T42 and T170 resolutions (horizontal grid spacing of 300 and 75 km respectively). All simulations use prescribed sea surface temperatures (SST). Simulations of the climate of 2100 ad use SSTs based on those from NCAR coupled model, Climate System Model (CSM). We find that the global climate sensitivity and large-scale patterns of climate change are similar at T42 and T170. However, there are important regional scale differences that arise due to better representation of topography and other factors at high resolution. Caution should be exercised in interpreting specific features in our results both because we have performed climate simulations using a single atmospheric general circulation model and because we used with prescribed sea surface temperatures rather than interactive ocean and sea-ice models. 相似文献