The interannual variability of the surface eddy kinetic energy in the Labrador Sea

The variability of the surface eddy kinetic energy (EKE) in the Labrador Sea is investigated with a suite of numerical integrations using a regional ocean model. Simulations are performed over the period 1980–2001 and are compared to satellite observations over the last 9 years. The surface EKE pattern in the basin is dominated by a region along the West coast of Greenland where eddies, mainly anticyclonic, are formed by instability of the main currents flowing over the continental slope, consistent with previous idealized results. Here the interannual changes are linked to the shear of the incoming boundary current system imposed as boundary condition to the model domain. The highly variable strength of the East Greenland current at the northeast boundary, derived from the Simple Ocean Data Assimilation (SODA) reanalysis, strongly influences the vortex formation.In the center of the Labrador Sea, where deep convection occurs, a statistically significant portion of the modeled interannual surface EKE variability is correlated with the local atmospheric forcing, and both heat and wind fluxes play an important role and can be adopted as predictors at a lag of 2–3 months. The Arctic Oscillation index can also be used as a remote indicator of the atmospheric fluxes, but with lower skill than local measurements. In contrast the North Atlantic Oscillation index does not correlate significantly with the surface EKE at intraseasonal and interannual scales. The analysis of altimeter data over the 1993–2001 supports the existence of this asymmetry between the regime locally forced by the atmosphere in the central basin, and the regime remotely forced by the incoming boundary current along the west Greenland coast. Those results have important implications for monitoring and predicting the surface eddy kinetic energy variability in the Labrador Sea.     

Applicability and intercalibration of macrophyte quality indices to characterise the ecological status of Mediterranean transitional waters: the case of the Venice lagoon

In the framework of the WFD 2000/60/EC intercalibration process the updated versions of the EEI and R‐MaQI, proposed by Italy and Greece for the transitional waters, have been applied to the macrophytes of the Venice lagoon to test their comparability and relationships with the pressure gradients. Submerged macrophytes were collected during spring 2007 at 60 sites spread within the lagoon. At each site, five random samples were collected and the total coverage of benthic macrophytes in the field was estimated based on a number of tests of the bottom. To assess seagrass epiphytes, five shoots were collected for each replicate. Physico‐chemical data were collected in the water column at 14 sites selected to reflect the main hydro‐geomorphological and trophic gradients of the lagoon. The analyses performed indicated that the two metrics appeared to be weakly intercalibrated and only the 30% of the sampling sites displayed the same quality class. The main differences fell into the Moderate and Low classes and the two indices provided discordant results in the intermediate and confined areas of the lagoon. In contrast, the two indices showed good affinity in the marine areas of inlets, which are characterised by seagrass meadows and late‐successional macroalgae. Similar results were evidenced also in a redundancy analysis by the different relationships between quality classes and the physico‐chemical gradients. The main reason for this seems to be the heterogeneity of species–environment relationships inside the groups of species on which the indices are based. Critical aspects of methodological differences and applicability of the macrophyte indices proposed by Italy and Greece for the transitional waters of the Mediterranean eco‐region are discussed.     

A structural and geophysical approach to the study of fractured aquifers in the Scansano-Magliano in Toscana Ridge, southern Tuscany, Italy

Fresh water availability has recently become a serious concern in the Italian Apennines, as various activities rely on a predictable supply. Along the ridge between Scansano and Magliano in Toscana, in southern Tuscany, the situation is further complicated by contamination of the nearby alluvial aquifers. Aquifers locally consist of thin fractured reservoirs, generally within low-permeability formations, and it can be difficult to plan the exploitation of resources based on conventional techniques. An integrated study based on geological data investigated the link between tectonics and groundwater circulation, to better define the hydrological model. After the regional identification of fault and fracture patterns, a major structure was investigated in detail to accurately map its spatial position and to understand the geometry and properties of the associated aquifer and assess its exploitation potential. The subsurface around the fault zone was clearly imaged using ground probing radar, two-dimensional and three-dimensional resistivity tomography, and three-dimensional shallow seismic surveys. The vertical and horizontal contacts between the different geological units of the Ligurian and Tuscan series were resolved with a high degree of spatial accuracy. Three-dimensional high-resolution geophysical imaging proved to be a very effective means of characterising small-scale fractured reservoirs.     

Polyphase thrusting and dyke emplacement in the central Southern Alps (Northern Italy)

The Triassic succession of the central Southern Alps (Italy) is stacked into several units bounded by south-verging low-angle thrust faults, which are related to two successive steps of crustal shortening. The thrust surfaces are cut by high-angle extensional and strike-slip faults, which controlled the emplacement of hypabissal magmatic intrusions that post-date thrusts motions. Intrusion ages based on SHRIMP U–Pb zircon dating span between 42 ± 1 and 39 ± 1 Ma, suggesting close time relationships with the earliest Adamello intrusion stages and, more in general, with the widespread calc-alkaline magmatism described in the Southern Alps. Fission-track ages of magmatic apatites are indistinguishable from U–Pb crystallization ages of zircons, suggesting that the intrusion occurred in country rocks already exhumed above the partial annealing zone of apatite (depth < 2–4 km). These data indicate that the central Southern Alps were already structured and largely exhumed in the Middle Eocene. Although we describe minor faults affecting magmatic bodies and local reactivations of older structures, no major internal deformations have occurred in the area after the Bartonian. Neogene deformations were instead concentrated farther south, along the frontal part of the belt.     

Exploring lava‐flow hazards at Pico Island,Azores Archipelago (Portugal)

Pico, the youngest island of the Azores Archipelago (Portugal), is characterized by a central volcano and a 30‐km‐long fissure zone. Its eruption rate is the highest of the Azores islands, with more than 35 eruptions in the last 2000 years. Here, we estimate the lava‐flow hazard for Pico Island by combining the vent opening probability derived from the spatial distribution of eruptive fissures, the classes of expected eruptions inferred from the physical and chemical characteristics of historical eruptions, and the lava‐flow paths simulated by the MAGFLOW model. The most likely area to host new eruptions is along a WNW–ESE trend centred on the central volcano, with the highest hazard affecting the two main residential zones of Lajes do Pico and Madalena. Our analysis is the first attempt to assess the lava‐flow hazard for Pico Island, and may have important implications for decision‐making in territorial management and future land‐use planning.     

In situ time resolved synchrotron powder diffraction study of thaumasite

Structural changes during dehydration and subsequent decomposition in thaumasite Ca₃Si(SO₄)(CO₃)(OH)₆·12 H₂O were studied by in situ synchrotron powder diffraction between 303 and 1,098 K. Evolution of the crystal structure was observed through 28 structure refinements, by full profile Rietveld analysis performed in the P6₃ space group, between 300 and 417 K, whereupon the thaumasite structure was observed to breakdown. Within this temperature range, the cell parameters of thaumasite increased as a function of temperature in a nearly linear fashion up to about 393 K, at which temperature, a slight slope change was observed. Above 400 K, the thermogravimetric analysis revealed that the dehydration process proceeded very rapidly while the refined occupancy of water molecules dropped below a critical level, leading to instability in the thaumasite structure. At a same time, a remarkable change in the unit cell parameters occurring at about 417 K indicated that the crystal structure of thaumasite collapsed on losing the crystallization water and it turned amorphous. This result indicated that the dehydration/decomposition of thaumasite was induced by the departure of the crystallization water. At about 950 K, anhydrite and cristobalite crystallized from the thaumasite glass.     

Impact of extreme CO2 levels on tropical climate: a CGCM study

A coupled general circulation model has been used to perform a set of experiments with high CO₂ concentration (2, 4, 16 times the present day mean value). The experiments have been analyzed to study the response of the climate system to strong radiative forcing in terms of the processes involved in the adjustment at the ocean–atmosphere interface. The analysis of the experiments revealed a non-linear response of the mean state of the atmosphere and ocean to the increase in the carbon dioxide concentration. In the 16 × CO₂ experiment the equilibrium at the ocean–atmosphere interface is characterized by an atmosphere with a shut off of the convective precipitation in the tropical Pacific sector, associated with air warmer than the ocean below. A cloud feedback mechanism is found to be involved in the increased stability of the troposphere. In this more stable condition the mean total precipitation is mainly due to large-scale moisture flux even in the tropics. In the equatorial Pacific Ocean the zonal temperature gradient of both surface and sub-surface waters is significantly smaller in the 16 × CO₂ experiment than in the control experiment. The thermocline slope and the zonal wind stress decrease as well. When the CO₂ concentration increases by about two and four times with respect to the control experiment there is an intensification of El Niño. On the other hand, in the experiment with 16 times the present-day value of CO₂, the Tropical Pacific variability weakens, suggesting the possibility of the establishment of permanent warm conditions that look like the peak of El Niño.     

Effects of increased CO2 levels on monsoons

Increased atmospheric carbon dioxide concentration provided warmer atmospheric temperature and higher atmospheric water vapor content, but not necessarily more precipitation. A set of experiments performed with a state-of-the-art coupled general circulation model forced with increased atmospheric CO₂ concentration (2, 4 and 16 times the present-day mean value) were analyzed and compared with a control experiment to evaluate the effect of increased CO₂ levels on monsoons. Generally, the monsoon precipitation responses to CO₂ forcing are largest if extreme concentrations of carbon dioxide are used, but they are not necessarly proportional to the forcing applied. In fact, despite a common response in terms of an atmospheric water vapor increase to the atmospheric warming, two out of the six monsoons studied simulate less or equal summer mean precipitation in the 16×CO₂ experiment compared to the intermediate sensitivity experiments. The precipitation differences between CO₂ sensitivity experiments and CTRL have been investigated specifying the contribution of thermodynamic and purely dynamic processes. As a general rule, the differences depending on the atmospheric moisture content changes (thermodynamic component) are large and positive, and they tend to be damped by the dynamic component associated with the changes in the vertical velocity. However, differences are observed among monsoons in terms of the role played by other terms (like moisture advection and evaporation) in shaping the precipitation changes in warmer climates. The precipitation increase, even if weak, occurs despite a weakening of the mean circulation in the monsoon regions (??precipitation-wind paradox??). In particular, the tropical east-west Walker circulation is reduced, as found from velocity potential analysis. The meridional component of the monsoon circulation is changed as well, with larger (smaller) meridional (vertical) scales.