An investigation of the SO2 content of the venusian mesosphere using SPICAV-UV in nadir mode

Using the SPICAV-UV spectrometer aboard Venus Express in nadir mode, we were able to derive spectral radiance factors in the middle atmosphere of Venus in the 170-320 nm range at a spectral resolution of R ? 200 during 2006 and 2007 in the northern hemisphere. By comparison with a radiative transfer model of the upper atmosphere of Venus, we could derive column abundance above the visible cloud top for SO₂ using its spectral absorption bands near 280 and 220 nm. SO₂ column densities show large temporal and spatial variations on a horizontal scale of a few hundred kilometers. Typical SO₂ column densities at low latitudes (up to 50°N) were found between 5 and 50 μm-atm, whereas in the northern polar region SO₂ content was usually below 5 μm-atm. The observed latitudinal variations follow closely the cloud top altitude derived by SPICAV-IR and are thought to be of dynamical origin. Also, a sudden increase of SO₂ column density in the whole northern hemisphere has been observed in early 2007, possibly related to a convective episode advecting some deep SO₂ into the upper atmosphere.     

Atmospheric electricity measurements over the Indian Ocean

Summary Results of measurements of the atmospheric electrical conductivity and potential gradient made during the sixth Scientific Cruise of the Indian Oceanographic Ship INS Kistna in the Bay of Bengal during February–March 1963 are presented. Observations were made when the skies were generally clear and the sea calm, in the geographical area 8°N to 17°N and 80°E to 95°E, on the outward journey of INS Kistna from Madras (80°E, 13°N) to Port Blair (93°E, 12°N) and on the return journey to Madras.Over the ocean where there are no local sources of pollution, the measured values of conductivity and potential gradient are in agreement with theoretical values, assuming that an ion equilibrium exists, that ions are destroyed primarily by collision with small ions of opposite sign and that small ions are produced only by cosmic radiation. The values of electrical conductivity obtained are generally of the same order as those to be expected from theoretical considerations and in general agreement with those obtained during the Carnegie cruises in the Indian Ocean in 1920. There are, however, significant variations near the coast where the electric structure above the ocean is affected by continental sources of pollution. Conductivity values near the land are about half that in the unpolluted air over the ocean but prevailing winds prevent the extension of pollution beyond 100–200 km from the coast in this season.

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Zusammenfassung Es wird über Messungen der luftelektrischen Leitfähigkeit und des Potentialgefälles berichtet, welche während der Sechsten Wissenschaftlichen Kreuzfahrt des indischen Ozeanographischen Forschungsschiffes Ins Kistna in der Bengalischen Bucht im Februar und März 1963 ausgeführt wurden. Die Beobachtungen sind im allgemeinen bei klarem Himmel und ruhiger See gemacht worden, und zwar in dem geographischen Bereich zwischen 8 und 17°N und 80 und 95°E während der Ausfahrt der INS Kistna von Madras (80°E, 13°N) nach Port Blair (93°E, 12°N) und auf der Rückreise nach Madras. In den Bereichen des Ozeans, in denen keine örtlichen Pollutionsquellen bestehen, stimmen die gemessenen Werte der Leitfähigkeit und des Potentialgefälles mit den theoretischen Werten überein, die man erhält, wenn man annimmt, dass ein Ionengleichgewicht besteht, dass die schnellen Ionen vorwiegend durch Zusammenstoss mit schnellen Ionen des entgegengesetzten Vorzeichens vernichtet werden, und dass die schnellen Ionen nur durch die kosmische Höhenstrahlung erzeugt werden. Die Werte der Leitfähigkeit stimmen mit denen überein, die man aus theoretischen Überlegungen gewinnt, und auch mit denen, die während der Kreuzfahrten des Forschungsschiffes Carnegie im Indischen Ozean im Jahre 1920 gemessen Küste sind jedoch bedeutsame Abweichungen festzustellen, wo die elektrischen Verhältenisse über dem Ozean durch Pollutionsquellen auf dem Lande beeinflusst werden. Die Leitfähigkeitswerte nahe dem Land sind nur ungefähr halb so gross wie die in der pollutionsfreien Luft des offenen Ozeans-jedoch haben die während der Mess-Jahreszeit vorherrschenden Winde eine Ausbreitung der Pollutionszone auf einen Bereich von 100 bis 200 km von der Küste beschränkt.

     

Late‐glacial to Holocene depositional architecture of the Ombrone palaeovalley system (Southern Tuscany,Italy): Sea‐level,climate and local control in valley‐fill variability

The Ombrone palaeovalley was incised during the last glacial sea‐level fall and was infilled during the subsequent Late‐glacial to Holocene transgression. A detailed sedimentological and stratigraphic study of two cores along the palaeovalley axis led to reconstruction of the post‐Last Glacial Maximum valley‐fill history. Stratigraphic correlations show remarkable similarity in the Late‐glacial to early‐Holocene succession, but discrepancy in the Holocene portion of the valley fill. Above the palaeovalley floor, about 60 m below sea‐level, Late‐glacial sedimentation is recorded by an unusually thick alluvial succession dated back to ca 18 cal kyr bp . The Holocene onset was followed by the retrogradational shift from alluvial to coastal facies. In seaward core OM1, the transition from inner to outer estuarine environments marks the maximum deepening of the system. By comparison, in landward core OM2, the emplacement of estuarine conditions was interrupted by renewed continental sedimentation. Swamp to lacustrine facies, stratigraphically equivalent to the fully estuarine facies of core OM1, represent the proximal expression of the maximum flooding zone. This succession reflects location in a confined segment of the valley, just landward of the confluence with a tributary valley. It is likely that sudden sediment input from the tributary produced a topographic threshold, damming the main valley course and isolating its landward segment from the sea. The seaward portion of the Ombrone palaeovalley presents the typical estuarine backfilling succession of allogenically controlled incised valleys. In contrast, in the landward portion of the system, local dynamics completely overwhelmed the sea‐level signal, following marine ingression. This study highlights the complexity of palaeovalley systems, where local morphologies, changes in catchment areas, drainage systems and tributary valleys may produce facies patterns significantly different from the general stratigraphic organization depicted by traditional sequence‐stratigraphic models.     

Balancing trade‐off issues in land use change and the impact on streamflow and salinity management

The south‐west region of the Goulburn–Broken catchment in the south‐eastern Murray–Darling Basin in Australia faces a range of natural resource challenges. A balanced strategy is required to achieve the contrasting objectives of remediation of land salinization and reducing salt export, while maintaining water supply security to satisfy human consumption and support ecosystems. This study linked the Catchment Analysis Tool (CAT), comprising a suite of farming system models, to the catchment‐scale CATNode hydrological model to investigate the effects of land use change and climate variation on catchment streamflow and salt export. The modelling explored and contrasted the impacts of a series of different revegetation and climate scenarios. The results indicated that targeted revegetation to only satisfy biodiversity outcomes within a catchment is unlikely to have much greater impact on streamflow and salt load in comparison with simple random plantings. Additionally, the results also indicated that revegetation to achieve salt export reduction can effectively reduce salt export while having a disproportionately smaller affect on streamflows. Furthermore, streamflow declines can be minimized by targeting revegetation activities without significantly altering salt export. The study also found that climate change scenarios will have an equal if not more significant impact on these issues over the next 70 years. Uncertainty in CATNode streamflow predictions was investigated because of the effect of parameter uncertainty. Copyright © 2012 John Wiley & Sons, Ltd.     

Relocation effects of dredged marine sediments on mercury geochemistry: Venice lagoon,Italy

Understanding the biogeochemical process of Hg is critical in the overall evaluation of the ecological impacts resulting from the reuse of Hg-contaminated dredged sediment. Sediment banks (V1 and V2) were constructed with freshly dredged sediments from a navigational channel in Venice Lagoon, Italy, with the goal of clarifying potential differences in the biogeochemistry of Hg between the reused dredged sediments and those from surrounding sites (SS1 and S2). Toward this purpose, Hg and monomethylmercury (MMHg) concentrations, and Hg methylation rates (MMRs) in the surface 2.5 cm sediments were monitored, along with ammonium, iron, sulfate and sulfide concentrations in the pore waters of banks and surrounding sites from November 2005 to February 2007. Pore water analyses indicate that the bank sediments are characterized by lower levels of sulfate and iron, and by higher levels of ammonium and sulfide compared to the surrounding sediments. With respect to Hg speciation, the fractions of MMHg in total Hg (%MMHg/Hg) and the MMRs were significantly lower in the bank V1 compared to those in the reference site SS1, whereas the %MMHg/Hg and the MMRs were similar between V2 and S2. A negative correlation is found between the logarithm of the particle-water partition coefficient of Hg and the MMR, indicating that the reduced MMRs in V1 are caused by the limited concentrations of dissolved Hg. Organic matter appears to play a key role in the control of MMR via the control of Hg solubility.     

Nutrients and zooplankton composition and dynamics in relation to the hydrological pattern in a confined Mediterranean salt marsh (NE Iberian Peninsula)

The role of the hydrological regime in the nutrients and zooplankton composition and dynamics has been analysed in five lagoons of La Pletera salt marshes (NE Iberian Peninsula) during a complete hydrological cycle (2002–2003). Two of the lagoons have their origin in the old river mouths while the other three were recently created in the framework of a Life Restoration project. This fact has also allowed us to study the effect of the lagoon age on nutrient and zooplankton composition and dynamics. The salt marsh hydrology is determined by a prolonged period of confinement without water inputs, irregularly interrupted by sudden water inputs due to flooding events (sea storms or intense rainfalls). While the dynamics of oxidized nitrogen compounds in the lagoons depends on the water inputs variability within each hydrological cycle, the internal load of phosphorus, total nitrogen and organic matter is related more to the cumulative mechanisms during the confinement periods. Accumulation processes may be easily related to lagoon age, since old lagoons have higher content of nutrients and organic matter, suggesting that these lagoons progressively accumulate nutrients during the successive confinement events. This is the usual case for most Mediterranean salt marshes without an artificially manipulated water regime. The zooplankton community in La Pletera integrates the effects of both the hydrological regime and the lagoon age since the former determines the temporal pattern of the main zooplankton species and the latter explains differences in composition and structure between old and new lagoons.     

Normal fault growth influenced by basement fabrics: The importance of preferential nucleation from pre‐existing structures

Reactivation of pre‐existing intra‐basement structures can influence the evolution of rift basins, yet the detailed kinematic relationship between these structures and overlying rift‐related faults remains poorly understood. Understanding the kinematic as well as geometric relationship between intra‐basement structures and rift‐related fault networks is important, with the extension direction in many rifted provinces typically thought to lie normal to fault strike. We here investigate this problem using a borehole‐constrained, 3D seismic reflection dataset from the Taranaki Basin, offshore New Zealand. Excellent imaging of intra‐basement structures and a relatively weakly deformed, stratigraphically simple sedimentary cover allow us to: (a) identify a range of interaction styles between intra‐basement structures and overlying, Plio‐Pleistocene rift‐related normal faults; and (b) examine the cover fault kinematics associated with each interaction style. Some of the normal faults parallel and are physically connected to intra‐basement reflections, which are interpreted as mylonitic reverse faults formed during Mesozoic subduction and basement terrane accretion. These geometric relationships indicate pre‐existing intra‐basement structures locally controlled the position and attitude of Plio‐Pleistocene rift‐related normal faults. However, through detailed 3D kinematic analysis of selected normal faults, we show that: (a) normal faults only nucleated above intra‐basement structures that experienced late Miocene compressional reactivation, (b) despite playing an important role during subsequent rifting, intra‐basement structures have not been significantly extensionally reactivated, and (c) preferential nucleation and propagation of normal faults within late Miocene reverse faults and folds appears to be the key genetic relationship between contractionally reactivated intra‐basement structures and rift‐related normal faults. Our analysis shows that km‐scale, intra‐basement structures can control the nucleation and development of newly formed, rift‐related normal faults, most likely due to a local perturbation of the regional stress field. Because of this, simply inverting fault strike for causal extension direction may be incorrect, especially in provinces where pre‐existing, intra‐basement structures occur. We also show that a detailed kinematic analysis is key to deciphering the temporal as well as simply the spatial or geometric relationship between structures developed at multiple structural levels.     

Solar Microflares Observed by SphinX and RHESSI

In 2009, the Russian Complex Orbital Observations Near-Earth of Activity of the Sun (CORONAS-Photon) spacecraft was launched, carrying the Polish Solar PHotometer In X-rays (SphinX). The SphinX was most sensitive in the spectral range 1.2?–?15 keV, thus an excellent opportunity appeared for comparison with the low-energy end of Ramaty High Energy Solar Spectroscopic Imager (RHESSI) spectra. Common spectral measurements with these instruments cover the range where most of the flare energy is accumulated. We have chosen four consecutive small solar events observed on 4 July 2009 at 13:43 UT, 13:48 UT, 13:52 UT, and 13:55 UT (RHESSI flare peak times) and used them to compare the data and results from the two instruments. Moreover, we included Geostationary Operational Environmental Satellite (GOES) records in our analysis. In practice, the range of comparison performed for SphinX and RHESSI is limited roughly to 3?–?6 keV. RHESSI fluxes measured with a use of one, four, and nine detectors in the 3?–?4 keV energy band agree with SphinX measurements. However, we observed that SphinX spectral irradiances are three times higher than those of RHESSI in the 4?–?6 keV energy band. This effect contributes to the difference in obtained emission measures, but the derived temperatures of plasma components are similar. RHESSI spectra were fitted using a model with two thermal components. We have found that the RHESSI hot component is in agreement with GOES, and the RHESSI hotter component fits the SphinX flaring component well. Moreover, we calculated the so-called thermodynamic measure and the total thermal energy content in the four microflares that we studied. The results obtained show that SphinX is a very sensitive complementary observatory for RHESSI and GOES.