Assessment of the topsoil heavy metals pollution in the Sarno River basin,south Italy

The Sarno River basin area is one of the most polluted in Europe and it is due to the waste products of the tomato industry, the leather tanneries and the pharmaceutical industry. This area also has been densely populated and urbanized since the Middle Bronze Age, as testified by the presence of numerous archeological sites, including the ancient Pompeii town, and environmental degradation that characterizes the area is absolutely unacceptable. This paper represents a detailed study to assess the potentially harmful element content of topsoils. In total, 283 soil samples were collected and analyzed, after an aqua regia extraction, by a combination of inductively coupled plasma atomic emission and inductively coupled plasma mass spectrometry for 53 elements. Univariate and multivariate analyses were carried out to show the single-element geochemical distribution and the distribution of factor scores of the elemental associations resulting from R-mode factor analysis. Maps showing elements and the association factor score distributions have been obtained using GeoDAS and ArcGIS software. The assessment of the soil contamination was also carried out using the contamination factor and degree of contamination. The results obtained indicate that soil pollution has different anthropogenic sources. Specifically, Cr pollution derives from tanneries discharging wastewaters in the main water bodies of the basin while Cu contamination seems to depend on widespread agricultural practices. Tin, Pb, Hg, Zn, Cd, Sb anomalies are found mainly in urban and industrial areas, sometimes close to roads with high traffic levels while there is a substantial coincidence with background values for other elements (Co, Ni, Se, Tl and V).     

A methodological approach for estimating turbidity in a river

During the operations of purging and disposal of sediments of a reservoir it is necessary to know the values of turbidity in the river downstream in natural condition,in the absence of dams or river training works.The paper shows that under these conditions the ratio of the average values of sediment discharge to the annual maximum value of water discharge is a function of the average annual turbidity.Turbidity can be considered as representative synthetic index of the climatic conditions,the lithological features and the land cover of the basin,and the geometric characteristics of the river network.The proposed relationship of sediment discharge as a function of water discharge were validated on the basis of data collected from different Italian regions that have very different morphological,geo-lithological and rainfall features and that are characterised by a basin area changing between a few dozen and thousands of square kilometres.The results can be considered satisfying.     

Pore pressure tension cut off in two-phase finite element analyses

In the coupled finite element analysis of the two-phase, saturated soils the pore pressure could decrease below the atmospheric pressure in particular when the plastic dilation of the skeleton is accounted for. The consequent reduction of the bulk modulus of the liquid phase is here modelled in a simplified manner through a tension cut off on the pore pressure. Two alternative approaches are outlined in the framework of the finite element method. The first one introduces a unilateral constraint on the nodal pore pressures and involves manipulations on matrices of the assembled mesh, whilst the second approach requires calculations solely at the element level. The effects of the pore pressure tension cut off are illustrated through some undrained test examples in elastic–plastic regime.     

U–Pb zircon data of Variscan meta-igneous and igneous acidic rocks from an Alpine shear zone in Calabria (southern Italy)

The paper deals with the U–Pb data of zircon separated from three samples representative of mylonitic leucogranites, trondhjemites and pegmatites occurring along the Alpine tectonic zone between the Castagna and Sila Units in northern Calabria. These mylonites are associated to Variscan granitic-granodioritic biotite-rich augen gneisses derived from Neo-Proterozoic-Early Cambrian protoliths. Apparent ages ranging from Early Cambrian to post-Variscan have been obtained. Th, U and rare earth elements have been determined in two zircon domains of mylonitic leucogranite and trondhjemite giving different ages in order to get information relative to their geological significance. The pegmatite preserves intrusive contact with the augen gneisses and with the other mylonites; it turns out to be emplaced at 290–300 Ma, like the Variscan plutonites of the Castagna Unit. The deformation masks the original contacts of the mylonitic leucogranite and trondhjemite with the biotite-rich augen gneisses. The age-group averaging 540 Ma is interpreted as indicative of the emplacement of the protoliths and it coincides with the age previously determined for the emplacement of the protoliths of the biotite-rich augen gneisses. Zircon from the mylonitic pegmatite includes domains showing concordant and discordant ages younger than 290 Ma, thus reflecting various degrees of partial resetting and Pb-loss caused by post-Variscan events. Zircon from the mylonitic leucogranite and trondhjemite includes apparent ages between 300 and 280 Ma as well as ages younger than 250 Ma. Perturbation of U–Pb system by Alpine shearing appears evident; however, possibile effects caused by thermal input and hydrothermal fluid infiltration from the Variscan plutonites cannot be excluded.     

<Superscript>40</Superscript>Ar/<Superscript>39</Superscript>Ar ages of the<Emphasis Type="Italic"> AD</Emphasis> 79 eruption of Vesuvius,Italy

The Italian volcano, Vesuvius, erupted explosively in AD 79. Sanidine from pumice collected at Casti Amanti in Pompeii and Villa Poppea in Oplontis yielded a weighted-mean ⁴⁰Ar/³⁹Ar age of 1925±66 years in 2004 (1σ uncertainty) from incremental-heating experiments of eight aliquants of sanidine. This is the calendar age of the eruption. Our results together with the work of Renne et al. (1997) and Renne and Min (1998) demonstrate the validity of the ⁴⁰Ar/³⁹Ar method to reconstruct the recent eruptive history of young, active volcanoes.     

Shallow-landslide susceptibility in the Costa Viola mountain ridge (southern Calabria,Italy) with considerations on the role of causal factors

The “Costa Viola” mountain ridge (southern Calabria), in the sector between Bagnara Calabra and Scilla, is particularly exposed to geo-hydrological risk conditions. The study area has repeatedly been affected by slope instability events in the last decades, mainly related to debris slides, rock falls and debris flows. These types of slope movements are among the most destructive and dangerous for people and infrastructures, and are characterized by abrupt onset and extremely rapid movements. Susceptibility evaluations to shallow landslides have been performed by only focusing on source activation. A logistic regression approach has been applied to estimating the presence/absence of sources in terms of probability, on the basis of linear statistical relationships with a set of territorial variables. An inventory map of 181 sources, obtained from interpretation of air photographs taken in 1954–1955, has been used as training set, and another map of 81 sources, extracted from 1990 to 1991 photographs, has been adopted for validation purposes. An initial set of 12 territorial variables (i.e. lithology, land use, soil sand percentage, elevation, slope angle, aspect, across-slope and down-slope curvatures, topographic wetness index, distance to road, distance to fault and index of daily rainfall) has been considered. The adopted regression procedure consists of the following steps: (1) parameterization of the independent variables, (2) sampling, (3) calibration, (4) application and (5) evaluation of the forecasting capability. The “best set” of variables could be identified by iteratively excluding one variable at a time, and comparing the ROC results. Through a sensitivity analysis, the role of the considered factors in predisposing shallow slope failures in the study area has been evaluated. The results obtained for the Costa Viola mountain ridge can be considered acceptable, as 98.1 % of the cells are correctly classified. According to the susceptibility map, the village of Scilla and its surroundings fall in the highest susceptibility class.     

An approximate F.E. analysis of seepage with a free surface

An approximate step-by-step procedure is presented for the finite element analysis of transient unconfined flow problems. At each step the free surface is modelled by means of segments coinciding with sides of the elements. This leads to an approximate but extremely simple solution scheme which can be readily incorporated into standard codes for confined analysis. The solutions of some significant problems are presented and compared with other non-approximate solutions. They show that the technique, in spite of its approximation, is capable of giving meaningful results from an engineering viewpoint.     

Pompeii Damaged by Volcaniclastic Debris Flows Triggered Centuries Prior to the 79 A.D. Vesuvius Eruption

This study records that Pompeii, long before its final devastation by the 79 A.D. Vesuvius eruption in southern Italy, was damaged by several mass gravity flows. Composition of the deposits indicates that they were derived from volcaniclastic cover of carbonate highlands positioned 14 km NE of the city. Stratigraphic and petrologic analyses of sections in excavations and drill cores in and near Pompeii record the presence of three downslope‐directed debris flows dated between 8th and 2nd century B.C. Some of these deposits were channelized via a stream bed that once extended from high reliefs to Pompeii. It is proposed that one of these events may have been partially responsible for urban decline during the 4th century B.C. These mass flows are interpreted as having been triggered primarily by intense rains in a manner similar to those that have occurred and destroyed towns in this region during the past 50 years. Our investigation shows that Pompeii and adjacent areas in the past, much as in recent time, have likely been most frequently susceptible to episodic damage by avalanches and mass flows of volcaniclastic material resulting from hydrological effects rather than from volcanic events, earthquake tremors, and societal disruptions such as wars.